N-Alkylation of amines with alcohols over nanosized zeolite beta
Direct N-alkylation of amines with alcohols was successfully performed by using nanosized zeolite beta, which showed the highest catalytic activity among other conventional zeolites. This method has several advantages, such as eco-friendliness, moderate to high yields, and simple work-up procedure....
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Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (12), p.3474-3483 |
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container_title | Green chemistry : an international journal and green chemistry resource : GC |
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creator | MARRI MAHENDER REDDY MACHARLA ARUN KUMAR SWAMY, Peraka NARESH, Mameda SRUJANA, Kodumuri SATYANARAYANA, Lanka VENUGOPAL, Akula NARENDER, Nama |
description | Direct N-alkylation of amines with alcohols was successfully performed by using nanosized zeolite beta, which showed the highest catalytic activity among other conventional zeolites. This method has several advantages, such as eco-friendliness, moderate to high yields, and simple work-up procedure. The catalyst was successfully recovered and reused without significant loss of activity and only water is produced as co-product. In addition, imines were also efficiently prepared from the tandem reactions of amines with 2-, 3- and 4-nitrobenzyl alcohols using nanosized zeolite beta. |
doi_str_mv | 10.1039/c3gc41345d |
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This method has several advantages, such as eco-friendliness, moderate to high yields, and simple work-up procedure. The catalyst was successfully recovered and reused without significant loss of activity and only water is produced as co-product. In addition, imines were also efficiently prepared from the tandem reactions of amines with 2-, 3- and 4-nitrobenzyl alcohols using nanosized zeolite beta.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/c3gc41345d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alcohols ; Amines ; Beta ; Catalysis ; Catalysts: preparations and properties ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Imines ; Nanocomposites ; Nanomaterials ; Nanostructure ; Noncondensed benzenic compounds ; Organic chemistry ; Preparations and properties ; Theory of reactions, general kinetics. Catalysis. 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This method has several advantages, such as eco-friendliness, moderate to high yields, and simple work-up procedure. The catalyst was successfully recovered and reused without significant loss of activity and only water is produced as co-product. In addition, imines were also efficiently prepared from the tandem reactions of amines with 2-, 3- and 4-nitrobenzyl alcohols using nanosized zeolite beta.</description><subject>Alcohols</subject><subject>Amines</subject><subject>Beta</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Imines</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Noncondensed benzenic compounds</subject><subject>Organic chemistry</subject><subject>Preparations and properties</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>MARRI MAHENDER REDDY</creatorcontrib><creatorcontrib>MACHARLA ARUN KUMAR</creatorcontrib><creatorcontrib>SWAMY, Peraka</creatorcontrib><creatorcontrib>NARESH, Mameda</creatorcontrib><creatorcontrib>SRUJANA, Kodumuri</creatorcontrib><creatorcontrib>SATYANARAYANA, Lanka</creatorcontrib><creatorcontrib>VENUGOPAL, Akula</creatorcontrib><creatorcontrib>NARENDER, Nama</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>MARRI MAHENDER REDDY</au><au>MACHARLA ARUN KUMAR</au><au>SWAMY, Peraka</au><au>NARESH, Mameda</au><au>SRUJANA, Kodumuri</au><au>SATYANARAYANA, Lanka</au><au>VENUGOPAL, Akula</au><au>NARENDER, Nama</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>N-Alkylation of amines with alcohols over nanosized zeolite beta</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>15</volume><issue>12</issue><spage>3474</spage><epage>3483</epage><pages>3474-3483</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Direct N-alkylation of amines with alcohols was successfully performed by using nanosized zeolite beta, which showed the highest catalytic activity among other conventional zeolites. This method has several advantages, such as eco-friendliness, moderate to high yields, and simple work-up procedure. The catalyst was successfully recovered and reused without significant loss of activity and only water is produced as co-product. In addition, imines were also efficiently prepared from the tandem reactions of amines with 2-, 3- and 4-nitrobenzyl alcohols using nanosized zeolite beta.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c3gc41345d</doi><tpages>10</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Alcohols Amines Beta Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Imines Nanocomposites Nanomaterials Nanostructure Noncondensed benzenic compounds Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zeolites |
title | N-Alkylation of amines with alcohols over nanosized zeolite beta |
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