Combined Time-Resolved Laser Fluorescence Spectroscopy and Extended X‑ray Absorption Fine Structure Spectroscopy Study on the Complexation of Trivalent Actinides with Chloride at T = 25–200 °C

The complexation of trivalent actinides (An(III)) with chloride is studied in the temperature range from 25 to 200 °C by spectroscopic methods. Time-resolved laser fluorescence spectroscopy (TRLFS) is applied to determine the thermodynamic data of Cm(III)–Cl– complexes, while extended X-ray absorpti...

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Veröffentlicht in:Inorganic chemistry 2014-01, Vol.53 (2), p.1062-1069
Hauptverfasser: Skerencak-Frech, Andrej, Fröhlich, Daniel R, Rothe, Jörg, Dardenne, Kathy, Panak, Petra J
Format: Artikel
Sprache:eng
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