Hollow metal–organic framework polyhedra synthesized by a CO2–ionic liquid interfacial templating route
•The hollow MOF polyhedra were prepared by a CO2–ionic liquid (IL) interface route.•The hollow MOF polyhedra showed applications in gas separation and catalysis.•The CO2–IL interface templating route can be applied to synthesize other MOFs. We proposed for the first time a CO2–ionic liquid (IL) inte...
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| Veröffentlicht in: | Journal of colloid and interface science 2014-02, Vol.416 (416), p.198-204 |
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| container_title | Journal of colloid and interface science |
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| creator | Peng, Li Zhang, Jianling Li, Jianshen Han, Buxing Xue, Zhimin Zhang, Binbin Shi, Jinghua Yang, Guanying |
| description | •The hollow MOF polyhedra were prepared by a CO2–ionic liquid (IL) interface route.•The hollow MOF polyhedra showed applications in gas separation and catalysis.•The CO2–IL interface templating route can be applied to synthesize other MOFs.
We proposed for the first time a CO2–ionic liquid (IL) interfacial templating route for the production of hollow MOF microparticles. By adding the gaseous CO2 into IL phase under stirring, a large number of CO2 bubbles are generated, which provide numerous CO2–IL interfaces, serving as the nucleation or agglomeration centers for the MOF nanocrystals. By this strategy, the hollow and mesoporous Zn–BTC (BTC: 1,3,5-benzenetricarboxylic) tetrahedroids were fabricated. The morphologies of the Zn–BTC polyhedra can be easily controlled by CO2 pressure. The as-synthesized Zn–BTC hollow microparticles have shown potential applications in gas separation and catalysis. Furthermore, the CO2–IL interface templating approach has been successfully applied to the fabrication of microsized Zn–BDC (BDC: 1,4-benzenedicarboxylic) hollow prisms. |
| doi_str_mv | 10.1016/j.jcis.2013.10.041 |
| format | Article |
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We proposed for the first time a CO2–ionic liquid (IL) interfacial templating route for the production of hollow MOF microparticles. By adding the gaseous CO2 into IL phase under stirring, a large number of CO2 bubbles are generated, which provide numerous CO2–IL interfaces, serving as the nucleation or agglomeration centers for the MOF nanocrystals. By this strategy, the hollow and mesoporous Zn–BTC (BTC: 1,3,5-benzenetricarboxylic) tetrahedroids were fabricated. The morphologies of the Zn–BTC polyhedra can be easily controlled by CO2 pressure. The as-synthesized Zn–BTC hollow microparticles have shown potential applications in gas separation and catalysis. Furthermore, the CO2–IL interface templating approach has been successfully applied to the fabrication of microsized Zn–BDC (BDC: 1,4-benzenedicarboxylic) hollow prisms.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2013.10.041</identifier><identifier>PMID: 24370422</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>Carbon Dioxide - chemistry ; Catalysis ; Catalyst ; Chemistry ; Exact sciences and technology ; Gas separation ; Gas–ionic liquid interface ; General and physical chemistry ; Hollow polyhedra ; Ionic Liquids - chemistry ; Metal–organic framework ; Microscopy, Electron, Scanning ; Nanoparticles - chemistry ; Nanoparticles - ultrastructure ; Particle Size ; Phthalic Acids - chemistry ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Tricarboxylic Acids - chemistry ; Zinc - chemistry</subject><ispartof>Journal of colloid and interface science, 2014-02, Vol.416 (416), p.198-204</ispartof><rights>2013 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c452t-4ccdf9877773480751a8c2d25f881188b858b67515d18860d79b52c4b86789433</citedby><cites>FETCH-LOGICAL-c452t-4ccdf9877773480751a8c2d25f881188b858b67515d18860d79b52c4b86789433</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S002197971300948X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28245199$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24370422$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Peng, Li</creatorcontrib><creatorcontrib>Zhang, Jianling</creatorcontrib><creatorcontrib>Li, Jianshen</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><creatorcontrib>Xue, Zhimin</creatorcontrib><creatorcontrib>Zhang, Binbin</creatorcontrib><creatorcontrib>Shi, Jinghua</creatorcontrib><creatorcontrib>Yang, Guanying</creatorcontrib><title>Hollow metal–organic framework polyhedra synthesized by a CO2–ionic liquid interfacial templating route</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>•The hollow MOF polyhedra were prepared by a CO2–ionic liquid (IL) interface route.•The hollow MOF polyhedra showed applications in gas separation and catalysis.•The CO2–IL interface templating route can be applied to synthesize other MOFs.
We proposed for the first time a CO2–ionic liquid (IL) interfacial templating route for the production of hollow MOF microparticles. By adding the gaseous CO2 into IL phase under stirring, a large number of CO2 bubbles are generated, which provide numerous CO2–IL interfaces, serving as the nucleation or agglomeration centers for the MOF nanocrystals. By this strategy, the hollow and mesoporous Zn–BTC (BTC: 1,3,5-benzenetricarboxylic) tetrahedroids were fabricated. The morphologies of the Zn–BTC polyhedra can be easily controlled by CO2 pressure. The as-synthesized Zn–BTC hollow microparticles have shown potential applications in gas separation and catalysis. Furthermore, the CO2–IL interface templating approach has been successfully applied to the fabrication of microsized Zn–BDC (BDC: 1,4-benzenedicarboxylic) hollow prisms.</description><subject>Carbon Dioxide - chemistry</subject><subject>Catalysis</subject><subject>Catalyst</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Gas separation</subject><subject>Gas–ionic liquid interface</subject><subject>General and physical chemistry</subject><subject>Hollow polyhedra</subject><subject>Ionic Liquids - chemistry</subject><subject>Metal–organic framework</subject><subject>Microscopy, Electron, Scanning</subject><subject>Nanoparticles - chemistry</subject><subject>Nanoparticles - ultrastructure</subject><subject>Particle Size</subject><subject>Phthalic Acids - chemistry</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Tricarboxylic Acids - chemistry</subject><subject>Zinc - chemistry</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kMFuFCEcxonR2LX6Ah4MFxMvswIDCyRezEatSZNe9EwY-E_Llhm2MNNmPfkOvqFPIuOuPcqF8OX3fSE_hF5TsqaEbt7v1jsXypoR2tZgTTh9glaUaNFIStqnaEUIo42WWp6hF6XsCKFUCP0cnTHeSsIZW6HbixRjesADTDb-_vkr5Ws7Bof7bAd4SPkW71M83IDPFpfDON1ACT_A4-6ALd5esVoJaSnEcDcHj8M4Qe6tCzbiCYZ9tFMYr3FO8wQv0bPexgKvTvc5-v7507ftRXN59eXr9uNl47hgU8Od871Wsp6WKyIFtcoxz0SvFKVKdUqoblNj4etrQ7zUnWCOd2ojleZte47eHXf3Od3NUCYzhOIgRjtCmouhXBOpWvIXZUfU5VRKht7scxhsPhhKzCLZ7Mwi2SySl6xKrqU3p_25G8A_Vv5ZrcDbE2CLs7G6HJeNR04xLqjWlftw5KDauA-QTXEBRgc-ZHCT8Sn87x9_ABqnnGg</recordid><startdate>20140215</startdate><enddate>20140215</enddate><creator>Peng, Li</creator><creator>Zhang, Jianling</creator><creator>Li, Jianshen</creator><creator>Han, Buxing</creator><creator>Xue, Zhimin</creator><creator>Zhang, Binbin</creator><creator>Shi, Jinghua</creator><creator>Yang, Guanying</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140215</creationdate><title>Hollow metal–organic framework polyhedra synthesized by a CO2–ionic liquid interfacial templating route</title><author>Peng, Li ; Zhang, Jianling ; Li, Jianshen ; Han, Buxing ; Xue, Zhimin ; Zhang, Binbin ; Shi, Jinghua ; Yang, Guanying</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c452t-4ccdf9877773480751a8c2d25f881188b858b67515d18860d79b52c4b86789433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Carbon Dioxide - chemistry</topic><topic>Catalysis</topic><topic>Catalyst</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Gas separation</topic><topic>Gas–ionic liquid interface</topic><topic>General and physical chemistry</topic><topic>Hollow polyhedra</topic><topic>Ionic Liquids - chemistry</topic><topic>Metal–organic framework</topic><topic>Microscopy, Electron, Scanning</topic><topic>Nanoparticles - chemistry</topic><topic>Nanoparticles - ultrastructure</topic><topic>Particle Size</topic><topic>Phthalic Acids - chemistry</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Tricarboxylic Acids - chemistry</topic><topic>Zinc - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Li</creatorcontrib><creatorcontrib>Zhang, Jianling</creatorcontrib><creatorcontrib>Li, Jianshen</creatorcontrib><creatorcontrib>Han, Buxing</creatorcontrib><creatorcontrib>Xue, Zhimin</creatorcontrib><creatorcontrib>Zhang, Binbin</creatorcontrib><creatorcontrib>Shi, Jinghua</creatorcontrib><creatorcontrib>Yang, Guanying</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Li</au><au>Zhang, Jianling</au><au>Li, Jianshen</au><au>Han, Buxing</au><au>Xue, Zhimin</au><au>Zhang, Binbin</au><au>Shi, Jinghua</au><au>Yang, Guanying</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hollow metal–organic framework polyhedra synthesized by a CO2–ionic liquid interfacial templating route</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2014-02-15</date><risdate>2014</risdate><volume>416</volume><issue>416</issue><spage>198</spage><epage>204</epage><pages>198-204</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>•The hollow MOF polyhedra were prepared by a CO2–ionic liquid (IL) interface route.•The hollow MOF polyhedra showed applications in gas separation and catalysis.•The CO2–IL interface templating route can be applied to synthesize other MOFs.
We proposed for the first time a CO2–ionic liquid (IL) interfacial templating route for the production of hollow MOF microparticles. By adding the gaseous CO2 into IL phase under stirring, a large number of CO2 bubbles are generated, which provide numerous CO2–IL interfaces, serving as the nucleation or agglomeration centers for the MOF nanocrystals. By this strategy, the hollow and mesoporous Zn–BTC (BTC: 1,3,5-benzenetricarboxylic) tetrahedroids were fabricated. The morphologies of the Zn–BTC polyhedra can be easily controlled by CO2 pressure. The as-synthesized Zn–BTC hollow microparticles have shown potential applications in gas separation and catalysis. Furthermore, the CO2–IL interface templating approach has been successfully applied to the fabrication of microsized Zn–BDC (BDC: 1,4-benzenedicarboxylic) hollow prisms.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>24370422</pmid><doi>10.1016/j.jcis.2013.10.041</doi><tpages>7</tpages></addata></record> |
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| subjects | Carbon Dioxide - chemistry Catalysis Catalyst Chemistry Exact sciences and technology Gas separation Gas–ionic liquid interface General and physical chemistry Hollow polyhedra Ionic Liquids - chemistry Metal–organic framework Microscopy, Electron, Scanning Nanoparticles - chemistry Nanoparticles - ultrastructure Particle Size Phthalic Acids - chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tricarboxylic Acids - chemistry Zinc - chemistry |
| title | Hollow metal–organic framework polyhedra synthesized by a CO2–ionic liquid interfacial templating route |
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