Ammonia-Rich High-Temperature Superconducting Intercalates of Iron Selenide Revealed through Time-Resolved in Situ X‑ray and Neutron Diffraction

Ammonia-Rich High-Temperature Superconducting Intercalates of Iron Selenide Revealed through Time-Resolved in Situ X‑ray and Neutron Diffraction

The development of a technique for following in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ray diffraction methods, reveals high-temperature superconducting ammonia-rich intercalates of iron selenide which reversibly absorb and desorb ammonia around ambie...

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Veröffentlicht in:Journal of the American Chemical Society 2014-01, Vol.136 (2), p.630-633
Hauptverfasser: Sedlmaier, Stefan J, Cassidy, Simon J, Morris, Richard G, Drakopoulos, Michael, Reinhard, Christina, Moorhouse, Saul J, O’Hare, Dermot, Manuel, Pascal, Khalyavin, Dmitry, Clarke, Simon J
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container_end_page 633
container_issue 2
container_start_page 630
container_title Journal of the American Chemical Society
container_volume 136
creator Sedlmaier, Stefan J
Cassidy, Simon J
Morris, Richard G
Drakopoulos, Michael
Reinhard, Christina
Moorhouse, Saul J
O’Hare, Dermot
Manuel, Pascal
Khalyavin, Dmitry
Clarke, Simon J
description The development of a technique for following in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ray diffraction methods, reveals high-temperature superconducting ammonia-rich intercalates of iron selenide which reversibly absorb and desorb ammonia around ambient temperatures.
doi_str_mv 10.1021/ja411624q
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title Ammonia-Rich High-Temperature Superconducting Intercalates of Iron Selenide Revealed through Time-Resolved in Situ X‑ray and Neutron Diffraction
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