Stroboscopic microscopy-direct imaging of structure development and phase separation during spin-coating

ABSTRACT Spin‐coated polymer blends possess a rich variety of accessible non‐equilibrium morphologies, formed through a process of phase separation and self‐assembly, the complexities of which remain incompletely understood. The technique of stroboscopic microscopy has now been developed to allow di...

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Veröffentlicht in:Journal of polymer science. Part B, Polymer physics Polymer physics, 2014-01, Vol.52 (1), p.17-25
Hauptverfasser: Toolan, Daniel T. W., Hodgkinson, Richard, Howse, Jonathan R.
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container_title Journal of polymer science. Part B, Polymer physics
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creator Toolan, Daniel T. W.
Hodgkinson, Richard
Howse, Jonathan R.
description ABSTRACT Spin‐coated polymer blends possess a rich variety of accessible non‐equilibrium morphologies, formed through a process of phase separation and self‐assembly, the complexities of which remain incompletely understood. The technique of stroboscopic microscopy has now been developed to allow direct observations of microscopic and mesoscopic morphological development during spin‐coating and has afforded unequivocal information regarding morphological development. The technique so far has three modes of operation providing information on topographical, compositional, and crystal development. In this review, we look at the technique's development, its applications and comment on the future potential for this technique. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 17–25 Spin‐coated polymer blends possess a rich variety of accessible nonequilibrium morphologies, formed through a process of phase separation and self‐assembly, the complexities of which still remain poorly understood. The technique of stroboscopic microscopy has now been developed to allow direct observations of microscopic and mesoscopic morphological development during spin‐coating and has afforded unequivocal information regarding morphological development. The technique so far has three modes of operation providing information on topographical, compositional, and crystal development and each are discussed within this review article.
doi_str_mv 10.1002/polb.23410
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source Wiley Online Library Journals Frontfile Complete
subjects Accessibility
Applied sciences
blends
block copolymers
crystallization
Exact sciences and technology
fluorescence
in situ studies
Machinery and processing
microstructure
Miscellaneous
nanotechnology
phase separation
Plastics
polymer blends
Polymer industry, paints, wood
spin-coating
Technology of polymers
title Stroboscopic microscopy-direct imaging of structure development and phase separation during spin-coating
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