Robust solid polymer electrolyte for conducting IPN actuators

Robust solid polymer electrolyte for conducting IPN actuators

Interpenetrating polymer networks (IPNs) based on nitrile butadiene rubber (NBR) as first component and poly(ethylene oxide) (PEO) as second component were synthesized and used as a solid polymer electrolyte film in the design of a mechanically robust conducting IPN actuator. IPN mechanical properti...

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Veröffentlicht in:Smart materials and structures 2013-10, Vol.22 (10), p.104005-1-11
Hauptverfasser: Festin, Nicolas, Maziz, Ali, Plesse, Cédric, Teyssié, Dominique, Chevrot, Claude, Vidal, Frédéric
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Actuators
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container_end_page 1-11
container_issue 10
container_start_page 104005
container_title Smart materials and structures
container_volume 22
creator Festin, Nicolas
Maziz, Ali
Plesse, Cédric
Teyssié, Dominique
Chevrot, Claude
Vidal, Frédéric
description Interpenetrating polymer networks (IPNs) based on nitrile butadiene rubber (NBR) as first component and poly(ethylene oxide) (PEO) as second component were synthesized and used as a solid polymer electrolyte film in the design of a mechanically robust conducting IPN actuator. IPN mechanical properties and morphologies were mainly investigated by dynamic mechanical analysis and transmission electron microscopy. For 1-ethyl-3-methylimidazolium bis-(trifluoromethylsulfonyl)-imide (EMITFSI) swollen IPNs, conductivity values are close to 1 × 10−3 S cm−1 at 25 ° C. Conducting IPN actuators have been synthesized by chemical polymerization of 3,4-ethylenedioxythiophene (EDOT) within the PEO NBR IPN. A pseudo-trilayer configuration has been obtained with PEO NBR IPN sandwiched between two interpenetrated PEDOT electrodes. The robust conducting IPN actuators showed a free strain of 2.4% and a blocking force of 30 mN for a low applied potential of ±2 V.
doi_str_mv 10.1088/0964-1726/22/10/104005
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title Robust solid polymer electrolyte for conducting IPN actuators
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