Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents

The removal of single heavy metals Co and Zn from aqueous solutions using various low-cost adsorbents (Fe 2O 3, Fe 3O 4, FeS, steel wool, Mg pellets, Cu pellets, Zn pellets, Al pellets, Fe pellets, coal, and GAC) was investigated. Experiments were performed at different solution pH values (1.5–9) an...

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Veröffentlicht in:Journal of hazardous materials 2003-08, Vol.102 (2), p.291-302
Hauptverfasser: Wang, Yuen-Hua, Lin, Su-Hsia, Juang, Ruey-Shin
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container_title Journal of hazardous materials
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creator Wang, Yuen-Hua
Lin, Su-Hsia
Juang, Ruey-Shin
description The removal of single heavy metals Co and Zn from aqueous solutions using various low-cost adsorbents (Fe 2O 3, Fe 3O 4, FeS, steel wool, Mg pellets, Cu pellets, Zn pellets, Al pellets, Fe pellets, coal, and GAC) was investigated. Experiments were performed at different solution pH values (1.5–9) and metal concentrations (0.67–333 mg/l). The effect of solution pH on metal adsorption using Fe 2O 3 and Fe 3O 4 was significant, but was negligibly small using steel wool, Mg pellets, Fe pellets, and Al pellets over the entire pH range. Steel wool and Mg pellets were the most excellent adsorbents; for example, the removal of Zn and Co from dilute solutions (
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Experiments were performed at different solution pH values (1.5–9) and metal concentrations (0.67–333 mg/l). The effect of solution pH on metal adsorption using Fe 2O 3 and Fe 3O 4 was significant, but was negligibly small using steel wool, Mg pellets, Fe pellets, and Al pellets over the entire pH range. Steel wool and Mg pellets were the most excellent adsorbents; for example, the removal of Zn and Co from dilute solutions (&lt;35 mg/l) was greater than 94% at an adsorbent dose of 1.7 g/l. A mass transfer model, which involves two parameters τ (50% breakthrough time) and k (proportionality constant), was proposed to describe breakthrough data of Co in the fixed beds packed with steel wool and Mg pellets. The calculated breakthrough curves agreed well with the measured data (standard deviation &lt; 6%). The value of τ decreased with increasing the flow rate. 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Experiments were performed at different solution pH values (1.5–9) and metal concentrations (0.67–333 mg/l). The effect of solution pH on metal adsorption using Fe 2O 3 and Fe 3O 4 was significant, but was negligibly small using steel wool, Mg pellets, Fe pellets, and Al pellets over the entire pH range. Steel wool and Mg pellets were the most excellent adsorbents; for example, the removal of Zn and Co from dilute solutions (&lt;35 mg/l) was greater than 94% at an adsorbent dose of 1.7 g/l. A mass transfer model, which involves two parameters τ (50% breakthrough time) and k (proportionality constant), was proposed to describe breakthrough data of Co in the fixed beds packed with steel wool and Mg pellets. The calculated breakthrough curves agreed well with the measured data (standard deviation &lt; 6%). The value of τ decreased with increasing the flow rate. The effects of flow rates on the value of k and adsorption capacity are discussed.</description><subject>Adsorption</subject><subject>Applied sciences</subject><subject>Breakthrough curve</subject><subject>Chemistry</subject><subject>Cobalt - isolation &amp; purification</subject><subject>Cost Control</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>General purification processes</subject><subject>Heavy metals</subject><subject>Hydrogen-Ion Concentration</subject><subject>Low-cost adsorbents</subject><subject>Pollution</subject><subject>Removal</subject><subject>Solid-liquid interface</subject><subject>Surface physical chemistry</subject><subject>Wastewaters</subject><subject>Water Movements</subject><subject>Water Pollutants - isolation &amp; purification</subject><subject>Water Purification - economics</subject><subject>Water Purification - methods</subject><subject>Water treatment and pollution</subject><subject>Zinc - isolation &amp; 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Lin, Su-Hsia ; Juang, Ruey-Shin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c525t-93608ad42f47b77f3ba5b5dbffad6f3564a6e2ac689ee5e9eb302fa1a80d21723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Adsorption</topic><topic>Applied sciences</topic><topic>Breakthrough curve</topic><topic>Chemistry</topic><topic>Cobalt - isolation &amp; purification</topic><topic>Cost Control</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>General purification processes</topic><topic>Heavy metals</topic><topic>Hydrogen-Ion Concentration</topic><topic>Low-cost adsorbents</topic><topic>Pollution</topic><topic>Removal</topic><topic>Solid-liquid interface</topic><topic>Surface physical chemistry</topic><topic>Wastewaters</topic><topic>Water Movements</topic><topic>Water Pollutants - isolation &amp; purification</topic><topic>Water Purification - economics</topic><topic>Water Purification - methods</topic><topic>Water treatment and pollution</topic><topic>Zinc - isolation &amp; purification</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yuen-Hua</creatorcontrib><creatorcontrib>Lin, Su-Hsia</creatorcontrib><creatorcontrib>Juang, Ruey-Shin</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yuen-Hua</au><au>Lin, Su-Hsia</au><au>Juang, Ruey-Shin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2003-08-29</date><risdate>2003</risdate><volume>102</volume><issue>2</issue><spage>291</spage><epage>302</epage><pages>291-302</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>The removal of single heavy metals Co and Zn from aqueous solutions using various low-cost adsorbents (Fe 2O 3, Fe 3O 4, FeS, steel wool, Mg pellets, Cu pellets, Zn pellets, Al pellets, Fe pellets, coal, and GAC) was investigated. Experiments were performed at different solution pH values (1.5–9) and metal concentrations (0.67–333 mg/l). The effect of solution pH on metal adsorption using Fe 2O 3 and Fe 3O 4 was significant, but was negligibly small using steel wool, Mg pellets, Fe pellets, and Al pellets over the entire pH range. Steel wool and Mg pellets were the most excellent adsorbents; for example, the removal of Zn and Co from dilute solutions (&lt;35 mg/l) was greater than 94% at an adsorbent dose of 1.7 g/l. A mass transfer model, which involves two parameters τ (50% breakthrough time) and k (proportionality constant), was proposed to describe breakthrough data of Co in the fixed beds packed with steel wool and Mg pellets. The calculated breakthrough curves agreed well with the measured data (standard deviation &lt; 6%). The value of τ decreased with increasing the flow rate. The effects of flow rates on the value of k and adsorption capacity are discussed.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>12972244</pmid><doi>10.1016/S0304-3894(03)00218-8</doi><tpages>12</tpages></addata></record>
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subjects Adsorption
Applied sciences
Breakthrough curve
Chemistry
Cobalt - isolation & purification
Cost Control
Exact sciences and technology
General and physical chemistry
General purification processes
Heavy metals
Hydrogen-Ion Concentration
Low-cost adsorbents
Pollution
Removal
Solid-liquid interface
Surface physical chemistry
Wastewaters
Water Movements
Water Pollutants - isolation & purification
Water Purification - economics
Water Purification - methods
Water treatment and pollution
Zinc - isolation & purification
title Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents
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