Investigation the inhibitory action of novel diquaternary Schiff dibases on the acid dissolution of carbon steel in 1 M hydrochloric acid solution

Corrosion inhibition of four diquaternary N,N-pentane-2,4-diylidenedipyridin-4-amine (NDSI), N,N-(3-benzylidenepentane-2,4-diylidene)dipyridin-4-amine (NBDSI), N,N-[3-(4-methoxybenzylidene)pentane-2,4-diylidene]dipyridin-4-ami ne (NMDSI) and N,N-[3-(4-chlorobenzylidene)pentane-2,4-diylidene]dipyridi...

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Veröffentlicht in:Corrosion science 2012-12, Vol.65, p.77-86
Hauptverfasser: NEGM, N. A, BADR, E. A, AIAD, I. A, ZAKI, M. F, SAID, M. M
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container_start_page 77
container_title Corrosion science
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creator NEGM, N. A
BADR, E. A
AIAD, I. A
ZAKI, M. F
SAID, M. M
description Corrosion inhibition of four diquaternary N,N-pentane-2,4-diylidenedipyridin-4-amine (NDSI), N,N-(3-benzylidenepentane-2,4-diylidene)dipyridin-4-amine (NBDSI), N,N-[3-(4-methoxybenzylidene)pentane-2,4-diylidene]dipyridin-4-ami ne (NMDSI) and N,N-[3-(4-chlorobenzylidene)pentane-2,4-diylidene]dipyridin-4-amin e (NCDSI) on carbon steel was investigated by gravimetric measurements, polarisation and electrochemical impedance spectroscopy (EIS). The effect of concentration and immersion time was studied. The results show that the inhibitors are good inhibitor for corrosion reaction of carbon steel and obey Langmuir adsorption isotherm. Polarisation curves showed their behaviours as mixed-type inhibitors. EIS spectra exhibit one capacitive loop and confirm the inhibitive ability.
doi_str_mv 10.1016/j.corsci.2012.08.004
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Carbon steels
Corrosion
Corrosion environments
Corrosion inhibitors
Corrosion prevention
Electrochemical impedance spectroscopy
Exact sciences and technology
Hydrochloric acid
Inhibition
Isotherms
Metals. Metallurgy
Spectra
title Investigation the inhibitory action of novel diquaternary Schiff dibases on the acid dissolution of carbon steel in 1 M hydrochloric acid solution
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