Formation Mechanisms of Ti3SnC2 Nanolaminate Carbide Using Fe as Additive
Reactive sintering of 3Ti:Sn:2C and 3Ti:Sn:2C:0.6Fe powder mixtures is studied in the temperature range 510°C–1200°C under argon. It is demonstrated that the recently discovered Ti3SnC2 phase is formed, provided that Fe is added to a 3Ti:Sn:2C reactant mixture within the synthesis conditions used. U...
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| Veröffentlicht in: | Journal of the American Ceramic Society 2013-10, Vol.96 (10), p.3239-3242 |
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| container_title | Journal of the American Ceramic Society |
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| creator | Ouabadi, Nadia Gauthier-Brunet, Véronique Cabioc'h, Thierry Bei, Guo-Ping Dubois, Sylvain |
| description | Reactive sintering of 3Ti:Sn:2C and 3Ti:Sn:2C:0.6Fe powder mixtures is studied in the temperature range 510°C–1200°C under argon. It is demonstrated that the recently discovered Ti3SnC2 phase is formed, provided that Fe is added to a 3Ti:Sn:2C reactant mixture within the synthesis conditions used. Using dilatometric and X‐Ray diffraction analyses, the formation mechanism of Ti3SnC2 is discussed. Results show that at low temperature (about 510°C), tin is consumed to form FexSny intermetallics. At high temperature (about 1060°C), tin is newly available to form Ti3SnC2 due to the melting of FexSny. Then, the intermediate phases, TiC and Ti2SnC, and/or Ti5Sn3, TiC, C, and Ti are dissolved in the (Fe + Sn) liquid phase and Ti3SnC2 very likely precipitate from the melt. The second part of the study deals with the optimization of the Fe content in the initial 3Ti:Sn:2C reactant powder mixture to synthesize samples with larger Ti3SnC2 content by hot isostatic pressing. |
| doi_str_mv | 10.1111/jace.12427 |
| format | Article |
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It is demonstrated that the recently discovered Ti3SnC2 phase is formed, provided that Fe is added to a 3Ti:Sn:2C reactant mixture within the synthesis conditions used. Using dilatometric and X‐Ray diffraction analyses, the formation mechanism of Ti3SnC2 is discussed. Results show that at low temperature (about 510°C), tin is consumed to form FexSny intermetallics. At high temperature (about 1060°C), tin is newly available to form Ti3SnC2 due to the melting of FexSny. Then, the intermediate phases, TiC and Ti2SnC, and/or Ti5Sn3, TiC, C, and Ti are dissolved in the (Fe + Sn) liquid phase and Ti3SnC2 very likely precipitate from the melt. The second part of the study deals with the optimization of the Fe content in the initial 3Ti:Sn:2C reactant powder mixture to synthesize samples with larger Ti3SnC2 content by hot isostatic pressing.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.12427</identifier><language>eng</language><publisher>Blackwell Publishing Ltd</publisher><subject>Consumption ; Dissolution ; Intermetallics ; Iron ; Nanomaterials ; Nanostructure ; Reactive sintering ; Tin ; Titanium</subject><ispartof>Journal of the American Ceramic Society, 2013-10, Vol.96 (10), p.3239-3242</ispartof><rights>2013 The American Ceramic Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fjace.12427$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fjace.12427$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><contributor>Zhou, Y.</contributor><creatorcontrib>Ouabadi, Nadia</creatorcontrib><creatorcontrib>Gauthier-Brunet, Véronique</creatorcontrib><creatorcontrib>Cabioc'h, Thierry</creatorcontrib><creatorcontrib>Bei, Guo-Ping</creatorcontrib><creatorcontrib>Dubois, Sylvain</creatorcontrib><title>Formation Mechanisms of Ti3SnC2 Nanolaminate Carbide Using Fe as Additive</title><title>Journal of the American Ceramic Society</title><addtitle>J. Am. Ceram. Soc</addtitle><description>Reactive sintering of 3Ti:Sn:2C and 3Ti:Sn:2C:0.6Fe powder mixtures is studied in the temperature range 510°C–1200°C under argon. It is demonstrated that the recently discovered Ti3SnC2 phase is formed, provided that Fe is added to a 3Ti:Sn:2C reactant mixture within the synthesis conditions used. Using dilatometric and X‐Ray diffraction analyses, the formation mechanism of Ti3SnC2 is discussed. Results show that at low temperature (about 510°C), tin is consumed to form FexSny intermetallics. At high temperature (about 1060°C), tin is newly available to form Ti3SnC2 due to the melting of FexSny. Then, the intermediate phases, TiC and Ti2SnC, and/or Ti5Sn3, TiC, C, and Ti are dissolved in the (Fe + Sn) liquid phase and Ti3SnC2 very likely precipitate from the melt. The second part of the study deals with the optimization of the Fe content in the initial 3Ti:Sn:2C reactant powder mixture to synthesize samples with larger Ti3SnC2 content by hot isostatic pressing.</description><subject>Consumption</subject><subject>Dissolution</subject><subject>Intermetallics</subject><subject>Iron</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Reactive sintering</subject><subject>Tin</subject><subject>Titanium</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNo9kE1PwkAQhjdGExG9-Av26KW4n93tEStFDOIBiN42Q7vVxX5gt6j8ewsY5zIzyfu8hweha0oGtJvbNaR2QJlg6gT1qJQ0YBENT1GPEMICpRk5Rxfer7uXRlr00CSpmxJaV1f4yabvUDlfelzneOH4vIoZnkFVF1C6ClqLY2hWLrN46V31hhOLweNhlrnWfdlLdJZD4e3V3-6jZTJaxA_B9Hk8iYfTwLFQqEDblaSUK2pBA5dZKjIWRpwLxRjjOV8JoUFayJmOVpSEGYM0ZDrPJVNWEs376ObYu2nqz631rSmdT21RQGXrrTdUhEJK3pV1UXqMfrvC7symcSU0O0OJ2csye1nmIMs8DuPR4eqY4Mg439qffwaaDxMqrqR5mY3NXTy_T-ZRZF75LwcabAo</recordid><startdate>201310</startdate><enddate>201310</enddate><creator>Ouabadi, Nadia</creator><creator>Gauthier-Brunet, Véronique</creator><creator>Cabioc'h, Thierry</creator><creator>Bei, Guo-Ping</creator><creator>Dubois, Sylvain</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201310</creationdate><title>Formation Mechanisms of Ti3SnC2 Nanolaminate Carbide Using Fe as Additive</title><author>Ouabadi, Nadia ; Gauthier-Brunet, Véronique ; Cabioc'h, Thierry ; Bei, Guo-Ping ; Dubois, Sylvain</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i2647-8eb511371ea8a35dc4d26933472223f3b448a5eaf289b106d2ac628ff527e5083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Consumption</topic><topic>Dissolution</topic><topic>Intermetallics</topic><topic>Iron</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Reactive sintering</topic><topic>Tin</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ouabadi, Nadia</creatorcontrib><creatorcontrib>Gauthier-Brunet, Véronique</creatorcontrib><creatorcontrib>Cabioc'h, Thierry</creatorcontrib><creatorcontrib>Bei, Guo-Ping</creatorcontrib><creatorcontrib>Dubois, Sylvain</creatorcontrib><collection>Istex</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ouabadi, Nadia</au><au>Gauthier-Brunet, Véronique</au><au>Cabioc'h, Thierry</au><au>Bei, Guo-Ping</au><au>Dubois, Sylvain</au><au>Zhou, Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation Mechanisms of Ti3SnC2 Nanolaminate Carbide Using Fe as Additive</atitle><jtitle>Journal of the American Ceramic Society</jtitle><addtitle>J. Am. Ceram. Soc</addtitle><date>2013-10</date><risdate>2013</risdate><volume>96</volume><issue>10</issue><spage>3239</spage><epage>3242</epage><pages>3239-3242</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>Reactive sintering of 3Ti:Sn:2C and 3Ti:Sn:2C:0.6Fe powder mixtures is studied in the temperature range 510°C–1200°C under argon. It is demonstrated that the recently discovered Ti3SnC2 phase is formed, provided that Fe is added to a 3Ti:Sn:2C reactant mixture within the synthesis conditions used. Using dilatometric and X‐Ray diffraction analyses, the formation mechanism of Ti3SnC2 is discussed. Results show that at low temperature (about 510°C), tin is consumed to form FexSny intermetallics. At high temperature (about 1060°C), tin is newly available to form Ti3SnC2 due to the melting of FexSny. Then, the intermediate phases, TiC and Ti2SnC, and/or Ti5Sn3, TiC, C, and Ti are dissolved in the (Fe + Sn) liquid phase and Ti3SnC2 very likely precipitate from the melt. The second part of the study deals with the optimization of the Fe content in the initial 3Ti:Sn:2C reactant powder mixture to synthesize samples with larger Ti3SnC2 content by hot isostatic pressing.</abstract><pub>Blackwell Publishing Ltd</pub><doi>10.1111/jace.12427</doi><tpages>4</tpages></addata></record> |
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| subjects | Consumption Dissolution Intermetallics Iron Nanomaterials Nanostructure Reactive sintering Tin Titanium |
| title | Formation Mechanisms of Ti3SnC2 Nanolaminate Carbide Using Fe as Additive |
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