One-pot myrtenol amination over Au nanoparticles supported on different metal oxides
•One-pot myrtenol amination over Au catalysts.•Different metal oxides as supports.•Products: biologically valuable compounds.•Correlation between support nature and catalytic performance.•The highest activity and selectivity in one-pot myrtenol amination with aniline over Au/ZrO2. The one-pot aminat...
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| Veröffentlicht in: | Applied catalysis. A, General General, 2013-08, Vol.464-465, p.348-356 |
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| container_title | Applied catalysis. A, General |
| container_volume | 464-465 |
| creator | Demidova, Yu.S. Simakova, I.L. Estrada, M. Beloshapkin, S. Suslov, E.V. Korchagina, D.V. Volcho, K.P. Salakhutdinov, N.F. Simakov, A.V. Murzin, D.Yu |
| description | •One-pot myrtenol amination over Au catalysts.•Different metal oxides as supports.•Products: biologically valuable compounds.•Correlation between support nature and catalytic performance.•The highest activity and selectivity in one-pot myrtenol amination with aniline over Au/ZrO2.
The one-pot amination of natural terpene alcohol (myrtenol, with a primary hydroxyl group) was studied over gold catalysts supported on different metal oxides such as ZrO2, MgO, Al2O3, CeO2, La2O3 using the equimolar amounts of substrates under nitrogen pressure. The synthesized catalysts were characterized by TEM, N2 adsorption techniques and XPS. The correlation between acid–base properties of support and catalytic performance was established. A nearly complete myrtenol conversion as well as the highest selectivity to secondary amine of about 52% were reached after 16h over Au/ZrO2 with both acidic and basic surface sites. |
| doi_str_mv | 10.1016/j.apcata.2013.06.013 |
| format | Article |
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The one-pot amination of natural terpene alcohol (myrtenol, with a primary hydroxyl group) was studied over gold catalysts supported on different metal oxides such as ZrO2, MgO, Al2O3, CeO2, La2O3 using the equimolar amounts of substrates under nitrogen pressure. The synthesized catalysts were characterized by TEM, N2 adsorption techniques and XPS. The correlation between acid–base properties of support and catalytic performance was established. A nearly complete myrtenol conversion as well as the highest selectivity to secondary amine of about 52% were reached after 16h over Au/ZrO2 with both acidic and basic surface sites.</description><identifier>ISSN: 0926-860X</identifier><identifier>EISSN: 1873-3875</identifier><identifier>DOI: 10.1016/j.apcata.2013.06.013</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Amination ; Catalysis ; Catalysts ; Gold ; Gold nanoparticles ; Hydroxyl groups ; Metal oxides ; Myrtenol ; One-pot ; Surface chemistry ; X-ray photoelectron spectroscopy ; Zirconium dioxide</subject><ispartof>Applied catalysis. A, General, 2013-08, Vol.464-465, p.348-356</ispartof><rights>2013 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-593387bb8ec6c804f75ac1e0daf403581568db6a5af65d87f56aa8ea196797f73</citedby><cites>FETCH-LOGICAL-c376t-593387bb8ec6c804f75ac1e0daf403581568db6a5af65d87f56aa8ea196797f73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0926860X13003438$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Demidova, Yu.S.</creatorcontrib><creatorcontrib>Simakova, I.L.</creatorcontrib><creatorcontrib>Estrada, M.</creatorcontrib><creatorcontrib>Beloshapkin, S.</creatorcontrib><creatorcontrib>Suslov, E.V.</creatorcontrib><creatorcontrib>Korchagina, D.V.</creatorcontrib><creatorcontrib>Volcho, K.P.</creatorcontrib><creatorcontrib>Salakhutdinov, N.F.</creatorcontrib><creatorcontrib>Simakov, A.V.</creatorcontrib><creatorcontrib>Murzin, D.Yu</creatorcontrib><title>One-pot myrtenol amination over Au nanoparticles supported on different metal oxides</title><title>Applied catalysis. A, General</title><description>•One-pot myrtenol amination over Au catalysts.•Different metal oxides as supports.•Products: biologically valuable compounds.•Correlation between support nature and catalytic performance.•The highest activity and selectivity in one-pot myrtenol amination with aniline over Au/ZrO2.
The one-pot amination of natural terpene alcohol (myrtenol, with a primary hydroxyl group) was studied over gold catalysts supported on different metal oxides such as ZrO2, MgO, Al2O3, CeO2, La2O3 using the equimolar amounts of substrates under nitrogen pressure. The synthesized catalysts were characterized by TEM, N2 adsorption techniques and XPS. The correlation between acid–base properties of support and catalytic performance was established. A nearly complete myrtenol conversion as well as the highest selectivity to secondary amine of about 52% were reached after 16h over Au/ZrO2 with both acidic and basic surface sites.</description><subject>Amination</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Gold</subject><subject>Gold nanoparticles</subject><subject>Hydroxyl groups</subject><subject>Metal oxides</subject><subject>Myrtenol</subject><subject>One-pot</subject><subject>Surface chemistry</subject><subject>X-ray photoelectron spectroscopy</subject><subject>Zirconium dioxide</subject><issn>0926-860X</issn><issn>1873-3875</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kDtrwzAUhUVpoWnaf9DBYxe7Umw9vBRC6AsCWVLoJm7kK1BwJFeSQ_vv65DOnc7yncO9HyH3jFaMMvG4r2AwkKFaUFZXVFRTXJAZU7IuayX5JZnRdiFKJejnNblJaU8pXTQtn5HtxmM5hFwcfmJGH_oCDs5DdsEX4YixWI6FBx8GiNmZHlORxmEIE9sVE9I5azGin_qYoS_Ct-sw3ZIrC33Cu7-ck4-X5-3qrVxvXt9Xy3Vpailyydt6um63U2iEUbSxkoNhSDuwDa25YlyobieAgxW8U9JyAaAQWCtkK62s5-ThvDvE8DViyvrgksG-B49hTJo1ouGcSXFCmzNqYkgpotVDdAeIP5pRfZKo9_osUZ8kair0FFPt6VzD6Y2jw6iTcegNdi6iyboL7v-BX_h_feU</recordid><startdate>20130815</startdate><enddate>20130815</enddate><creator>Demidova, Yu.S.</creator><creator>Simakova, I.L.</creator><creator>Estrada, M.</creator><creator>Beloshapkin, S.</creator><creator>Suslov, E.V.</creator><creator>Korchagina, D.V.</creator><creator>Volcho, K.P.</creator><creator>Salakhutdinov, N.F.</creator><creator>Simakov, A.V.</creator><creator>Murzin, D.Yu</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130815</creationdate><title>One-pot myrtenol amination over Au nanoparticles supported on different metal oxides</title><author>Demidova, Yu.S. ; Simakova, I.L. ; Estrada, M. ; Beloshapkin, S. ; Suslov, E.V. ; Korchagina, D.V. ; Volcho, K.P. ; Salakhutdinov, N.F. ; Simakov, A.V. ; Murzin, D.Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-593387bb8ec6c804f75ac1e0daf403581568db6a5af65d87f56aa8ea196797f73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Amination</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Gold</topic><topic>Gold nanoparticles</topic><topic>Hydroxyl groups</topic><topic>Metal oxides</topic><topic>Myrtenol</topic><topic>One-pot</topic><topic>Surface chemistry</topic><topic>X-ray photoelectron spectroscopy</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Demidova, Yu.S.</creatorcontrib><creatorcontrib>Simakova, I.L.</creatorcontrib><creatorcontrib>Estrada, M.</creatorcontrib><creatorcontrib>Beloshapkin, S.</creatorcontrib><creatorcontrib>Suslov, E.V.</creatorcontrib><creatorcontrib>Korchagina, D.V.</creatorcontrib><creatorcontrib>Volcho, K.P.</creatorcontrib><creatorcontrib>Salakhutdinov, N.F.</creatorcontrib><creatorcontrib>Simakov, A.V.</creatorcontrib><creatorcontrib>Murzin, D.Yu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. A, General</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Demidova, Yu.S.</au><au>Simakova, I.L.</au><au>Estrada, M.</au><au>Beloshapkin, S.</au><au>Suslov, E.V.</au><au>Korchagina, D.V.</au><au>Volcho, K.P.</au><au>Salakhutdinov, N.F.</au><au>Simakov, A.V.</au><au>Murzin, D.Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-pot myrtenol amination over Au nanoparticles supported on different metal oxides</atitle><jtitle>Applied catalysis. A, General</jtitle><date>2013-08-15</date><risdate>2013</risdate><volume>464-465</volume><spage>348</spage><epage>356</epage><pages>348-356</pages><issn>0926-860X</issn><eissn>1873-3875</eissn><abstract>•One-pot myrtenol amination over Au catalysts.•Different metal oxides as supports.•Products: biologically valuable compounds.•Correlation between support nature and catalytic performance.•The highest activity and selectivity in one-pot myrtenol amination with aniline over Au/ZrO2.
The one-pot amination of natural terpene alcohol (myrtenol, with a primary hydroxyl group) was studied over gold catalysts supported on different metal oxides such as ZrO2, MgO, Al2O3, CeO2, La2O3 using the equimolar amounts of substrates under nitrogen pressure. The synthesized catalysts were characterized by TEM, N2 adsorption techniques and XPS. The correlation between acid–base properties of support and catalytic performance was established. A nearly complete myrtenol conversion as well as the highest selectivity to secondary amine of about 52% were reached after 16h over Au/ZrO2 with both acidic and basic surface sites.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.apcata.2013.06.013</doi><tpages>9</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Amination Catalysis Catalysts Gold Gold nanoparticles Hydroxyl groups Metal oxides Myrtenol One-pot Surface chemistry X-ray photoelectron spectroscopy Zirconium dioxide |
| title | One-pot myrtenol amination over Au nanoparticles supported on different metal oxides |
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