Influence of co-existing alcohol on charge transfer of H(2) evolution under visible light with dye-sensitized nanocrystalline TiO(2)

The dye-sensitized nanocrystalline TiO(2) colloidal suspension in aqueous systems has been applied for H(2) evolution in the photocatalytic water splitting under visible irradiation. We have reported that the conversion efficiency is strongly influenced by the combination of dye-sensitizers and co-e...

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Veröffentlicht in:Applied catalysis. B, Environmental Environmental, 2013-09, Vol.140-141, p.406-411
Hauptverfasser: Maitani Masato, M, Zhan, Conghong, Mochizuki, Dai, Suzuki, Eiichi, Wada, Yuji
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container_title Applied catalysis. B, Environmental
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creator Maitani Masato, M
Zhan, Conghong
Mochizuki, Dai
Suzuki, Eiichi
Wada, Yuji
description The dye-sensitized nanocrystalline TiO(2) colloidal suspension in aqueous systems has been applied for H(2) evolution in the photocatalytic water splitting under visible irradiation. We have reported that the conversion efficiency is strongly influenced by the combination of dye-sensitizers and co-existing species in the suspension system. We herein analyze the fluorescence quenching of the dye-sensitized TiO(2) nanoparticles in the suspensions and photoelectrochemical properties of dye-sensitized nanoporous TiO(2) films. The combination of dye-sensitizers and co-existing species dominates the charge recombination resulting in significant differences in the efficiencies of the proton reduction into H(2).
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source Elsevier ScienceDirect Journals
subjects Charge
Charge transfer
Dyes
Evolution
Nanocrystals
Nanostructure
Reduction
Titanium dioxide
title Influence of co-existing alcohol on charge transfer of H(2) evolution under visible light with dye-sensitized nanocrystalline TiO(2)
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