Novel chitosan-ZnO based nanocomposites as luminescent tags for cellulosic materials
•We report the synthesis, characterization, and evaluation of the novel luminescent tagging nanocomposites.•Eu3+ doping of CS-ZnO-oleic leads to a remarkable increase in the visible photoluminescence intensity.•The prepared luminescent CS-ZnO nanomaterials were formulated in a printing paste and app...
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| Veröffentlicht in: | Carbohydrate polymers 2014, Vol.99, p.817-824 |
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| container_title | Carbohydrate polymers |
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| creator | Saeed, Saeed El-Sayed El-Molla, Mohamed M. Hassan, Mohammad L. Bakir, Esam Abdel-Mottaleb, Mohamed M.S. Abdel-Mottaleb, Mohamed S.A. |
| description | •We report the synthesis, characterization, and evaluation of the novel luminescent tagging nanocomposites.•Eu3+ doping of CS-ZnO-oleic leads to a remarkable increase in the visible photoluminescence intensity.•The prepared luminescent CS-ZnO nanomaterials were formulated in a printing paste and applied to different types of papers and textiles.•The synthesized highly luminescent CS-ZnO-oleic and highly luminescence CS-ZnO-oleic:Eu3+ nanocomposites are suitable for use as a printed security feature.
Novel chitosan-ZnO composites have been synthesized as luminescent taggants for cellulosic materials. The synthesized chitosan-ZnO nanospheres (CS-ZnO NS), chitosan-ZnO-oleic acid quantum dots (CS-ZnO-oleic QD) and chitosan-ZnO-oleic acid:Eu3+ doped nanorods (CS-ZnO-oleic:Eu3+ NR) were characterized by X-ray diffraction, photoluminescence spectroscopy, FTIR spectroscopy and transmission electron microscopy. The prepared luminescent CS-ZnO composites were used in printing paste and applied to different types of papers and textiles by using screen printing technique. The colorimetric values of the printed CS-ZnO-oleic acid and CS-ZnO-oleic:Eu3+ showed that printing caused slightly change in color values. Scanning electron microscopy images and color values of the printed surface showed that CS-ZnO-oleic QD and highly luminescence CS-ZnO-olic:Eu3+ NR are suitable for use as a printed security feature. |
| doi_str_mv | 10.1016/j.carbpol.2013.08.096 |
| format | Article |
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Novel chitosan-ZnO composites have been synthesized as luminescent taggants for cellulosic materials. The synthesized chitosan-ZnO nanospheres (CS-ZnO NS), chitosan-ZnO-oleic acid quantum dots (CS-ZnO-oleic QD) and chitosan-ZnO-oleic acid:Eu3+ doped nanorods (CS-ZnO-oleic:Eu3+ NR) were characterized by X-ray diffraction, photoluminescence spectroscopy, FTIR spectroscopy and transmission electron microscopy. The prepared luminescent CS-ZnO composites were used in printing paste and applied to different types of papers and textiles by using screen printing technique. The colorimetric values of the printed CS-ZnO-oleic acid and CS-ZnO-oleic:Eu3+ showed that printing caused slightly change in color values. Scanning electron microscopy images and color values of the printed surface showed that CS-ZnO-oleic QD and highly luminescence CS-ZnO-olic:Eu3+ NR are suitable for use as a printed security feature.</description><identifier>ISSN: 0144-8617</identifier><identifier>EISSN: 1879-1344</identifier><identifier>DOI: 10.1016/j.carbpol.2013.08.096</identifier><identifier>PMID: 24274574</identifier><identifier>CODEN: CAPOD8</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Cellulose ; Cellulose - chemistry ; Chitosan - chemistry ; Composites ; Eu3+ doped chitosan-ZnO ; Exact sciences and technology ; Forms of application and semi-finished materials ; Luminescence ; Luminescent Measurements ; Luminescent tags ; Microscopy, Electron, Transmission ; Nanocomposites ; Nanocomposites - chemistry ; Nanocomposites - ultrastructure ; Nanotubes - chemistry ; Oleic Acid - chemistry ; Polymer industry, paints, wood ; Printing ; Quantum Dots - chemistry ; Quantumdots ; Security features ; Spectroscopy, Fourier Transform Infrared ; Staining and Labeling - methods ; Technology of polymers ; Textiles ; X-Ray Diffraction ; Zinc Oxide - chemistry</subject><ispartof>Carbohydrate polymers, 2014, Vol.99, p.817-824</ispartof><rights>2013 Elsevier Ltd.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c461t-b31d79002457885b1b0045e5602e3a2a023ee4e693268202fbf05162e99c131a3</citedby><cites>FETCH-LOGICAL-c461t-b31d79002457885b1b0045e5602e3a2a023ee4e693268202fbf05162e99c131a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0144861713008801$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28031973$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24274574$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Saeed, Saeed El-Sayed</creatorcontrib><creatorcontrib>El-Molla, Mohamed M.</creatorcontrib><creatorcontrib>Hassan, Mohammad L.</creatorcontrib><creatorcontrib>Bakir, Esam</creatorcontrib><creatorcontrib>Abdel-Mottaleb, Mohamed M.S.</creatorcontrib><creatorcontrib>Abdel-Mottaleb, Mohamed S.A.</creatorcontrib><title>Novel chitosan-ZnO based nanocomposites as luminescent tags for cellulosic materials</title><title>Carbohydrate polymers</title><addtitle>Carbohydr Polym</addtitle><description>•We report the synthesis, characterization, and evaluation of the novel luminescent tagging nanocomposites.•Eu3+ doping of CS-ZnO-oleic leads to a remarkable increase in the visible photoluminescence intensity.•The prepared luminescent CS-ZnO nanomaterials were formulated in a printing paste and applied to different types of papers and textiles.•The synthesized highly luminescent CS-ZnO-oleic and highly luminescence CS-ZnO-oleic:Eu3+ nanocomposites are suitable for use as a printed security feature.
Novel chitosan-ZnO composites have been synthesized as luminescent taggants for cellulosic materials. The synthesized chitosan-ZnO nanospheres (CS-ZnO NS), chitosan-ZnO-oleic acid quantum dots (CS-ZnO-oleic QD) and chitosan-ZnO-oleic acid:Eu3+ doped nanorods (CS-ZnO-oleic:Eu3+ NR) were characterized by X-ray diffraction, photoluminescence spectroscopy, FTIR spectroscopy and transmission electron microscopy. The prepared luminescent CS-ZnO composites were used in printing paste and applied to different types of papers and textiles by using screen printing technique. The colorimetric values of the printed CS-ZnO-oleic acid and CS-ZnO-oleic:Eu3+ showed that printing caused slightly change in color values. Scanning electron microscopy images and color values of the printed surface showed that CS-ZnO-oleic QD and highly luminescence CS-ZnO-olic:Eu3+ NR are suitable for use as a printed security feature.</description><subject>Applied sciences</subject><subject>Cellulose</subject><subject>Cellulose - chemistry</subject><subject>Chitosan - chemistry</subject><subject>Composites</subject><subject>Eu3+ doped chitosan-ZnO</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Luminescence</subject><subject>Luminescent Measurements</subject><subject>Luminescent tags</subject><subject>Microscopy, Electron, Transmission</subject><subject>Nanocomposites</subject><subject>Nanocomposites - chemistry</subject><subject>Nanocomposites - ultrastructure</subject><subject>Nanotubes - chemistry</subject><subject>Oleic Acid - chemistry</subject><subject>Polymer industry, paints, wood</subject><subject>Printing</subject><subject>Quantum Dots - chemistry</subject><subject>Quantumdots</subject><subject>Security features</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Staining and Labeling - methods</subject><subject>Technology of polymers</subject><subject>Textiles</subject><subject>X-Ray Diffraction</subject><subject>Zinc Oxide - chemistry</subject><issn>0144-8617</issn><issn>1879-1344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkMFu1DAQhi0EokvhEUC-IHFJmLEdJzkhVBWKVNFLuXCxHGcCXiX2YieVeHu82gWOnctcvn_m18fYa4QaAfX7fe1sGg5xrgWgrKGroddP2A67tq9QKvWU7QCVqjqN7QV7kfMeymiE5-xCKNGqplU7dv81PtDM3U-_xmxD9T3c8cFmGnmwIbq4HGL2K2VuM5-3xQfKjsLKV_sj8ykm7miet7lAji92peTtnF-yZ1NZ9Oq8L9m3T9f3VzfV7d3nL1cfbyunNK7VIHFsewBRqnRdM-AAoBpqNAiSVlgQkkiR7qXQnQAxDRM0qAX1vUOJVl6yd6e7hxR_bZRXs_h8LGQDxS0bVFpguSzagjYn1KWYc6LJHJJfbPptEMxRqNmbs1BzFGqgM0Voyb05v9iGhcZ_qb8GC_D2DNjs7DwlG5zP_7kOJPatLNyHE0dFyIOnZLLzFByNPpFbzRj9I1X-AGHmleE</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Saeed, Saeed El-Sayed</creator><creator>El-Molla, Mohamed M.</creator><creator>Hassan, Mohammad L.</creator><creator>Bakir, Esam</creator><creator>Abdel-Mottaleb, Mohamed M.S.</creator><creator>Abdel-Mottaleb, Mohamed S.A.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>2014</creationdate><title>Novel chitosan-ZnO based nanocomposites as luminescent tags for cellulosic materials</title><author>Saeed, Saeed El-Sayed ; El-Molla, Mohamed M. ; Hassan, Mohammad L. ; Bakir, Esam ; Abdel-Mottaleb, Mohamed M.S. ; Abdel-Mottaleb, Mohamed S.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c461t-b31d79002457885b1b0045e5602e3a2a023ee4e693268202fbf05162e99c131a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Cellulose</topic><topic>Cellulose - chemistry</topic><topic>Chitosan - chemistry</topic><topic>Composites</topic><topic>Eu3+ doped chitosan-ZnO</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Luminescence</topic><topic>Luminescent Measurements</topic><topic>Luminescent tags</topic><topic>Microscopy, Electron, Transmission</topic><topic>Nanocomposites</topic><topic>Nanocomposites - chemistry</topic><topic>Nanocomposites - ultrastructure</topic><topic>Nanotubes - chemistry</topic><topic>Oleic Acid - chemistry</topic><topic>Polymer industry, paints, wood</topic><topic>Printing</topic><topic>Quantum Dots - chemistry</topic><topic>Quantumdots</topic><topic>Security features</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Staining and Labeling - methods</topic><topic>Technology of polymers</topic><topic>Textiles</topic><topic>X-Ray Diffraction</topic><topic>Zinc Oxide - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saeed, Saeed El-Sayed</creatorcontrib><creatorcontrib>El-Molla, Mohamed M.</creatorcontrib><creatorcontrib>Hassan, Mohammad L.</creatorcontrib><creatorcontrib>Bakir, Esam</creatorcontrib><creatorcontrib>Abdel-Mottaleb, Mohamed M.S.</creatorcontrib><creatorcontrib>Abdel-Mottaleb, Mohamed S.A.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Carbohydrate polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saeed, Saeed El-Sayed</au><au>El-Molla, Mohamed M.</au><au>Hassan, Mohammad L.</au><au>Bakir, Esam</au><au>Abdel-Mottaleb, Mohamed M.S.</au><au>Abdel-Mottaleb, Mohamed S.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel chitosan-ZnO based nanocomposites as luminescent tags for cellulosic materials</atitle><jtitle>Carbohydrate polymers</jtitle><addtitle>Carbohydr Polym</addtitle><date>2014</date><risdate>2014</risdate><volume>99</volume><spage>817</spage><epage>824</epage><pages>817-824</pages><issn>0144-8617</issn><eissn>1879-1344</eissn><coden>CAPOD8</coden><abstract>•We report the synthesis, characterization, and evaluation of the novel luminescent tagging nanocomposites.•Eu3+ doping of CS-ZnO-oleic leads to a remarkable increase in the visible photoluminescence intensity.•The prepared luminescent CS-ZnO nanomaterials were formulated in a printing paste and applied to different types of papers and textiles.•The synthesized highly luminescent CS-ZnO-oleic and highly luminescence CS-ZnO-oleic:Eu3+ nanocomposites are suitable for use as a printed security feature.
Novel chitosan-ZnO composites have been synthesized as luminescent taggants for cellulosic materials. The synthesized chitosan-ZnO nanospheres (CS-ZnO NS), chitosan-ZnO-oleic acid quantum dots (CS-ZnO-oleic QD) and chitosan-ZnO-oleic acid:Eu3+ doped nanorods (CS-ZnO-oleic:Eu3+ NR) were characterized by X-ray diffraction, photoluminescence spectroscopy, FTIR spectroscopy and transmission electron microscopy. The prepared luminescent CS-ZnO composites were used in printing paste and applied to different types of papers and textiles by using screen printing technique. The colorimetric values of the printed CS-ZnO-oleic acid and CS-ZnO-oleic:Eu3+ showed that printing caused slightly change in color values. Scanning electron microscopy images and color values of the printed surface showed that CS-ZnO-oleic QD and highly luminescence CS-ZnO-olic:Eu3+ NR are suitable for use as a printed security feature.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>24274574</pmid><doi>10.1016/j.carbpol.2013.08.096</doi><tpages>8</tpages></addata></record> |
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| ispartof | Carbohydrate polymers, 2014, Vol.99, p.817-824 |
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| subjects | Applied sciences Cellulose Cellulose - chemistry Chitosan - chemistry Composites Eu3+ doped chitosan-ZnO Exact sciences and technology Forms of application and semi-finished materials Luminescence Luminescent Measurements Luminescent tags Microscopy, Electron, Transmission Nanocomposites Nanocomposites - chemistry Nanocomposites - ultrastructure Nanotubes - chemistry Oleic Acid - chemistry Polymer industry, paints, wood Printing Quantum Dots - chemistry Quantumdots Security features Spectroscopy, Fourier Transform Infrared Staining and Labeling - methods Technology of polymers Textiles X-Ray Diffraction Zinc Oxide - chemistry |
| title | Novel chitosan-ZnO based nanocomposites as luminescent tags for cellulosic materials |
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