1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents

1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents

The first synthesis of 1,4,7-tri-tert-butyl-1,4,7-triazacyclononane ( t Bu3tacn) and its adamantyl analog Ad3tacn are described. CrII, MnII, FeII, CoII, NiII, and CuI compounds of t Bu3tacn are reported: the steric properties of this ligand enforce four-coordinate geometries except in the case of fi...

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Veröffentlicht in:Inorganic chemistry 2013-11, Vol.52 (22), p.13282-13287
Hauptverfasser: Thangavel, Arumugam, Wieliczko, Marika, Bacsa, John, Scarborough, Christopher C
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container_title Inorganic chemistry
container_volume 52
creator Thangavel, Arumugam
Wieliczko, Marika
Bacsa, John
Scarborough, Christopher C
description The first synthesis of 1,4,7-tri-tert-butyl-1,4,7-triazacyclononane ( t Bu3tacn) and its adamantyl analog Ad3tacn are described. CrII, MnII, FeII, CoII, NiII, and CuI compounds of t Bu3tacn are reported: the steric properties of this ligand enforce four-coordinate geometries except in the case of five-coordinate CrII, enabling design of pseudotetrahedral compounds bearing this tridentate redox-inert ancillary ligand.
doi_str_mv 10.1021/ic402626p
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title 1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents
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