Multifunctional TiO2–C/MnO2 Core–Double-Shell Nanowire Arrays as High-Performance 3D Electrodes for Lithium Ion Batteries

The unique TiO2–C/MnO2 core–double-shell nanowires are synthesized for the first time using as anode materials for lithium ion batteries (LIBs). They combine both advantages from TiO2 such as excellent cycle stability and MnO2 with high capacity (1230 mA h g–1). The additional C interlayer intends t...

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Veröffentlicht in:Nano letters 2013-11, Vol.13 (11), p.5467-5473
Hauptverfasser: Liao, Jin-Yun, Higgins, Drew, Lui, Gregory, Chabot, Victor, Xiao, Xingcheng, Chen, Zhongwei
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container_end_page 5473
container_issue 11
container_start_page 5467
container_title Nano letters
container_volume 13
creator Liao, Jin-Yun
Higgins, Drew
Lui, Gregory
Chabot, Victor
Xiao, Xingcheng
Chen, Zhongwei
description The unique TiO2–C/MnO2 core–double-shell nanowires are synthesized for the first time using as anode materials for lithium ion batteries (LIBs). They combine both advantages from TiO2 such as excellent cycle stability and MnO2 with high capacity (1230 mA h g–1). The additional C interlayer intends to improve the electrical conductivity. The self-supported nanowire arrays grown directly on current-collecting substrates greatly simplify the fabrication processing of electrodes without applying binder and conductive additives. Each nanowire is anchored to the current collector, leading to fast charge transfer. The unique one-dimensional core–double-shell nanowires exhibit enhanced electrochemical performance with a higher discharge/charge capacity, superior rate capability, and longer cycling lifetime.
doi_str_mv 10.1021/nl4030159
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subjects Applied sciences
Cross-disciplinary physics: materials science
rheology
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Exact sciences and technology
Materials science
Methods of nanofabrication
Nanocrystalline materials
Nanoscale materials and structures: fabrication and characterization
Physics
Quantum wires
title Multifunctional TiO2–C/MnO2 Core–Double-Shell Nanowire Arrays as High-Performance 3D Electrodes for Lithium Ion Batteries
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