Use of non-conventional electrolyte salt and additives in high-voltage graphite/LiNi sub(0.4)Mn sub(1.6)O sub(4) batteries
The performance of full cells featuring high-voltage LiNi sub(0.4)Mn sub(1.6)O sub(4) cathode and graphite anode with carbonate-based electrolytes, ethylene carbonate (EC) -dimethyl carbonate (DMC) with conventional LiPF sub(6) and non-conventional Li[(C sub(2)F sub(5)) sub(3)PF sub(3)] (LiFAP) lith...
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| Veröffentlicht in: | Journal of power sources 2013-09, Vol.238, p.17-20 |
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| container_title | Journal of power sources |
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| creator | Arbizzani, C De Giorgio, F Porcarelli, L Mastragostino, M Khomenko, V Barsukov, V Bresser, D Passerini, S |
| description | The performance of full cells featuring high-voltage LiNi sub(0.4)Mn sub(1.6)O sub(4) cathode and graphite anode with carbonate-based electrolytes, ethylene carbonate (EC) -dimethyl carbonate (DMC) with conventional LiPF sub(6) and non-conventional Li[(C sub(2)F sub(5)) sub(3)PF sub(3)] (LiFAP) lithium salts with and without SEI-forming additives 1-fluoro ethylene carbonate (F sub(1)EC) and succinic anhydride (SA) is investigated. The results evidence the beneficial impact of EC-DMC-1M LiFAP electrolyte (LF30), with respect to EC-DMC-1M LiPF sub(6) electrolyte (LP30), also in presence of 1.6% F sub(1)EC-2% SA additives, on charge retention over cycling and on self-discharge of full cells. After the 25 cycles of the charge capability test, the charge retention reached values up to 70% with LF30 and 87% with LF30 and additives, and fully charged cells with LF30-additives delivered 53% of the stored charge after one week in OCV. |
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The results evidence the beneficial impact of EC-DMC-1M LiFAP electrolyte (LF30), with respect to EC-DMC-1M LiPF sub(6) electrolyte (LP30), also in presence of 1.6% F sub(1)EC-2% SA additives, on charge retention over cycling and on self-discharge of full cells. 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The results evidence the beneficial impact of EC-DMC-1M LiFAP electrolyte (LF30), with respect to EC-DMC-1M LiPF sub(6) electrolyte (LP30), also in presence of 1.6% F sub(1)EC-2% SA additives, on charge retention over cycling and on self-discharge of full cells. 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The results evidence the beneficial impact of EC-DMC-1M LiFAP electrolyte (LF30), with respect to EC-DMC-1M LiPF sub(6) electrolyte (LP30), also in presence of 1.6% F sub(1)EC-2% SA additives, on charge retention over cycling and on self-discharge of full cells. After the 25 cycles of the charge capability test, the charge retention reached values up to 70% with LF30 and 87% with LF30 and additives, and fully charged cells with LF30-additives delivered 53% of the stored charge after one week in OCV.</abstract></addata></record> |
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| title | Use of non-conventional electrolyte salt and additives in high-voltage graphite/LiNi sub(0.4)Mn sub(1.6)O sub(4) batteries |
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