Influence of partial cross-linking degree on basic physical properties of RTM6 epoxy resin
ABSTRACT Thermo‐physical and mechanical properties of partially and completely cross‐linked RTM6 epoxy resin samples in the glassy state have been investigated. A significant dependence of glass transition temperature, density, and modulus on the curing history and the curing degree is found. Densit...
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Veröffentlicht in: | Journal of applied polymer science 2013-12, Vol.130 (6), p.4338-4346 |
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creator | Moosburger-Will, Judith Greisel, Michael Sause, Markus G. R. Horny, Robert Horn, Siegfried |
description | ABSTRACT
Thermo‐physical and mechanical properties of partially and completely cross‐linked RTM6 epoxy resin samples in the glassy state have been investigated. A significant dependence of glass transition temperature, density, and modulus on the curing history and the curing degree is found. Density and modulus decrease with increasing curing degree and show a step‐like irregularity in the so called transition region, which is related to the transition from rubber to glassy state during cross‐linking and the starting of structural relaxation processes. The relationship between the thermo‐physical and mechanical properties, which is important for the development of new processing routes for fiber reinforced polymers, is addressed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4338–4346, 2013 |
doi_str_mv | 10.1002/app.39722 |
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Thermo‐physical and mechanical properties of partially and completely cross‐linked RTM6 epoxy resin samples in the glassy state have been investigated. A significant dependence of glass transition temperature, density, and modulus on the curing history and the curing degree is found. Density and modulus decrease with increasing curing degree and show a step‐like irregularity in the so called transition region, which is related to the transition from rubber to glassy state during cross‐linking and the starting of structural relaxation processes. The relationship between the thermo‐physical and mechanical properties, which is important for the development of new processing routes for fiber reinforced polymers, is addressed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4338–4346, 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.39722</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken, NJ: Blackwell Publishing Ltd</publisher><subject>Applied sciences ; Chemical properties ; Crosslinking ; Curing ; Density ; Epoxy resins ; Exact sciences and technology ; Glassy ; Materials science ; Mechanical properties ; Physical properties ; Polymer industry, paints, wood ; Polymers ; Properties and testing ; Technology of polymers ; thermal properties ; thermosets ; Thermosetting resins</subject><ispartof>Journal of applied polymer science, 2013-12, Vol.130 (6), p.4338-4346</ispartof><rights>Copyright © 2013 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4332-883eb815281ac32fde9b3802627cfb0a5fb16beb3938953c6097c3ed527e9d3f3</citedby><cites>FETCH-LOGICAL-c4332-883eb815281ac32fde9b3802627cfb0a5fb16beb3938953c6097c3ed527e9d3f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.39722$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.39722$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27931,27932,45581,45582</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27761884$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Moosburger-Will, Judith</creatorcontrib><creatorcontrib>Greisel, Michael</creatorcontrib><creatorcontrib>Sause, Markus G. R.</creatorcontrib><creatorcontrib>Horny, Robert</creatorcontrib><creatorcontrib>Horn, Siegfried</creatorcontrib><title>Influence of partial cross-linking degree on basic physical properties of RTM6 epoxy resin</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
Thermo‐physical and mechanical properties of partially and completely cross‐linked RTM6 epoxy resin samples in the glassy state have been investigated. A significant dependence of glass transition temperature, density, and modulus on the curing history and the curing degree is found. Density and modulus decrease with increasing curing degree and show a step‐like irregularity in the so called transition region, which is related to the transition from rubber to glassy state during cross‐linking and the starting of structural relaxation processes. The relationship between the thermo‐physical and mechanical properties, which is important for the development of new processing routes for fiber reinforced polymers, is addressed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4338–4346, 2013</description><subject>Applied sciences</subject><subject>Chemical properties</subject><subject>Crosslinking</subject><subject>Curing</subject><subject>Density</subject><subject>Epoxy resins</subject><subject>Exact sciences and technology</subject><subject>Glassy</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>Physical properties</subject><subject>Polymer industry, paints, wood</subject><subject>Polymers</subject><subject>Properties and testing</subject><subject>Technology of polymers</subject><subject>thermal properties</subject><subject>thermosets</subject><subject>Thermosetting resins</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kE1PGzEQhi3USqShB_7BSgiJHjbx167tI6JtiEhpWlEhcbG8zhgMi3drJ2ry7zEEckDqaQ7zPK9mXoQOCR4RjOnY9P2IKUHpHhoQrETJayo_oEHekVIqVe2jTyndY0xIhesBupkG164gWCg6V_QmLr1pCxu7lMrWhwcfbosF3EbI-1A0Jnlb9HebPDLWx66HbEB6ln9f_agL6Lv1poiQfDhAH51pE3x-nUP05_u3q7PzcvZzMj07nZWWM0ZLKRk0klRUEmMZdQtQDZOY1lRY12BTuYbUDTRMMakqZuv8lWWwqKgAtWCODdHJNjef83cFaakffbLQtiZAt0qacC4FV5xWGT16h953qxjydZligijMKc7Uly31UkMEp_voH03caIL1c8s6t6xfWs7s8WuiSbkSF02wPu0EKkRNpOSZG2-5f76Fzf8D9el8_pZcbg2flrDeGSY-6FowUenry4mez_jXizn9pTF7AriDmWQ</recordid><startdate>20131215</startdate><enddate>20131215</enddate><creator>Moosburger-Will, Judith</creator><creator>Greisel, Michael</creator><creator>Sause, Markus G. 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R. ; Horny, Robert ; Horn, Siegfried</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4332-883eb815281ac32fde9b3802627cfb0a5fb16beb3938953c6097c3ed527e9d3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Chemical properties</topic><topic>Crosslinking</topic><topic>Curing</topic><topic>Density</topic><topic>Epoxy resins</topic><topic>Exact sciences and technology</topic><topic>Glassy</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>Physical properties</topic><topic>Polymer industry, paints, wood</topic><topic>Polymers</topic><topic>Properties and testing</topic><topic>Technology of polymers</topic><topic>thermal properties</topic><topic>thermosets</topic><topic>Thermosetting resins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moosburger-Will, Judith</creatorcontrib><creatorcontrib>Greisel, Michael</creatorcontrib><creatorcontrib>Sause, Markus G. 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Sci</addtitle><date>2013-12-15</date><risdate>2013</risdate><volume>130</volume><issue>6</issue><spage>4338</spage><epage>4346</epage><pages>4338-4346</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
Thermo‐physical and mechanical properties of partially and completely cross‐linked RTM6 epoxy resin samples in the glassy state have been investigated. A significant dependence of glass transition temperature, density, and modulus on the curing history and the curing degree is found. Density and modulus decrease with increasing curing degree and show a step‐like irregularity in the so called transition region, which is related to the transition from rubber to glassy state during cross‐linking and the starting of structural relaxation processes. The relationship between the thermo‐physical and mechanical properties, which is important for the development of new processing routes for fiber reinforced polymers, is addressed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4338–4346, 2013</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.39722</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Applied sciences Chemical properties Crosslinking Curing Density Epoxy resins Exact sciences and technology Glassy Materials science Mechanical properties Physical properties Polymer industry, paints, wood Polymers Properties and testing Technology of polymers thermal properties thermosets Thermosetting resins |
title | Influence of partial cross-linking degree on basic physical properties of RTM6 epoxy resin |
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