Metal-Free Direct CH Perfluoroalkylation of Arenes and Heteroarenes Using a Photoredox Organocatalyst

We report the visible‐light‐induced trifluoromethylation of arenes and heteroarenes using sodium trifluoromethanesulfinate catalyzed by anthraquinone‐2‐carboxylic acid. This reaction is a metal‐free trifluoromethylation of arenes and heteroarenes catalyzed by a photoredox organocatalyst. Perfluoroal...

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Veröffentlicht in:	Advanced synthesis & catalysis 2013-08, Vol.355 (11-12), p.2203-2207
Hauptverfasser:	Cui, Lei, Matusaki, Yoko, Tada, Norihiro, Miura, Tsuyoshi, Uno, Bunji, Itoh, Akichika
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis CH activation electron transfer organocatalysis photochemistry radical reactions Sodium Synthesis
Online-Zugang:	Volltext
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