Aluminium alloy corrosion inhibition by chromate-free composition of zinc phosphate and ion-exchanged zeolite

Corrosion inhibition of aluminium alloy D16T by natural and calcium and zinc ion‐exchanged zeolites and their compositions with phosphate pigment was studied. Clinoptilolite, a natural zeolite from Sokyrnytsia deposit (Transcarpathian region, Ukraine), has been used in this study as a basic componen...

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Veröffentlicht in:Surface and interface analysis 2013-10, Vol.45 (10), p.1474-1478
Hauptverfasser: Pokhmurskii, V. I., Zin, I. M., Bily, L. M., Vynar, V. A., Zin, Ya I.
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container_end_page 1478
container_issue 10
container_start_page 1474
container_title Surface and interface analysis
container_volume 45
creator Pokhmurskii, V. I.
Zin, I. M.
Bily, L. M.
Vynar, V. A.
Zin, Ya I.
description Corrosion inhibition of aluminium alloy D16T by natural and calcium and zinc ion‐exchanged zeolites and their compositions with phosphate pigment was studied. Clinoptilolite, a natural zeolite from Sokyrnytsia deposit (Transcarpathian region, Ukraine), has been used in this study as a basic component. Protective properties of polyurethane coatings containing ion‐exchanged zeolites were investigated in acid rain solution. Direct current polarization methods and electrochemical impedance spectroscopy were used. It was established that composition of zinc phosphate and calcium ion‐exchanged zeolite has significant anti‐corrosion synergistic effect because of deposition of protective film on aluminium alloy surface. The addition of phosphate/zeolite‐inhibiting composition to polyurethane coating offers substantial increase of its protective properties in corrosion environment compared with the use of a single phosphate pigment. Copyright © 2013 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/sia.5275
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The addition of phosphate/zeolite‐inhibiting composition to polyurethane coating offers substantial increase of its protective properties in corrosion environment compared with the use of a single phosphate pigment. 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subjects aluminium alloy
Aluminum base alloys
Calcium
Coatings
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
corrosion inhibition
Corrosion prevention
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
phosphate
Phosphates
Physics
polyurethane coating
Polyurethane resins
Protective
zeolite
Zeolites
title Aluminium alloy corrosion inhibition by chromate-free composition of zinc phosphate and ion-exchanged zeolite
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