Cationic photopolymerization of bisphenol A diglycidyl ether epoxy under 385 nm
ABSTRACT The cationic photopolymerization of bisphenol A diglycidyl ether epoxy (DGEBA) at λ = 385 nm was conducted by the combination of a cationic photoinitiator PAG30201 (Bis (4‐isobutylphenyl) iodonium hexafluorophosphate) and a photosensitizer PSS303 (9,10‐dibutoxy‐9,10‐dihydroanthrance). The k...
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| Veröffentlicht in: | Journal of applied polymer science 2013-12, Vol.130 (5), p.3698-3703 |
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| container_title | Journal of applied polymer science |
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| creator | Liu, Guodong Zhu, Xiaoqun Xu, Bingbing Qian, Xiaochun Song, Guoqiang Nie, Jun |
| description | ABSTRACT
The cationic photopolymerization of bisphenol A diglycidyl ether epoxy (DGEBA) at λ = 385 nm was conducted by the combination of a cationic photoinitiator PAG30201 (Bis (4‐isobutylphenyl) iodonium hexafluorophosphate) and a photosensitizer PSS303 (9,10‐dibutoxy‐9,10‐dihydroanthrance). The kinetic characterization was investigated by real‐time Fourier transform infrared spectroscopy. The enhancement of epoxy conversion of DGEBA was achieved by increasing temperature, adding alcohols, active monomers and radical photoinitiators. As a result, in the presence of 2 wt % PAG30201 and 1.2 wt % PSS303, the epoxy rings conversion of DGEBA has reached to more than 70% from 55.9% at room temperature; it could be increased to almost 80% if heated to 60°C. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3698–3703, 2013 |
| doi_str_mv | 10.1002/app.39612 |
| format | Article |
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The cationic photopolymerization of bisphenol A diglycidyl ether epoxy (DGEBA) at λ = 385 nm was conducted by the combination of a cationic photoinitiator PAG30201 (Bis (4‐isobutylphenyl) iodonium hexafluorophosphate) and a photosensitizer PSS303 (9,10‐dibutoxy‐9,10‐dihydroanthrance). The kinetic characterization was investigated by real‐time Fourier transform infrared spectroscopy. The enhancement of epoxy conversion of DGEBA was achieved by increasing temperature, adding alcohols, active monomers and radical photoinitiators. As a result, in the presence of 2 wt % PAG30201 and 1.2 wt % PSS303, the epoxy rings conversion of DGEBA has reached to more than 70% from 55.9% at room temperature; it could be increased to almost 80% if heated to 60°C. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3698–3703, 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.39612</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken, NJ: Blackwell Publishing Ltd</publisher><subject>Applied sciences ; Bisphenol A ; Cationic ; Conversion ; Ethers ; Exact sciences and technology ; Fourier transforms ; Infrared spectroscopy ; irradiation ; kinetics ; Materials science ; monomers ; oligomers and telechelics ; Photoinitiators ; Photopolymerization ; Physicochemistry of polymers ; Polymerization ; Polymers ; Polymers and radiations ; ring-opening polymerization ; Spectrum analysis</subject><ispartof>Journal of applied polymer science, 2013-12, Vol.130 (5), p.3698-3703</ispartof><rights>Copyright © 2013 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5012-80def0828873c92e279db60392c9cf36ef23225e8b26d105bc88ef3cfbcb33393</citedby><cites>FETCH-LOGICAL-c5012-80def0828873c92e279db60392c9cf36ef23225e8b26d105bc88ef3cfbcb33393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.39612$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.39612$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27745948$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Guodong</creatorcontrib><creatorcontrib>Zhu, Xiaoqun</creatorcontrib><creatorcontrib>Xu, Bingbing</creatorcontrib><creatorcontrib>Qian, Xiaochun</creatorcontrib><creatorcontrib>Song, Guoqiang</creatorcontrib><creatorcontrib>Nie, Jun</creatorcontrib><title>Cationic photopolymerization of bisphenol A diglycidyl ether epoxy under 385 nm</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
The cationic photopolymerization of bisphenol A diglycidyl ether epoxy (DGEBA) at λ = 385 nm was conducted by the combination of a cationic photoinitiator PAG30201 (Bis (4‐isobutylphenyl) iodonium hexafluorophosphate) and a photosensitizer PSS303 (9,10‐dibutoxy‐9,10‐dihydroanthrance). The kinetic characterization was investigated by real‐time Fourier transform infrared spectroscopy. The enhancement of epoxy conversion of DGEBA was achieved by increasing temperature, adding alcohols, active monomers and radical photoinitiators. As a result, in the presence of 2 wt % PAG30201 and 1.2 wt % PSS303, the epoxy rings conversion of DGEBA has reached to more than 70% from 55.9% at room temperature; it could be increased to almost 80% if heated to 60°C. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3698–3703, 2013</description><subject>Applied sciences</subject><subject>Bisphenol A</subject><subject>Cationic</subject><subject>Conversion</subject><subject>Ethers</subject><subject>Exact sciences and technology</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>irradiation</subject><subject>kinetics</subject><subject>Materials science</subject><subject>monomers</subject><subject>oligomers and telechelics</subject><subject>Photoinitiators</subject><subject>Photopolymerization</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polymers and radiations</subject><subject>ring-opening polymerization</subject><subject>Spectrum analysis</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LHDEYh4O00K3tod8gIAV7GM2fmUlyXBa1Bal7aCl4CZnMGzc2OxmTWXT66Rtd9VDoIbwheX4PLz-EPlFyQglhp2YcT7hqKTtAC0qUqOqWyTdoUf5oJZVq3qH3Od8SQmlD2gW6WpnJx8FbPG7iFMcY5i0k_-fpFUeHO5_HDQwx4CXu_U2Yre_ngGHaQMIwxocZ74a-3Lls8LD9gN46EzJ8fJ6H6Of52Y_V1-ry6uLbanlZ2YZQVknSgyOSSSm4VQyYUH3XEq6YVdbxFhzjjDUgO9b2lDSdlRIct66zHedc8UN0vPeOKd7tIE9667OFEMwAcZc1rWspKJeMF_ToH_Q27tJQtisUp-UIIQv1ZU_ZFHNO4PSY_NakWVOiH6vVpVr9VG1hPz8bTbYmuGQG6_NrgAlRN6p-dJ7uuXsfYP6_UC_X6xdztU_4PMHDa8Kk37oVXDT61_cLfX29ki1ZK035X2EelWI</recordid><startdate>20131205</startdate><enddate>20131205</enddate><creator>Liu, Guodong</creator><creator>Zhu, Xiaoqun</creator><creator>Xu, Bingbing</creator><creator>Qian, Xiaochun</creator><creator>Song, Guoqiang</creator><creator>Nie, Jun</creator><general>Blackwell Publishing Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20131205</creationdate><title>Cationic photopolymerization of bisphenol A diglycidyl ether epoxy under 385 nm</title><author>Liu, Guodong ; Zhu, Xiaoqun ; Xu, Bingbing ; Qian, Xiaochun ; Song, Guoqiang ; Nie, Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5012-80def0828873c92e279db60392c9cf36ef23225e8b26d105bc88ef3cfbcb33393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Bisphenol A</topic><topic>Cationic</topic><topic>Conversion</topic><topic>Ethers</topic><topic>Exact sciences and technology</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>irradiation</topic><topic>kinetics</topic><topic>Materials science</topic><topic>monomers</topic><topic>oligomers and telechelics</topic><topic>Photoinitiators</topic><topic>Photopolymerization</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polymers and radiations</topic><topic>ring-opening polymerization</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Guodong</creatorcontrib><creatorcontrib>Zhu, Xiaoqun</creatorcontrib><creatorcontrib>Xu, Bingbing</creatorcontrib><creatorcontrib>Qian, Xiaochun</creatorcontrib><creatorcontrib>Song, Guoqiang</creatorcontrib><creatorcontrib>Nie, Jun</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Guodong</au><au>Zhu, Xiaoqun</au><au>Xu, Bingbing</au><au>Qian, Xiaochun</au><au>Song, Guoqiang</au><au>Nie, Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cationic photopolymerization of bisphenol A diglycidyl ether epoxy under 385 nm</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2013-12-05</date><risdate>2013</risdate><volume>130</volume><issue>5</issue><spage>3698</spage><epage>3703</epage><pages>3698-3703</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
The cationic photopolymerization of bisphenol A diglycidyl ether epoxy (DGEBA) at λ = 385 nm was conducted by the combination of a cationic photoinitiator PAG30201 (Bis (4‐isobutylphenyl) iodonium hexafluorophosphate) and a photosensitizer PSS303 (9,10‐dibutoxy‐9,10‐dihydroanthrance). The kinetic characterization was investigated by real‐time Fourier transform infrared spectroscopy. The enhancement of epoxy conversion of DGEBA was achieved by increasing temperature, adding alcohols, active monomers and radical photoinitiators. As a result, in the presence of 2 wt % PAG30201 and 1.2 wt % PSS303, the epoxy rings conversion of DGEBA has reached to more than 70% from 55.9% at room temperature; it could be increased to almost 80% if heated to 60°C. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3698–3703, 2013</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.39612</doi><tpages>6</tpages></addata></record> |
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| subjects | Applied sciences Bisphenol A Cationic Conversion Ethers Exact sciences and technology Fourier transforms Infrared spectroscopy irradiation kinetics Materials science monomers oligomers and telechelics Photoinitiators Photopolymerization Physicochemistry of polymers Polymerization Polymers Polymers and radiations ring-opening polymerization Spectrum analysis |
| title | Cationic photopolymerization of bisphenol A diglycidyl ether epoxy under 385 nm |
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