Effect of a variety of carbon nanotubes on the iodine–iodide redox pair
The iodide (I−)-triiodide (I3-) redox pair was used as a model system to evaluate the potential catalytic activity of various carbon nanotubes. Aqueous solutions of hydroiodic acid were irradiated with ultraviolet light in the presence of single wall, multi-wall, boron-doped and nitrogen-doped multi...
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| Veröffentlicht in: | Carbon (New York) 2013-10, Vol.62, p.177-181 |
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| container_title | Carbon (New York) |
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| creator | Simmons, Trevor J. Maeda, Noriko Miyauchi, Minoru Miao, Jianjun Hashim, Daniel P. Ajayan, Pulickel M. Dordick, Jonathan S. Linhardt, Robert J. |
| description | The iodide (I−)-triiodide (I3-) redox pair was used as a model system to evaluate the potential catalytic activity of various carbon nanotubes. Aqueous solutions of hydroiodic acid were irradiated with ultraviolet light in the presence of single wall, multi-wall, boron-doped and nitrogen-doped multi-wall carbon nanotubes. The nitrogen-doped multi-wall carbon nanotubes showed significant catalytic activity in the generation of hydrogen triiodide, while the other carbon nanotubes studied inhibited the generation of hydrogen triiodide. The photoconversion of hydroiodic acid to hydrogen triiodide, catalyzed by the nitrogen-doped multi-wall carbon nanotubes, was further accelerated by the presence of dissolved oxygen, offering an additional decomposition pathway for hydroiodic acid. |
| doi_str_mv | 10.1016/j.carbon.2013.06.009 |
| format | Article |
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Aqueous solutions of hydroiodic acid were irradiated with ultraviolet light in the presence of single wall, multi-wall, boron-doped and nitrogen-doped multi-wall carbon nanotubes. The nitrogen-doped multi-wall carbon nanotubes showed significant catalytic activity in the generation of hydrogen triiodide, while the other carbon nanotubes studied inhibited the generation of hydrogen triiodide. The photoconversion of hydroiodic acid to hydrogen triiodide, catalyzed by the nitrogen-doped multi-wall carbon nanotubes, was further accelerated by the presence of dissolved oxygen, offering an additional decomposition pathway for hydroiodic acid.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2013.06.009</identifier><identifier>CODEN: CRBNAH</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Aqueous solutions ; Carbon ; Carbon nanotubes ; Catalysis ; Catalytic activity ; Chemistry ; Cross-disciplinary physics: materials science; rheology ; Electrochemistry ; Electrodes: preparations and properties ; Exact sciences and technology ; Fullerenes and related materials; diamonds, graphite ; General and physical chemistry ; Iodides ; Materials science ; Multi wall carbon nanotubes ; Nanoscale materials and structures: fabrication and characterization ; Nanotubes ; Pathways ; Physics ; Specific materials ; Theory of reactions, general kinetics. 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Nomenclature, chemical documentation, computer chemistry ; Walls</subject><ispartof>Carbon (New York), 2013-10, Vol.62, p.177-181</ispartof><rights>2013 Elsevier Ltd</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-7cbe86a94ebc755c2bb80cc0820cdc269ba409a731f789da61149a4a0e66c99d3</citedby><cites>FETCH-LOGICAL-c439t-7cbe86a94ebc755c2bb80cc0820cdc269ba409a731f789da61149a4a0e66c99d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0008622313005022$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27584176$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Simmons, Trevor J.</creatorcontrib><creatorcontrib>Maeda, Noriko</creatorcontrib><creatorcontrib>Miyauchi, Minoru</creatorcontrib><creatorcontrib>Miao, Jianjun</creatorcontrib><creatorcontrib>Hashim, Daniel P.</creatorcontrib><creatorcontrib>Ajayan, Pulickel M.</creatorcontrib><creatorcontrib>Dordick, Jonathan S.</creatorcontrib><creatorcontrib>Linhardt, Robert J.</creatorcontrib><title>Effect of a variety of carbon nanotubes on the iodine–iodide redox pair</title><title>Carbon (New York)</title><description>The iodide (I−)-triiodide (I3-) redox pair was used as a model system to evaluate the potential catalytic activity of various carbon nanotubes. 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The photoconversion of hydroiodic acid to hydrogen triiodide, catalyzed by the nitrogen-doped multi-wall carbon nanotubes, was further accelerated by the presence of dissolved oxygen, offering an additional decomposition pathway for hydroiodic acid.</description><subject>Aqueous solutions</subject><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electrochemistry</subject><subject>Electrodes: preparations and properties</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>General and physical chemistry</subject><subject>Iodides</subject><subject>Materials science</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>Nanotubes</subject><subject>Pathways</subject><subject>Physics</subject><subject>Specific materials</subject><subject>Theory of reactions, general kinetics. 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Aqueous solutions of hydroiodic acid were irradiated with ultraviolet light in the presence of single wall, multi-wall, boron-doped and nitrogen-doped multi-wall carbon nanotubes. The nitrogen-doped multi-wall carbon nanotubes showed significant catalytic activity in the generation of hydrogen triiodide, while the other carbon nanotubes studied inhibited the generation of hydrogen triiodide. The photoconversion of hydroiodic acid to hydrogen triiodide, catalyzed by the nitrogen-doped multi-wall carbon nanotubes, was further accelerated by the presence of dissolved oxygen, offering an additional decomposition pathway for hydroiodic acid.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2013.06.009</doi><tpages>5</tpages></addata></record> |
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| ispartof | Carbon (New York), 2013-10, Vol.62, p.177-181 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Aqueous solutions Carbon Carbon nanotubes Catalysis Catalytic activity Chemistry Cross-disciplinary physics: materials science rheology Electrochemistry Electrodes: preparations and properties Exact sciences and technology Fullerenes and related materials diamonds, graphite General and physical chemistry Iodides Materials science Multi wall carbon nanotubes Nanoscale materials and structures: fabrication and characterization Nanotubes Pathways Physics Specific materials Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Walls |
| title | Effect of a variety of carbon nanotubes on the iodine–iodide redox pair |
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