A mononuclear cobalt(II)-dithienylethene complex showing slow magnetic relaxation and photochromic behavior

Mononuclear complex Co(hpbdti)2·3CH3OH (1) was synthesized [hpbdtiH = 2-(2-hydroxyphenyl)-4,5-bis(2,5-dimethyl(3-thienyl))-1H-imidazole], showing multiple-step field-induced slow magnetic relaxation behaviors, and photochromic properties in CH2Cl2-CH3CN solution.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-10, Vol.49 (78), p.8863-8865
Hauptverfasser: Cao, Deng-Ke, Feng, Jia-Qi, Ren, Min, Gu, Yan-Wei, Song, You, Ward, Michael D
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Sprache:eng
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Zusammenfassung:Mononuclear complex Co(hpbdti)2·3CH3OH (1) was synthesized [hpbdtiH = 2-(2-hydroxyphenyl)-4,5-bis(2,5-dimethyl(3-thienyl))-1H-imidazole], showing multiple-step field-induced slow magnetic relaxation behaviors, and photochromic properties in CH2Cl2-CH3CN solution.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc45315d