Persistence of quinalphos and occurrence of its primary metabolite in soils
Quinalphos is used widely in India for the control of pests in cotton, groundnut, and rice. A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil...
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Veröffentlicht in: | Bulletin of environmental contamination and toxicology 1998-05, Vol.60 (5), p.724-731 |
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description | Quinalphos is used widely in India for the control of pests in cotton, groundnut, and rice. A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil and a black clay soil were used, which were both sterile and nonsterile. Results showed that the dissipation rate of quinalphos followed first-order kinetics. The rate constant and half-life for quinalphos disappearance in black soil and in red sandy loam sandy clay soil were 0.0533 and 0.0462/d, and 13 and 15 d, respectively. Quinalphos persisted to the same extent in the soils with and without pre-exposure, but the recovery of 2-hydroxyquinoxaline was higher from soils with repeated quinalphos applications. |
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A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil and a black clay soil were used, which were both sterile and nonsterile. Results showed that the dissipation rate of quinalphos followed first-order kinetics. The rate constant and half-life for quinalphos disappearance in black soil and in red sandy loam sandy clay soil were 0.0533 and 0.0462/d, and 13 and 15 d, respectively. Quinalphos persisted to the same extent in the soils with and without pre-exposure, but the recovery of 2-hydroxyquinoxaline was higher from soils with repeated quinalphos applications.</description><identifier>ISSN: 0007-4861</identifier><identifier>EISSN: 1432-0800</identifier><identifier>DOI: 10.1007/s001289900686</identifier><identifier>PMID: 9595187</identifier><identifier>CODEN: BECTA6</identifier><language>eng</language><publisher>New York, NY: Springer-Verlag</publisher><subject>Agriculture ; Agronomy. Soil science and plant productions ; Applied sciences ; Biological and medical sciences ; Biological and physicochemical properties of pollutants. Interaction in the soil ; Environmental Monitoring ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; Insecticides - metabolism ; Insecticides - pharmacokinetics ; METABOLITE ; METABOLITES ; METABOLITOS ; Organothiophosphorus Compounds - metabolism ; Organothiophosphorus Compounds - pharmacokinetics ; Pest Control ; Pesticide Residues - metabolism ; Pesticide Residues - pharmacokinetics ; Pollution ; QUINALFOS ; QUINALPHOS ; SOIL ; Soil and sediments pollution ; Soil and water pollution ; Soil Pollutants - metabolism ; Soil Pollutants - pharmacokinetics ; Soil science ; SOL ; SUELO</subject><ispartof>Bulletin of environmental contamination and toxicology, 1998-05, Vol.60 (5), p.724-731</ispartof><rights>1998 INIST-CNRS</rights><rights>Springer-Verlag New York Inc. 1998</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c431t-157eefa8010ef13084959eabf24b22a4d4b4501b775ccd7e940c9504ade583c43</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2238652$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/9595187$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Babu, G.V.A.K</creatorcontrib><creatorcontrib>Reddy, B.R</creatorcontrib><creatorcontrib>Narasimha, G</creatorcontrib><creatorcontrib>Sethunathan, N</creatorcontrib><title>Persistence of quinalphos and occurrence of its primary metabolite in soils</title><title>Bulletin of environmental contamination and toxicology</title><addtitle>Bull Environ Contam Toxicol</addtitle><description>Quinalphos is used widely in India for the control of pests in cotton, groundnut, and rice. A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil and a black clay soil were used, which were both sterile and nonsterile. Results showed that the dissipation rate of quinalphos followed first-order kinetics. The rate constant and half-life for quinalphos disappearance in black soil and in red sandy loam sandy clay soil were 0.0533 and 0.0462/d, and 13 and 15 d, respectively. Quinalphos persisted to the same extent in the soils with and without pre-exposure, but the recovery of 2-hydroxyquinoxaline was higher from soils with repeated quinalphos applications.</description><subject>Agriculture</subject><subject>Agronomy. Soil science and plant productions</subject><subject>Applied sciences</subject><subject>Biological and medical sciences</subject><subject>Biological and physicochemical properties of pollutants. 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Soil science and plant productions</topic><topic>Applied sciences</topic><topic>Biological and medical sciences</topic><topic>Biological and physicochemical properties of pollutants. Interaction in the soil</topic><topic>Environmental Monitoring</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Insecticides - metabolism</topic><topic>Insecticides - pharmacokinetics</topic><topic>METABOLITE</topic><topic>METABOLITES</topic><topic>METABOLITOS</topic><topic>Organothiophosphorus Compounds - metabolism</topic><topic>Organothiophosphorus Compounds - pharmacokinetics</topic><topic>Pest Control</topic><topic>Pesticide Residues - metabolism</topic><topic>Pesticide Residues - pharmacokinetics</topic><topic>Pollution</topic><topic>QUINALFOS</topic><topic>QUINALPHOS</topic><topic>SOIL</topic><topic>Soil and sediments pollution</topic><topic>Soil and water pollution</topic><topic>Soil Pollutants - metabolism</topic><topic>Soil Pollutants - pharmacokinetics</topic><topic>Soil science</topic><topic>SOL</topic><topic>SUELO</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Babu, G.V.A.K</creatorcontrib><creatorcontrib>Reddy, B.R</creatorcontrib><creatorcontrib>Narasimha, G</creatorcontrib><creatorcontrib>Sethunathan, N</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Neurosciences Abstracts</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Environment Abstracts</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Safety Science and Risk</collection><collection>Environment Abstracts</collection><jtitle>Bulletin of environmental contamination and toxicology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Babu, G.V.A.K</au><au>Reddy, B.R</au><au>Narasimha, G</au><au>Sethunathan, N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Persistence of quinalphos and occurrence of its primary metabolite in soils</atitle><jtitle>Bulletin of environmental contamination and toxicology</jtitle><addtitle>Bull Environ Contam Toxicol</addtitle><date>1998-05-01</date><risdate>1998</risdate><volume>60</volume><issue>5</issue><spage>724</spage><epage>731</epage><pages>724-731</pages><issn>0007-4861</issn><eissn>1432-0800</eissn><coden>BECTA6</coden><abstract>Quinalphos is used widely in India for the control of pests in cotton, groundnut, and rice. A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil and a black clay soil were used, which were both sterile and nonsterile. Results showed that the dissipation rate of quinalphos followed first-order kinetics. The rate constant and half-life for quinalphos disappearance in black soil and in red sandy loam sandy clay soil were 0.0533 and 0.0462/d, and 13 and 15 d, respectively. Quinalphos persisted to the same extent in the soils with and without pre-exposure, but the recovery of 2-hydroxyquinoxaline was higher from soils with repeated quinalphos applications.</abstract><cop>New York, NY</cop><pub>Springer-Verlag</pub><pmid>9595187</pmid><doi>10.1007/s001289900686</doi><tpages>8</tpages></addata></record> |
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subjects | Agriculture Agronomy. Soil science and plant productions Applied sciences Biological and medical sciences Biological and physicochemical properties of pollutants. Interaction in the soil Environmental Monitoring Exact sciences and technology Fundamental and applied biological sciences. Psychology Insecticides - metabolism Insecticides - pharmacokinetics METABOLITE METABOLITES METABOLITOS Organothiophosphorus Compounds - metabolism Organothiophosphorus Compounds - pharmacokinetics Pest Control Pesticide Residues - metabolism Pesticide Residues - pharmacokinetics Pollution QUINALFOS QUINALPHOS SOIL Soil and sediments pollution Soil and water pollution Soil Pollutants - metabolism Soil Pollutants - pharmacokinetics Soil science SOL SUELO |
title | Persistence of quinalphos and occurrence of its primary metabolite in soils |
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