Persistence of quinalphos and occurrence of its primary metabolite in soils

Quinalphos is used widely in India for the control of pests in cotton, groundnut, and rice. A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil...

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Veröffentlicht in:Bulletin of environmental contamination and toxicology 1998-05, Vol.60 (5), p.724-731
Hauptverfasser: Babu, G.V.A.K, Reddy, B.R, Narasimha, G, Sethunathan, N
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creator Babu, G.V.A.K
Reddy, B.R
Narasimha, G
Sethunathan, N
description Quinalphos is used widely in India for the control of pests in cotton, groundnut, and rice. A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil and a black clay soil were used, which were both sterile and nonsterile. Results showed that the dissipation rate of quinalphos followed first-order kinetics. The rate constant and half-life for quinalphos disappearance in black soil and in red sandy loam sandy clay soil were 0.0533 and 0.0462/d, and 13 and 15 d, respectively. Quinalphos persisted to the same extent in the soils with and without pre-exposure, but the recovery of 2-hydroxyquinoxaline was higher from soils with repeated quinalphos applications.
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A study was conducted to examine the formation of the quinalphos metabolite, 2-hydroxyquinoxaline, during degradation of the parent compound in soils under aerobic conditions. A red sandy loam sandy clay soil and a black clay soil were used, which were both sterile and nonsterile. Results showed that the dissipation rate of quinalphos followed first-order kinetics. The rate constant and half-life for quinalphos disappearance in black soil and in red sandy loam sandy clay soil were 0.0533 and 0.0462/d, and 13 and 15 d, respectively. Quinalphos persisted to the same extent in the soils with and without pre-exposure, but the recovery of 2-hydroxyquinoxaline was higher from soils with repeated quinalphos applications.</abstract><cop>New York, NY</cop><pub>Springer-Verlag</pub><pmid>9595187</pmid><doi>10.1007/s001289900686</doi><tpages>8</tpages></addata></record>
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subjects Agriculture
Agronomy. Soil science and plant productions
Applied sciences
Biological and medical sciences
Biological and physicochemical properties of pollutants. Interaction in the soil
Environmental Monitoring
Exact sciences and technology
Fundamental and applied biological sciences. Psychology
Insecticides - metabolism
Insecticides - pharmacokinetics
METABOLITE
METABOLITES
METABOLITOS
Organothiophosphorus Compounds - metabolism
Organothiophosphorus Compounds - pharmacokinetics
Pest Control
Pesticide Residues - metabolism
Pesticide Residues - pharmacokinetics
Pollution
QUINALFOS
QUINALPHOS
SOIL
Soil and sediments pollution
Soil and water pollution
Soil Pollutants - metabolism
Soil Pollutants - pharmacokinetics
Soil science
SOL
SUELO
title Persistence of quinalphos and occurrence of its primary metabolite in soils
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