Conversion of radioactive and hazardous chemical wastes into borosilicate glass using the glass material oxidation and dissolution system

A new vitrification process has been invented. The Glass Material Oxidation and Dissolution System (GMODS) allows direct conversion of radioactive and hazardous chemical wastes to borosilicate glass. GMODS directly converts metals, ceramics and amorphous solids to glass, oxidizes organics with the r...

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Veröffentlicht in:Waste Management 1996-01, Vol.16 (7), p.615-623
Hauptverfasser: Forsberg, C.W., Beahm, E.C., Parker, G.W., Elam, K.R.
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container_end_page 623
container_issue 7
container_start_page 615
container_title Waste Management
container_volume 16
creator Forsberg, C.W.
Beahm, E.C.
Parker, G.W.
Elam, K.R.
description A new vitrification process has been invented. The Glass Material Oxidation and Dissolution System (GMODS) allows direct conversion of radioactive and hazardous chemical wastes to borosilicate glass. GMODS directly converts metals, ceramics and amorphous solids to glass, oxidizes organics with the residue converted to glass, and converts halides (such as chlorides) to borosilicate glass and a secondary sodium halide stream. The glass is designed to meet EPA criteria for chemically non-hazardous waste forms. Laboratory work has demonstrated the conversion of stainless steel, aluminum, cerium (a plutonium surrogate), uranium, Zircaloy, multiple oxides and other materials to glass. Equipment options have been identified for processing rates between 1 and 100,000 t/y. Significant work, including a pilot plant, is required to develop GMODS for applications at an industrial scale.
doi_str_mv 10.1016/S0956-053X(97)00002-0
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ispartof Waste Management, 1996-01, Vol.16 (7), p.615-623
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source Elsevier ScienceDirect Journals
subjects 05 NUCLEAR FUELS
Applied sciences
BOROSILICATE GLASS
CHEMICAL WASTES
Exact sciences and technology
HAZARDOUS MATERIALS
Pollution
RADIOACTIVE WASTE PROCESSING
RADIOACTIVE WASTES
TECHNOLOGY ASSESSMENT
VITRIFICATION
Wastes
title Conversion of radioactive and hazardous chemical wastes into borosilicate glass using the glass material oxidation and dissolution system
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