Total synthesis of ionophore antibiotic X-14547A

A hishly stereocontrolled and convergent total synthesis of optically active ionophore antibiotic X-14547A was designed and carried out. Degradative reactions led to the key intermediates 3 and 6, which served as convenient comparison stages. Attachment of the 2-ketopyrrole system by new technology...

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Veröffentlicht in:	Journal of organic chemistry 1985-05, Vol.50 (9), p.1440-1456
Hauptverfasser:	Nicolaou, K. C, Papahatjis, D. P, Claremon, D. A, Magolda, R. L, Dolle, R. E
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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