Morphologically Robust NiFe2O4 Nanofibers as High Capacity Li-Ion Battery Anode Material
In this work, the electrochemical performance of NiFe2O4 nanofibers synthesized by an electrospinning approach have been discussed in detail. Lithium storage properties of nanofibers are evaluated and compared with NiFe2O4 nanoparticles by galvanostatic cycling and cyclic voltammetry studies, both i...
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| Veröffentlicht in: | ACS applied materials & interfaces 2013-10, Vol.5 (20), p.9957-9963 |
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| creator | Cherian, Christie Thomas Sundaramurthy, Jayaraman Reddy, M. V Suresh Kumar, Palanisamy Mani, Kalaivani Pliszka, Damian Sow, Chorng Haur Ramakrishna, Seeram Chowdari, B. V. R |
| description | In this work, the electrochemical performance of NiFe2O4 nanofibers synthesized by an electrospinning approach have been discussed in detail. Lithium storage properties of nanofibers are evaluated and compared with NiFe2O4 nanoparticles by galvanostatic cycling and cyclic voltammetry studies, both in half-cell configurations. Nanofibers exhibit a higher charge-storage capacity of 1000 mAh g–1 even after 100 cycles with high Coulmbic efficiency of 100 % between 10 and 100 cycles. Ex situ microscopy studies confirmed that cycled nanofiber electrodes maintained the morphology and remained intact even after 100 charge–discharge cycles. The NiFe2O4 nanofiber electrode does not experience any structural stress and eventual pulverisation during lithium cycling and hence provides an efficient electron conducting pathway. The excellent electrochemical performance of NiFe2O4 nanofibers is due to the unique porous morphology of continuous nanofibers. |
| doi_str_mv | 10.1021/am401779p |
| format | Article |
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Ex situ microscopy studies confirmed that cycled nanofiber electrodes maintained the morphology and remained intact even after 100 charge–discharge cycles. The NiFe2O4 nanofiber electrode does not experience any structural stress and eventual pulverisation during lithium cycling and hence provides an efficient electron conducting pathway. 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Nanofibers exhibit a higher charge-storage capacity of 1000 mAh g–1 even after 100 cycles with high Coulmbic efficiency of 100 % between 10 and 100 cycles. Ex situ microscopy studies confirmed that cycled nanofiber electrodes maintained the morphology and remained intact even after 100 charge–discharge cycles. The NiFe2O4 nanofiber electrode does not experience any structural stress and eventual pulverisation during lithium cycling and hence provides an efficient electron conducting pathway. 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| subjects | Electric Power Supplies Electrochemical Techniques Electrodes Ferric Compounds - chemistry Ions - chemistry Lithium - chemistry Nanofibers - chemistry Nickel - chemistry Povidone - chemistry Temperature |
| title | Morphologically Robust NiFe2O4 Nanofibers as High Capacity Li-Ion Battery Anode Material |
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