Cobalt Catalysis in the Gas Phase: Experimental Characterization of Cobalt(I) Complexes as Intermediates in Regioselective Diels–Alder Reactions

In situ-formed cobalt(I) complexes are proposed to act as efficient catalysts in regioselective Diels–Alder reactions of unactivated substrates such as 1,3-dienes and alkynes. We report the first experimental evidence for the in situ reduction of CoBr2(dppe) [dppe = 1,2-bis(diphenyl­phosphino)ethane...

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Veröffentlicht in:	Journal of organic chemistry 2013-10, Vol.78 (20), p.10485-10493
Hauptverfasser:	Fiebig, Lukas, Kuttner, Julian, Hilt, Gerhard, Schwarzer, Martin C, Frenking, Gernot, Schmalz, Hans-Günther, Schäfer, Mathias
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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