High-Efficiency Polymer Solar Cells via the Incorporation of an Amino-Functionalized Conjugated Metallopolymer as a Cathode Interlayer

An amino-functionalized conjugated metallopolymer PFEN-Hg was developed as a cathode interlayer for inverted polymer solar cells. The resulting devices exhibited significantly improved performance with power conversion efficiencies exceeding 9%. Moreover, good device performance was achievable with...

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Veröffentlicht in:Journal of the American Chemical Society 2013-10, Vol.135 (41), p.15326-15329
Hauptverfasser: Liu, Shengjian, Zhang, Kai, Lu, Junming, Zhang, Jie, Yip, Hin-Lap, Huang, Fei, Cao, Yong
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container_end_page 15329
container_issue 41
container_start_page 15326
container_title Journal of the American Chemical Society
container_volume 135
creator Liu, Shengjian
Zhang, Kai
Lu, Junming
Zhang, Jie
Yip, Hin-Lap
Huang, Fei
Cao, Yong
description An amino-functionalized conjugated metallopolymer PFEN-Hg was developed as a cathode interlayer for inverted polymer solar cells. The resulting devices exhibited significantly improved performance with power conversion efficiencies exceeding 9%. Moreover, good device performance was achievable with the PFEN-Hg over a wider range of film thickness, likely due to the Hg–Hg interactions and improved π–π stacking.
doi_str_mv 10.1021/ja408363c
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subjects Electric Power Supplies
Electrodes
Mercury - chemistry
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Polymers - chemistry
Solar Energy
title High-Efficiency Polymer Solar Cells via the Incorporation of an Amino-Functionalized Conjugated Metallopolymer as a Cathode Interlayer
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