Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols
Allyl amides were synthesised from the reaction of allyl alcohols and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addition and subsequent [3,3]-sigmatropic rearrangement steps of the process were catalysed by the same complex. Additionally, (1...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2013-11, Vol.11 (43), p.7472-7476 |
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| container_end_page | 7476 |
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| container_issue | 43 |
| container_start_page | 7472 |
| container_title | Organic & biomolecular chemistry |
| container_volume | 11 |
| creator | Lester, Roy P Dunsford, Jay J Camp, Jason E |
| description | Allyl amides were synthesised from the reaction of allyl alcohols and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addition and subsequent [3,3]-sigmatropic rearrangement steps of the process were catalysed by the same complex. Additionally, (1)H/(13)C{(1)H} NMR and GC studies provided the first insights into the mechanism of this transformation. |
| doi_str_mv | 10.1039/c3ob41692e |
| format | Article |
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Additionally, (1)H/(13)C{(1)H} NMR and GC studies provided the first insights into the mechanism of this transformation.</abstract><cop>England</cop><pmid>24068345</pmid><doi>10.1039/c3ob41692e</doi><tpages>5</tpages></addata></record> |
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| ispartof | Organic & biomolecular chemistry, 2013-11, Vol.11 (43), p.7472-7476 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols |
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