Fluctuations of systems in finite heat reservoirs with applications to phase transitions in lipid membranes

In an adiabatically shielded system, the total enthalpy is conserved. Enthalpy fluctuations of an arbitrarily chosen subsystem must be buffered by the remainder of the total system which serves as a heat reservoir. The magnitude of these fluctuations depends on the size of the reservoir. This leads...

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Veröffentlicht in:	The Journal of chemical physics 2013-09, Vol.139 (12), p.125101-125101
Hauptverfasser:	Mosgaard, Lars D, Jackson, Andrew D, Heimburg, Thomas
Format:	Artikel
Sprache:	eng
Schlagworte:	Calorimetry, Differential Scanning Hot Temperature Lipid Bilayers - chemistry Membrane Lipids - chemistry Phase Transition Thermodynamics Water - chemistry
Online-Zugang:	Volltext
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