Measurement of butyltin compounds in San Diego Bay

Inorganic tin and butyltin compounds were analysed in water samples collected from several areas within San Diego Bay. Highest concentrations of butyltins were detected in the Shelter Island and Commercial Basin Yacht harbours where anthropogenic inputs of butyltin from antifouling paints were proba...

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Veröffentlicht in:Marine pollution bulletin 1986, Vol.17 (7), p.319-324
Hauptverfasser: Valkirs, Aldis O, Seligman, Peter F, Stang, Peter M, Homer, Victoria, Lieberman, Stephen H, Vafa, Giti, Dooley, Carol A
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container_end_page 324
container_issue 7
container_start_page 319
container_title Marine pollution bulletin
container_volume 17
creator Valkirs, Aldis O
Seligman, Peter F
Stang, Peter M
Homer, Victoria
Lieberman, Stephen H
Vafa, Giti
Dooley, Carol A
description Inorganic tin and butyltin compounds were analysed in water samples collected from several areas within San Diego Bay. Highest concentrations of butyltins were detected in the Shelter Island and Commercial Basin Yacht harbours where anthropogenic inputs of butyltin from antifouling paints were probable. A distinct increase in tributyltin concentration was seen in the Shelter Island Yacht harbour over a period spanning more than 2 years, suggesting that the use of antifouling paints containing tributyltin is increasing. Samples extracted with methylisobutyl ketone and analysed by graphite furnace atomic absorption spectrophotometry consistently yielded higher tin concentrations than the same samples analysed by a hydride reduction/flame atomic absorption method, suggesting a non-hydride reducible tin fraction was present. Gas chromatographymass spectrometry confirmed the presence of tributyltin in an environmental marine water sample following derivatization to the hydride species.
doi_str_mv 10.1016/0025-326X(86)90218-3
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ispartof Marine pollution bulletin, 1986, Vol.17 (7), p.319-324
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1879-3363
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source Access via ScienceDirect (Elsevier)
subjects Applied sciences
Exact sciences and technology
Marine
Natural water pollution
Pollution
Seawaters, estuaries
Water treatment and pollution
title Measurement of butyltin compounds in San Diego Bay
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