Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties
Nanocomposites of poly(vinylidene fluoride) (PVDF) with chemically reduced graphene nanosheets (GNs) were prepared by melt mixing method and their structure and morphology characterized by SEM analysis. The addition of GNs in the PVDF matrix resulted in changes of the crystallization and melting beh...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2013-03, Vol.127 (6), p.4697-4707 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4707 |
|---|---|
| container_issue | 6 |
| container_start_page | 4697 |
| container_title | Journal of applied polymer science |
| container_volume | 127 |
| creator | El Achaby, M. Arrakhiz, F. Z. Vaudreuil, S. Essassi, E. M. Qaiss, A. Bousmina, M. |
| description | Nanocomposites of poly(vinylidene fluoride) (PVDF) with chemically reduced graphene nanosheets (GNs) were prepared by melt mixing method and their structure and morphology characterized by SEM analysis. The addition of GNs in the PVDF matrix resulted in changes of the crystallization and melting behaviors. Furthermore, increasing GNs content led to improved thermal stability of the PVDF nanocomposites in air and nitrogen, as well as significant increase in tensile and flexural properties. The nanocomposites' rheological behavior is also affected by the GNs' content. Using oscillatory rheology to monitor the GNs' dispersion, it was found that as the GNs loading increase, the Newtonian behavior disappears at low frequency. This suggests a viscoelastic behavior transition from liquid‐like to solid‐like, with greater GNs content and more homogeneous dispersion resulting in a stronger solid‐like and nonterminal behavior. By using the melt mixing method to disperse GNs, the properties of PVDF are enhanced due to the better dispersion and distribution of GNs throughout the matrix. This improvement could broaden the applications for PVDF nanocomposites. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| doi_str_mv | 10.1002/app.38081 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1439782674</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2849156341</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4331-63d72820ed5f5e26569e770dd54d4f01345cbe6aab4888d25ae3a2fcc7abfe143</originalsourceid><addsrcrecordid>eNp1kctu1DAUhi0EEkNhwRtEQkjtIq1viZ1lVcFAGcEsimBneewT4uKxUztDGR6A58bTlC6QWPlyvvMdyz9CLwk-JRjTMz2Op0xiSR6hBcGdqHlL5WO0KDVSy65rnqJnOV9jTEiD2wX6vU4w6qQnF0Olg63MUE5mguR-zZexr7bgp3rjIViw1bekxwECVEGHmAeAKddj9PvjHy7svbOHUu93MZXtyR1k4naM2U2Qq1s3DRWEQQdTVGOKI6TJQX6OnvTaZ3hxvx6hz2_fXF28q1eflu8vzle14YyRumVWUEkx2KZvgLZN24EQ2NqGW95jwnhjNtBqveFSSksbDUzT3hihNz0Qzo7Q8ewto292kCe1ddmA9zpA3GVVkE5I2ooD-uof9DruUiivU4RyKjkXlBTqZKZMijkn6NWY3FanvSJYHRJRJRF1l0hhX98bdTba96n8gssPDbTtSCsYLtzZzN06D_v_C9X5ev3XXM8dLk_w86FDp--qGEWjvnxcqkvKvi5Xlx_UFfsDYwisiA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1242844721</pqid></control><display><type>article</type><title>Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties</title><source>Wiley Online Library All Journals</source><creator>El Achaby, M. ; Arrakhiz, F. Z. ; Vaudreuil, S. ; Essassi, E. M. ; Qaiss, A. ; Bousmina, M.</creator><creatorcontrib>El Achaby, M. ; Arrakhiz, F. Z. ; Vaudreuil, S. ; Essassi, E. M. ; Qaiss, A. ; Bousmina, M.</creatorcontrib><description>Nanocomposites of poly(vinylidene fluoride) (PVDF) with chemically reduced graphene nanosheets (GNs) were prepared by melt mixing method and their structure and morphology characterized by SEM analysis. The addition of GNs in the PVDF matrix resulted in changes of the crystallization and melting behaviors. Furthermore, increasing GNs content led to improved thermal stability of the PVDF nanocomposites in air and nitrogen, as well as significant increase in tensile and flexural properties. The nanocomposites' rheological behavior is also affected by the GNs' content. Using oscillatory rheology to monitor the GNs' dispersion, it was found that as the GNs loading increase, the Newtonian behavior disappears at low frequency. This suggests a viscoelastic behavior transition from liquid‐like to solid‐like, with greater GNs content and more homogeneous dispersion resulting in a stronger solid‐like and nonterminal behavior. By using the melt mixing method to disperse GNs, the properties of PVDF are enhanced due to the better dispersion and distribution of GNs throughout the matrix. This improvement could broaden the applications for PVDF nanocomposites. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.38081</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Composites ; Dispersions ; Exact sciences and technology ; Fluorides ; Forms of application and semi-finished materials ; Graphene ; graphene, polymer nanocomposite ; Materials science ; mechanical properties ; melt blending ; Melts ; Nanocomposites ; Nanomaterials ; Nanostructure ; Polymer industry, paints, wood ; polymer nanocomposite ; Polymers ; Polyvinylidene fluorides ; Technology of polymers ; thermal properties</subject><ispartof>Journal of applied polymer science, 2013-03, Vol.127 (6), p.4697-4707</ispartof><rights>Copyright © 2012 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4331-63d72820ed5f5e26569e770dd54d4f01345cbe6aab4888d25ae3a2fcc7abfe143</citedby><cites>FETCH-LOGICAL-c4331-63d72820ed5f5e26569e770dd54d4f01345cbe6aab4888d25ae3a2fcc7abfe143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.38081$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.38081$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26916730$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>El Achaby, M.</creatorcontrib><creatorcontrib>Arrakhiz, F. Z.</creatorcontrib><creatorcontrib>Vaudreuil, S.</creatorcontrib><creatorcontrib>Essassi, E. M.</creatorcontrib><creatorcontrib>Qaiss, A.</creatorcontrib><creatorcontrib>Bousmina, M.</creatorcontrib><title>Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Nanocomposites of poly(vinylidene fluoride) (PVDF) with chemically reduced graphene nanosheets (GNs) were prepared by melt mixing method and their structure and morphology characterized by SEM analysis. The addition of GNs in the PVDF matrix resulted in changes of the crystallization and melting behaviors. Furthermore, increasing GNs content led to improved thermal stability of the PVDF nanocomposites in air and nitrogen, as well as significant increase in tensile and flexural properties. The nanocomposites' rheological behavior is also affected by the GNs' content. Using oscillatory rheology to monitor the GNs' dispersion, it was found that as the GNs loading increase, the Newtonian behavior disappears at low frequency. This suggests a viscoelastic behavior transition from liquid‐like to solid‐like, with greater GNs content and more homogeneous dispersion resulting in a stronger solid‐like and nonterminal behavior. By using the melt mixing method to disperse GNs, the properties of PVDF are enhanced due to the better dispersion and distribution of GNs throughout the matrix. This improvement could broaden the applications for PVDF nanocomposites. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Dispersions</subject><subject>Exact sciences and technology</subject><subject>Fluorides</subject><subject>Forms of application and semi-finished materials</subject><subject>Graphene</subject><subject>graphene, polymer nanocomposite</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>melt blending</subject><subject>Melts</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Polymer industry, paints, wood</subject><subject>polymer nanocomposite</subject><subject>Polymers</subject><subject>Polyvinylidene fluorides</subject><subject>Technology of polymers</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kctu1DAUhi0EEkNhwRtEQkjtIq1viZ1lVcFAGcEsimBneewT4uKxUztDGR6A58bTlC6QWPlyvvMdyz9CLwk-JRjTMz2Op0xiSR6hBcGdqHlL5WO0KDVSy65rnqJnOV9jTEiD2wX6vU4w6qQnF0Olg63MUE5mguR-zZexr7bgp3rjIViw1bekxwECVEGHmAeAKddj9PvjHy7svbOHUu93MZXtyR1k4naM2U2Qq1s3DRWEQQdTVGOKI6TJQX6OnvTaZ3hxvx6hz2_fXF28q1eflu8vzle14YyRumVWUEkx2KZvgLZN24EQ2NqGW95jwnhjNtBqveFSSksbDUzT3hihNz0Qzo7Q8ewto292kCe1ddmA9zpA3GVVkE5I2ooD-uof9DruUiivU4RyKjkXlBTqZKZMijkn6NWY3FanvSJYHRJRJRF1l0hhX98bdTba96n8gssPDbTtSCsYLtzZzN06D_v_C9X5ev3XXM8dLk_w86FDp--qGEWjvnxcqkvKvi5Xlx_UFfsDYwisiA</recordid><startdate>20130315</startdate><enddate>20130315</enddate><creator>El Achaby, M.</creator><creator>Arrakhiz, F. Z.</creator><creator>Vaudreuil, S.</creator><creator>Essassi, E. M.</creator><creator>Qaiss, A.</creator><creator>Bousmina, M.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130315</creationdate><title>Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties</title><author>El Achaby, M. ; Arrakhiz, F. Z. ; Vaudreuil, S. ; Essassi, E. M. ; Qaiss, A. ; Bousmina, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4331-63d72820ed5f5e26569e770dd54d4f01345cbe6aab4888d25ae3a2fcc7abfe143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Dispersions</topic><topic>Exact sciences and technology</topic><topic>Fluorides</topic><topic>Forms of application and semi-finished materials</topic><topic>Graphene</topic><topic>graphene, polymer nanocomposite</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>melt blending</topic><topic>Melts</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Polymer industry, paints, wood</topic><topic>polymer nanocomposite</topic><topic>Polymers</topic><topic>Polyvinylidene fluorides</topic><topic>Technology of polymers</topic><topic>thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El Achaby, M.</creatorcontrib><creatorcontrib>Arrakhiz, F. Z.</creatorcontrib><creatorcontrib>Vaudreuil, S.</creatorcontrib><creatorcontrib>Essassi, E. M.</creatorcontrib><creatorcontrib>Qaiss, A.</creatorcontrib><creatorcontrib>Bousmina, M.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El Achaby, M.</au><au>Arrakhiz, F. Z.</au><au>Vaudreuil, S.</au><au>Essassi, E. M.</au><au>Qaiss, A.</au><au>Bousmina, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2013-03-15</date><risdate>2013</risdate><volume>127</volume><issue>6</issue><spage>4697</spage><epage>4707</epage><pages>4697-4707</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Nanocomposites of poly(vinylidene fluoride) (PVDF) with chemically reduced graphene nanosheets (GNs) were prepared by melt mixing method and their structure and morphology characterized by SEM analysis. The addition of GNs in the PVDF matrix resulted in changes of the crystallization and melting behaviors. Furthermore, increasing GNs content led to improved thermal stability of the PVDF nanocomposites in air and nitrogen, as well as significant increase in tensile and flexural properties. The nanocomposites' rheological behavior is also affected by the GNs' content. Using oscillatory rheology to monitor the GNs' dispersion, it was found that as the GNs loading increase, the Newtonian behavior disappears at low frequency. This suggests a viscoelastic behavior transition from liquid‐like to solid‐like, with greater GNs content and more homogeneous dispersion resulting in a stronger solid‐like and nonterminal behavior. By using the melt mixing method to disperse GNs, the properties of PVDF are enhanced due to the better dispersion and distribution of GNs throughout the matrix. This improvement could broaden the applications for PVDF nanocomposites. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.38081</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2013-03, Vol.127 (6), p.4697-4707 |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1439782674 |
| source | Wiley Online Library All Journals |
| subjects | Applied sciences Composites Dispersions Exact sciences and technology Fluorides Forms of application and semi-finished materials Graphene graphene, polymer nanocomposite Materials science mechanical properties melt blending Melts Nanocomposites Nanomaterials Nanostructure Polymer industry, paints, wood polymer nanocomposite Polymers Polyvinylidene fluorides Technology of polymers thermal properties |
| title | Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T14%3A10%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20and%20characterization%20of%20melt-blended%20graphene%20nanosheets-poly(vinylidene%20fluoride)%20nanocomposites%20with%20enhanced%20properties&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=El%20Achaby,%20M.&rft.date=2013-03-15&rft.volume=127&rft.issue=6&rft.spage=4697&rft.epage=4707&rft.pages=4697-4707&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.38081&rft_dat=%3Cproquest_cross%3E2849156341%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1242844721&rft_id=info:pmid/&rfr_iscdi=true |