A study on thermal behavior of a poly(VDF-CTFE) copolymers binder for high energy materials
This article describes a study on thermal behavior of poly(vinylidene fluoride‐chlorotrifluoroetheylene) [poly(VDF‐CTFE)] copolymers as polymeric binders of specific interest for high energy materials (HEMs) composites by thermal analytical techniques. The non‐isothermal thermogravimetry (TG) for po...
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| Veröffentlicht in: | Journal of applied polymer science 2013-02, Vol.127 (3), p.1751-1757 |
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| container_title | Journal of applied polymer science |
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| creator | Singh, Arjun Soni, P. K. Shekharam, T. Srivastava, Alok |
| description | This article describes a study on thermal behavior of poly(vinylidene fluoride‐chlorotrifluoroetheylene) [poly(VDF‐CTFE)] copolymers as polymeric binders of specific interest for high energy materials (HEMs) composites by thermal analytical techniques. The non‐isothermal thermogravimetry (TG) for poly (VDF‐CTFE) copolymers was recorded in air and N2 atmospheres. The results of TG thermograms show that poly(VDF‐CTFE) copolymers get degrade at lower temperature when in air than in N2 atmosphere. In the derivative curve, there was single maximum degradation peak (Tmax) indicating one‐stage degradation of poly(VDF‐CTFE) copolymers for all the samples. The other thermal properties such as glass transition temperature (Tg) and degradation temperature (Td) for poly(VDF‐CTFE) copolymers were measured by employing differential scanning calorimeter (DSC) technique. The kinetic parameters related to thermal degradation of poly(VDF‐CTFE) copolymers were investigated through non‐isothermal Kissinger kinetic method using DSC method. The activation energies for thermal degradation of poly(VDF‐CTFE) copolymers were found in a range of 218–278 kJ/mol. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| doi_str_mv | 10.1002/app.37780 |
| format | Article |
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K. ; Shekharam, T. ; Srivastava, Alok</creator><creatorcontrib>Singh, Arjun ; Soni, P. K. ; Shekharam, T. ; Srivastava, Alok</creatorcontrib><description>This article describes a study on thermal behavior of poly(vinylidene fluoride‐chlorotrifluoroetheylene) [poly(VDF‐CTFE)] copolymers as polymeric binders of specific interest for high energy materials (HEMs) composites by thermal analytical techniques. The non‐isothermal thermogravimetry (TG) for poly (VDF‐CTFE) copolymers was recorded in air and N2 atmospheres. The results of TG thermograms show that poly(VDF‐CTFE) copolymers get degrade at lower temperature when in air than in N2 atmosphere. In the derivative curve, there was single maximum degradation peak (Tmax) indicating one‐stage degradation of poly(VDF‐CTFE) copolymers for all the samples. The other thermal properties such as glass transition temperature (Tg) and degradation temperature (Td) for poly(VDF‐CTFE) copolymers were measured by employing differential scanning calorimeter (DSC) technique. The kinetic parameters related to thermal degradation of poly(VDF‐CTFE) copolymers were investigated through non‐isothermal Kissinger kinetic method using DSC method. The activation energies for thermal degradation of poly(VDF‐CTFE) copolymers were found in a range of 218–278 kJ/mol. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. 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K.</creatorcontrib><creatorcontrib>Shekharam, T.</creatorcontrib><creatorcontrib>Srivastava, Alok</creatorcontrib><title>A study on thermal behavior of a poly(VDF-CTFE) copolymers binder for high energy materials</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>This article describes a study on thermal behavior of poly(vinylidene fluoride‐chlorotrifluoroetheylene) [poly(VDF‐CTFE)] copolymers as polymeric binders of specific interest for high energy materials (HEMs) composites by thermal analytical techniques. The non‐isothermal thermogravimetry (TG) for poly (VDF‐CTFE) copolymers was recorded in air and N2 atmospheres. The results of TG thermograms show that poly(VDF‐CTFE) copolymers get degrade at lower temperature when in air than in N2 atmosphere. In the derivative curve, there was single maximum degradation peak (Tmax) indicating one‐stage degradation of poly(VDF‐CTFE) copolymers for all the samples. The other thermal properties such as glass transition temperature (Tg) and degradation temperature (Td) for poly(VDF‐CTFE) copolymers were measured by employing differential scanning calorimeter (DSC) technique. The kinetic parameters related to thermal degradation of poly(VDF‐CTFE) copolymers were investigated through non‐isothermal Kissinger kinetic method using DSC method. The activation energies for thermal degradation of poly(VDF‐CTFE) copolymers were found in a range of 218–278 kJ/mol. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><subject>Applied sciences</subject><subject>Binders</subject><subject>Chemical reactions and properties</subject><subject>Copolymers</subject><subject>Degradation</subject><subject>Derivatives</subject><subject>differential scanning calorimeter</subject><subject>Differential scanning calorimetry</subject><subject>Exact sciences and technology</subject><subject>fluoropolymer</subject><subject>Materials science</subject><subject>Mathematical analysis</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Reproduction</subject><subject>Thermal degradation</subject><subject>thermal kinetics</subject><subject>thermal properties</subject><subject>thermogravimetry</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kMFu1DAQhi0EEkvhwBtYQkjtIa3HjhP7uFq6W6SKRqLAgYPl9dpdlyRO7Sxt3h4vW3qoxGmkme__NPoReg_kFAihZ3oYTlldC_ICzYDIuigrKl6iWb5BIaTkr9GblG4JAeCkmqGfc5zG3WbCocfj1sZOt3htt_q3DxEHhzUeQjsdf_-0LBbXy_MTbMJ-0dmY8Nr3Gxuxy-TW32yx7W28mXCnRxu9btNb9MrlYd89ziP0bXl-vbgoLq9Wnxfzy8KUjJOiEja_o4WsLHUcuBSlM04Lzg2UYm0M0LWpJN_UYDjTpiyFoM6B1JoyLYAdoeODd4jhbmfTqDqfjG1b3duwSwpKJmtBGS0z-uEZeht2sc_fKQDKOa0E7IUnB8rEkFK0Tg3RdzpOCoja16xyzepvzZn9-GjUyejWRd0bn54CtJJQMy4yd3bg7n1rp_8L1bxp_pmLQ8Kn0T48JXT8paqa1Vz9-LJSDW8uGv51pRj7AzPnmHY</recordid><startdate>20130205</startdate><enddate>20130205</enddate><creator>Singh, Arjun</creator><creator>Soni, P. 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K. ; Shekharam, T. ; Srivastava, Alok</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4350-68e001a896e2f515984fcfa855c148bcc12bc695d71c53ac44882ff19aa23a813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Binders</topic><topic>Chemical reactions and properties</topic><topic>Copolymers</topic><topic>Degradation</topic><topic>Derivatives</topic><topic>differential scanning calorimeter</topic><topic>Differential scanning calorimetry</topic><topic>Exact sciences and technology</topic><topic>fluoropolymer</topic><topic>Materials science</topic><topic>Mathematical analysis</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Reproduction</topic><topic>Thermal degradation</topic><topic>thermal kinetics</topic><topic>thermal properties</topic><topic>thermogravimetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Arjun</creatorcontrib><creatorcontrib>Soni, P. K.</creatorcontrib><creatorcontrib>Shekharam, T.</creatorcontrib><creatorcontrib>Srivastava, Alok</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Arjun</au><au>Soni, P. K.</au><au>Shekharam, T.</au><au>Srivastava, Alok</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A study on thermal behavior of a poly(VDF-CTFE) copolymers binder for high energy materials</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2013-02-05</date><risdate>2013</risdate><volume>127</volume><issue>3</issue><spage>1751</spage><epage>1757</epage><pages>1751-1757</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>This article describes a study on thermal behavior of poly(vinylidene fluoride‐chlorotrifluoroetheylene) [poly(VDF‐CTFE)] copolymers as polymeric binders of specific interest for high energy materials (HEMs) composites by thermal analytical techniques. The non‐isothermal thermogravimetry (TG) for poly (VDF‐CTFE) copolymers was recorded in air and N2 atmospheres. The results of TG thermograms show that poly(VDF‐CTFE) copolymers get degrade at lower temperature when in air than in N2 atmosphere. In the derivative curve, there was single maximum degradation peak (Tmax) indicating one‐stage degradation of poly(VDF‐CTFE) copolymers for all the samples. The other thermal properties such as glass transition temperature (Tg) and degradation temperature (Td) for poly(VDF‐CTFE) copolymers were measured by employing differential scanning calorimeter (DSC) technique. The kinetic parameters related to thermal degradation of poly(VDF‐CTFE) copolymers were investigated through non‐isothermal Kissinger kinetic method using DSC method. The activation energies for thermal degradation of poly(VDF‐CTFE) copolymers were found in a range of 218–278 kJ/mol. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.37780</doi><tpages>7</tpages></addata></record> |
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| subjects | Applied sciences Binders Chemical reactions and properties Copolymers Degradation Derivatives differential scanning calorimeter Differential scanning calorimetry Exact sciences and technology fluoropolymer Materials science Mathematical analysis Organic polymers Physicochemistry of polymers Polymers Reproduction Thermal degradation thermal kinetics thermal properties thermogravimetry |
| title | A study on thermal behavior of a poly(VDF-CTFE) copolymers binder for high energy materials |
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