Facile synthesis and micellization of biodegradable poly(decamethylene succinate)-graft-poly(ethylene glycol)
In this article, we report the facile one‐pot synthesis of poly(decamethylene succinate) (PDS) with multiple hydroxyl groups by direct polycondensation with malic acid (MA) as the functional monomer and dysprosium triflate as the chemoselective catalyst at 80°C. The secondary hydroxyl groups of mali...
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| Veröffentlicht in: | Journal of applied polymer science 2013-06, Vol.128 (5), p.2817-2822 |
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| container_title | Journal of applied polymer science |
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| creator | Zhu, Guixiang Wang, Ying Zhu, Weipu Zhu, Kui Xu, Xiaoyan Shen, Zhiquan |
| description | In this article, we report the facile one‐pot synthesis of poly(decamethylene succinate) (PDS) with multiple hydroxyl groups by direct polycondensation with malic acid (MA) as the functional monomer and dysprosium triflate as the chemoselective catalyst at 80°C. The secondary hydroxyl groups of malic units were inactive during the polycondensation process. The density of hydroxyl groups of the copolymer could be well‐controlled by the molar ratio of succinic acid and MA in the feed. These hydroxylated PDSs were grafted by poly(ethylene glycol) (PEG) through a simple esterification reaction; this resulted in amphiphilic PDS‐g‐PEG copolymers, which could undergo micellization in aqueous media to form nanosized aggregates with diverse morphologies and diameters. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013. |
| doi_str_mv | 10.1002/app.38327 |
| format | Article |
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The secondary hydroxyl groups of malic units were inactive during the polycondensation process. The density of hydroxyl groups of the copolymer could be well‐controlled by the molar ratio of succinic acid and MA in the feed. These hydroxylated PDSs were grafted by poly(ethylene glycol) (PEG) through a simple esterification reaction; this resulted in amphiphilic PDS‐g‐PEG copolymers, which could undergo micellization in aqueous media to form nanosized aggregates with diverse morphologies and diameters. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. 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Sci., 2013.</description><subject>Applied sciences</subject><subject>biodegradable</subject><subject>Exact sciences and technology</subject><subject>grafting</subject><subject>Materials science</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polycondensation</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kUFrFTEUhYMo-Kwu_AcDIvQtpk0myWSyLMW-Cg8tUim4CTeZpE3NTMZkHjr-etO--haCq7u43znccy5Cbwk-IRg3pzBNJ7SjjXiGVgRLUbO26Z6jVdmRupOSv0Svcr7HmBCO2xUaLsD4YKu8jPOdzT5XMPbV4I0Nwf-G2cexiq7SPvb2NkEPusBTDMtxbw0Mdr5bgh2LfmeMH2G267pgbq4fmcP6NiwmhvVr9MJByPbN0zxCXy8-XJ9f1tvPm4_nZ9vaMMpFDa3sLDNUMIeBdBSgsYwL7aQWpDXccse1kMTRVnPeaIO7vtOkJ5p1TDJOj9Dx3ndK8cfO5lkNPj9EgtHGXVaEUSk6LFpR0Hf_oPdxl8ZynSKUMCEFb0mh1nvKpJhzsk5NyQ-QFkWweiheleLVY_GFff_kCNlAcAlG4_NB0JQILeG0cKd77md5wPJ_Q3V2dfXXud4rfJ7tr4MC0ndVkgiubj5tlNxuyJebb5fqmv4BD4mhmQ</recordid><startdate>20130605</startdate><enddate>20130605</enddate><creator>Zhu, Guixiang</creator><creator>Wang, Ying</creator><creator>Zhu, Weipu</creator><creator>Zhu, Kui</creator><creator>Xu, Xiaoyan</creator><creator>Shen, Zhiquan</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7QO</scope><scope>7T7</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20130605</creationdate><title>Facile synthesis and micellization of biodegradable poly(decamethylene succinate)-graft-poly(ethylene glycol)</title><author>Zhu, Guixiang ; Wang, Ying ; Zhu, Weipu ; Zhu, Kui ; Xu, Xiaoyan ; Shen, Zhiquan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4357-a698e4c374f0a183aa2e457bf9b716c5e5f5b791f36b552bc08d8b1d1b4849453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>biodegradable</topic><topic>Exact sciences and technology</topic><topic>grafting</topic><topic>Materials science</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polycondensation</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, Guixiang</creatorcontrib><creatorcontrib>Wang, Ying</creatorcontrib><creatorcontrib>Zhu, Weipu</creatorcontrib><creatorcontrib>Zhu, Kui</creatorcontrib><creatorcontrib>Xu, Xiaoyan</creatorcontrib><creatorcontrib>Shen, Zhiquan</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Biotechnology Research Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, Guixiang</au><au>Wang, Ying</au><au>Zhu, Weipu</au><au>Zhu, Kui</au><au>Xu, Xiaoyan</au><au>Shen, Zhiquan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis and micellization of biodegradable poly(decamethylene succinate)-graft-poly(ethylene glycol)</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2013-06-05</date><risdate>2013</risdate><volume>128</volume><issue>5</issue><spage>2817</spage><epage>2822</epage><pages>2817-2822</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>In this article, we report the facile one‐pot synthesis of poly(decamethylene succinate) (PDS) with multiple hydroxyl groups by direct polycondensation with malic acid (MA) as the functional monomer and dysprosium triflate as the chemoselective catalyst at 80°C. The secondary hydroxyl groups of malic units were inactive during the polycondensation process. The density of hydroxyl groups of the copolymer could be well‐controlled by the molar ratio of succinic acid and MA in the feed. These hydroxylated PDSs were grafted by poly(ethylene glycol) (PEG) through a simple esterification reaction; this resulted in amphiphilic PDS‐g‐PEG copolymers, which could undergo micellization in aqueous media to form nanosized aggregates with diverse morphologies and diameters. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.38327</doi><tpages>6</tpages></addata></record> |
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| subjects | Applied sciences biodegradable Exact sciences and technology grafting Materials science Organic polymers Physicochemistry of polymers Polycondensation Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Facile synthesis and micellization of biodegradable poly(decamethylene succinate)-graft-poly(ethylene glycol) |
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