Crystal growth and characterization of potassium(I)-doped tetrakis(thiourea)nickel(II) chloride
The influence of alkali metal potassium(I)-doping on the properties of tetrakis(thiourea)nickel(II) chloride crystals has been investigated. The variation in the intensity observed in powder X-ray diffraction (XRD) of doped specimen and slight shifts in vibrational frequencies confirm the lattice st...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2013-05, Vol.112 (2), p.1101-1106 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Muthu, K. Meenatchi, V. Rajasekar, M. Meenakshisundaram, S. P. Mojumdar, S. C. |
| description | The influence of alkali metal potassium(I)-doping on the properties of tetrakis(thiourea)nickel(II) chloride crystals has been investigated. The variation in the intensity observed in powder X-ray diffraction (XRD) of doped specimen and slight shifts in vibrational frequencies confirm the lattice stress as a result of doping. Surface morphological changes due to doping of the alkali metal are observed by scanning electron microscopy. The incorporation of K(I)- into the crystal lattice was confirmed by energy dispersive X-ray spectroscopy. Lattice parameters are determined by single crystal XRD analysis. The thermogravimetric and differential thermal analysis studies reveal the purity of the materials and no decomposition is observed up to the melting point. The crystal is further characterized by UV–Vis and Kurtz powder technique. |
| doi_str_mv | 10.1007/s10973-013-3100-9 |
| format | Article |
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P.</creatorcontrib><creatorcontrib>Mojumdar, S. C.</creatorcontrib><title>Crystal growth and characterization of potassium(I)-doped tetrakis(thiourea)nickel(II) chloride</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The influence of alkali metal potassium(I)-doping on the properties of tetrakis(thiourea)nickel(II) chloride crystals has been investigated. The variation in the intensity observed in powder X-ray diffraction (XRD) of doped specimen and slight shifts in vibrational frequencies confirm the lattice stress as a result of doping. Surface morphological changes due to doping of the alkali metal are observed by scanning electron microscopy. The incorporation of K(I)- into the crystal lattice was confirmed by energy dispersive X-ray spectroscopy. Lattice parameters are determined by single crystal XRD analysis. The thermogravimetric and differential thermal analysis studies reveal the purity of the materials and no decomposition is observed up to the melting point. The crystal is further characterized by UV–Vis and Kurtz powder technique.</description><subject>Alkali metals</subject><subject>Analytical Chemistry</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Crystal lattices</subject><subject>Crystals</subject><subject>Diffraction</subject><subject>Doping</subject><subject>Exact sciences and technology</subject><subject>Fundamental areas of phenomenology (including applications)</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Melting points</subject><subject>Optical materials</subject><subject>Optics</subject><subject>Other nonlinear optical materials; photorefractive and semiconductor materials</subject><subject>Physical Chemistry</subject><subject>Physics</subject><subject>Polymer Sciences</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRSMEElXpB7DLBildBPyInXiJKh6VKrGBteU4k9Y0jYPtCJWvx1UqlqxmNHPv1cxJkluM7jFC5YPHSJQ0R5jmNA5ycZHMMKuqnAjCL2NPY88xQ9fJwntTI4IRF6wSs0Su3NEH1aVbZ7_DLlV9k-qdckoHcOZHBWP71LbpYIOK1vGQrZd5Ywdo0gDBqb3xWdgZOzpQy97oPXTZer2MGZ11poGb5KpVnYfFuc6Tj-en99Vrvnl7Wa8eN7mmDIdcM1pxRnjDgSLGqMaiBq0KXFEGolRc17QkDeiWgmgJxbrglcCsiJUhUtN5kk25g7NfI_ggD8Zr6DrVgx29xAUVJS8LSqIUT1LtrPcOWjk4c1DuKDGSJ55y4ikjT3niKUX03J3jldeqa53qtfF_RlLyeBM56cik83HVb8HJz4imj5__E_4Ljn-E8g</recordid><startdate>20130501</startdate><enddate>20130501</enddate><creator>Muthu, K.</creator><creator>Meenatchi, V.</creator><creator>Rajasekar, M.</creator><creator>Meenakshisundaram, S. 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C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal growth and characterization of potassium(I)-doped tetrakis(thiourea)nickel(II) chloride</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2013-05-01</date><risdate>2013</risdate><volume>112</volume><issue>2</issue><spage>1101</spage><epage>1106</epage><pages>1101-1106</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>The influence of alkali metal potassium(I)-doping on the properties of tetrakis(thiourea)nickel(II) chloride crystals has been investigated. The variation in the intensity observed in powder X-ray diffraction (XRD) of doped specimen and slight shifts in vibrational frequencies confirm the lattice stress as a result of doping. Surface morphological changes due to doping of the alkali metal are observed by scanning electron microscopy. The incorporation of K(I)- into the crystal lattice was confirmed by energy dispersive X-ray spectroscopy. Lattice parameters are determined by single crystal XRD analysis. The thermogravimetric and differential thermal analysis studies reveal the purity of the materials and no decomposition is observed up to the melting point. The crystal is further characterized by UV–Vis and Kurtz powder technique.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-013-3100-9</doi><tpages>6</tpages></addata></record> |
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| subjects | Alkali metals Analytical Chemistry Calorimetry Chemistry Chemistry and Materials Science Chlorides Crystal lattices Crystals Diffraction Doping Exact sciences and technology Fundamental areas of phenomenology (including applications) Inorganic Chemistry Measurement Science and Instrumentation Melting points Optical materials Optics Other nonlinear optical materials photorefractive and semiconductor materials Physical Chemistry Physics Polymer Sciences |
| title | Crystal growth and characterization of potassium(I)-doped tetrakis(thiourea)nickel(II) chloride |
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