Ring-opening metathesis polymerization of bicyclo[2.2.1]hepta-2,5-diene (norbornadiene) initiated by new ruthenium(II) complex
The polymerization of norbornadiene (NBD) initiated by a novel ruthenium (Ru)(II) complex (3) containing 1,1′‐pyridine‐2,6‐diylbis[3‐(dimethylamino)prop‐2‐en‐1‐one] (1) as ligand has been investigated. Ru complexes exhibit more catalytic activity in the ring‐opening metathesis polymerization (ROMP)...
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| Veröffentlicht in: | Journal of applied polymer science 2013-02, Vol.127 (3), p.1691-1696 |
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| container_title | Journal of applied polymer science |
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| creator | Yalçınkaya, Esra Evrim Dayan, Osman Balcan, Mehmet Güler, Çetin |
| description | The polymerization of norbornadiene (NBD) initiated by a novel ruthenium (Ru)(II) complex (3) containing 1,1′‐pyridine‐2,6‐diylbis[3‐(dimethylamino)prop‐2‐en‐1‐one] (1) as ligand has been investigated. Ru complexes exhibit more catalytic activity in the ring‐opening metathesis polymerization (ROMP) of NBD when activated with trimethylsilyldiazomethane (TMSD). The influence of the various experimental parameters such as reaction time and temperature, nature of the solvent and catalyst, ratio of the NBD/Ru, and TMSD addition has been investigated. The polymers have been obtained in high yields with a relatively low polydispersity index for ROMP and a high
$ \bar M_n $
and
$ \bar M_w $
values in a monomodal distribution. Their structures have been determined by means of FTIR and 1H‐NMR spectroscopy. Thermal properties have been determined via thermogravimetric analysis and DTG methods. The NBD polymerization results that initiated by Ru‐based catalyst coordinated to amine ligand have been compared to initiated by [RuCl2(p‐cymene)]2. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| doi_str_mv | 10.1002/app.37867 |
| format | Article |
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$ \bar M_n $
and
$ \bar M_w $
values in a monomodal distribution. Their structures have been determined by means of FTIR and 1H‐NMR spectroscopy. Thermal properties have been determined via thermogravimetric analysis and DTG methods. The NBD polymerization results that initiated by Ru‐based catalyst coordinated to amine ligand have been compared to initiated by [RuCl2(p‐cymene)]2. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.37867</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Catalysts ; characterization ; Decomposition reactions ; Exact sciences and technology ; Ligands ; Materials science ; Metathesis ; norbornadiene ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Reproduction ; ring-opening metathesis polymerization ; Ruthenium ; ruthenium-based catalyst ; Solvents</subject><ispartof>Journal of applied polymer science, 2013-02, Vol.127 (3), p.1691-1696</ispartof><rights>Copyright © 2012 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4357-56b8d5bb98dfdcc1c4b421c611237b2e18454f31a01a88bd678bbef197349b7c3</citedby><cites>FETCH-LOGICAL-c4357-56b8d5bb98dfdcc1c4b421c611237b2e18454f31a01a88bd678bbef197349b7c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.37867$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.37867$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26917349$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yalçınkaya, Esra Evrim</creatorcontrib><creatorcontrib>Dayan, Osman</creatorcontrib><creatorcontrib>Balcan, Mehmet</creatorcontrib><creatorcontrib>Güler, Çetin</creatorcontrib><title>Ring-opening metathesis polymerization of bicyclo[2.2.1]hepta-2,5-diene (norbornadiene) initiated by new ruthenium(II) complex</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The polymerization of norbornadiene (NBD) initiated by a novel ruthenium (Ru)(II) complex (3) containing 1,1′‐pyridine‐2,6‐diylbis[3‐(dimethylamino)prop‐2‐en‐1‐one] (1) as ligand has been investigated. Ru complexes exhibit more catalytic activity in the ring‐opening metathesis polymerization (ROMP) of NBD when activated with trimethylsilyldiazomethane (TMSD). The influence of the various experimental parameters such as reaction time and temperature, nature of the solvent and catalyst, ratio of the NBD/Ru, and TMSD addition has been investigated. The polymers have been obtained in high yields with a relatively low polydispersity index for ROMP and a high
$ \bar M_n $
and
$ \bar M_w $
values in a monomodal distribution. Their structures have been determined by means of FTIR and 1H‐NMR spectroscopy. Thermal properties have been determined via thermogravimetric analysis and DTG methods. The NBD polymerization results that initiated by Ru‐based catalyst coordinated to amine ligand have been compared to initiated by [RuCl2(p‐cymene)]2. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><subject>Applied sciences</subject><subject>Catalysts</subject><subject>characterization</subject><subject>Decomposition reactions</subject><subject>Exact sciences and technology</subject><subject>Ligands</subject><subject>Materials science</subject><subject>Metathesis</subject><subject>norbornadiene</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Reproduction</subject><subject>ring-opening metathesis polymerization</subject><subject>Ruthenium</subject><subject>ruthenium-based catalyst</subject><subject>Solvents</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kcFq3DAURU1poNMki_6BoBRmoJ74yZZlLUNop1NCOxkSuihFSLLcKLUlR7JJ3EW_vcpMmkUhq4d45x70uEnyBrIlZBk-EX2_zGlV0hfJDDJG06LE1ctkFneQVoyRV8nrEG6yDIBk5Sz5szX2Z-p6beNEnR7EcK2DCah37dRpb36LwTiLXIOkUZNq3Xe8xEv4ca37QaT4PUlro61Gc-u8dN6K3XOBjDWDEYOukZyQ1XfIj9FszdjN1-sFUq7rW31_lBw0og36-HEeJlcfP1yefUrPv67WZ6fnqSpyQlNSyqomUrKqbmqlQBWywKBKAJxTiTVUBSmaHEQGoqpkXdJKSt0Ao3nBJFX5YTLfe3vvbkcdBt6ZoHTbCqvdGDgUOaMlxoxF9O1_6I0b411tpAATgku6oxZ7SnkXgtcN773phJ84ZPyhCR6b4LsmIvvu0SiCEm3jhVUmPAVwyeDhn5E72XN3ptXT80J-utn8M6f7hAmDvn9KCP-Lxy0l_NuXFb_YFNvt5_yCr_K_XB-miA</recordid><startdate>20130205</startdate><enddate>20130205</enddate><creator>Yalçınkaya, Esra Evrim</creator><creator>Dayan, Osman</creator><creator>Balcan, Mehmet</creator><creator>Güler, Çetin</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130205</creationdate><title>Ring-opening metathesis polymerization of bicyclo[2.2.1]hepta-2,5-diene (norbornadiene) initiated by new ruthenium(II) complex</title><author>Yalçınkaya, Esra Evrim ; Dayan, Osman ; Balcan, Mehmet ; Güler, Çetin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4357-56b8d5bb98dfdcc1c4b421c611237b2e18454f31a01a88bd678bbef197349b7c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Catalysts</topic><topic>characterization</topic><topic>Decomposition reactions</topic><topic>Exact sciences and technology</topic><topic>Ligands</topic><topic>Materials science</topic><topic>Metathesis</topic><topic>norbornadiene</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Reproduction</topic><topic>ring-opening metathesis polymerization</topic><topic>Ruthenium</topic><topic>ruthenium-based catalyst</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yalçınkaya, Esra Evrim</creatorcontrib><creatorcontrib>Dayan, Osman</creatorcontrib><creatorcontrib>Balcan, Mehmet</creatorcontrib><creatorcontrib>Güler, Çetin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yalçınkaya, Esra Evrim</au><au>Dayan, Osman</au><au>Balcan, Mehmet</au><au>Güler, Çetin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ring-opening metathesis polymerization of bicyclo[2.2.1]hepta-2,5-diene (norbornadiene) initiated by new ruthenium(II) complex</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2013-02-05</date><risdate>2013</risdate><volume>127</volume><issue>3</issue><spage>1691</spage><epage>1696</epage><pages>1691-1696</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The polymerization of norbornadiene (NBD) initiated by a novel ruthenium (Ru)(II) complex (3) containing 1,1′‐pyridine‐2,6‐diylbis[3‐(dimethylamino)prop‐2‐en‐1‐one] (1) as ligand has been investigated. Ru complexes exhibit more catalytic activity in the ring‐opening metathesis polymerization (ROMP) of NBD when activated with trimethylsilyldiazomethane (TMSD). The influence of the various experimental parameters such as reaction time and temperature, nature of the solvent and catalyst, ratio of the NBD/Ru, and TMSD addition has been investigated. The polymers have been obtained in high yields with a relatively low polydispersity index for ROMP and a high
$ \bar M_n $
and
$ \bar M_w $
values in a monomodal distribution. Their structures have been determined by means of FTIR and 1H‐NMR spectroscopy. Thermal properties have been determined via thermogravimetric analysis and DTG methods. The NBD polymerization results that initiated by Ru‐based catalyst coordinated to amine ligand have been compared to initiated by [RuCl2(p‐cymene)]2. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.37867</doi><tpages>6</tpages></addata></record> |
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| subjects | Applied sciences Catalysts characterization Decomposition reactions Exact sciences and technology Ligands Materials science Metathesis norbornadiene Organic polymers Physicochemistry of polymers Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Reproduction ring-opening metathesis polymerization Ruthenium ruthenium-based catalyst Solvents |
| title | Ring-opening metathesis polymerization of bicyclo[2.2.1]hepta-2,5-diene (norbornadiene) initiated by new ruthenium(II) complex |
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