Polymer nanocomposite coatings based on polyhedral oligosilsesquioxanes: route for industrial manufacturing and barrier properties
A route to a large variety of functionalized POSS compounds by a two-step procedure has been developed. Up-scaling to high volume industrial applications is feasible. In the first step, an amino-functionalized silane such as 3-aminopropyltriethoxy silane is converted to amino-functionalized POSS (am...
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| Veröffentlicht in: | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2011-10, Vol.13 (10), p.4691-4701 |
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| creator | Männle, Ferdinand Rosquist Tofteberg, Terje Skaugen, Morten Bu, Huaitian Peters, Thijs Dietzel, Pascal D. C. Pilz, Monika |
| description | A route to a large variety of functionalized POSS compounds by a two-step procedure has been developed. Up-scaling to high volume industrial applications is feasible. In the first step, an amino-functionalized silane such as 3-aminopropyltriethoxy silane is converted to amino-functionalized POSS (amine-POSS) by a sol–gel process. In the second step, the amine groups of amine-POSS are converted by state-of-the-art amine chemistry. A large number of reactants including carboxylic acids, esters, anhydrides, isocyanates, carbonates, epoxides, and acrylates as well as reactants suitable for nucleophilic substitution can be applied. Conversion of an amine-POSS with hexanoic acid leads to an amide-POSS. Amine chemistry can usually be performed under mild conditions, which suppresses degradation and/or cross-linking reactions of the amine-POSS during the conversion. MALDI-TOF mass spectroscopy and dynamic light scattering (particle size: 3–6 nm) have been applied to prove the conversion of an amine-POSS to an amide-POSS.
1
H-NMR and TGA-MS prove the presence of amide-POSS and its thermal stability. Gas barrier properties of nanocomposite coatings based on functionalized POSS are characterized. |
| doi_str_mv | 10.1007/s11051-011-0435-7 |
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1
H-NMR and TGA-MS prove the presence of amide-POSS and its thermal stability. Gas barrier properties of nanocomposite coatings based on functionalized POSS are characterized.</description><identifier>ISSN: 1388-0764</identifier><identifier>EISSN: 1572-896X</identifier><identifier>DOI: 10.1007/s11051-011-0435-7</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Amines ; Barriers ; Carbonates ; Carboxylic acids ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Coatings ; Conversion ; Esters ; Inorganic Chemistry ; Isocyanates ; Lasers ; Light scattering ; Mass spectroscopy ; Materials Science ; Nanocomposites ; Nanomaterials ; Nanoparticles ; Nanostructure ; Nanotechnology ; Optical Devices ; Optics ; Photonics ; Physical Chemistry ; Polymers ; Research Paper ; Silanes</subject><ispartof>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology, 2011-10, Vol.13 (10), p.4691-4701</ispartof><rights>Springer Science+Business Media B.V. 2011</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-5cf09b44eb398887d67c9c2406d9ec8b5996546ee1aa4647e4fdd8b7cefa961a3</citedby><cites>FETCH-LOGICAL-c349t-5cf09b44eb398887d67c9c2406d9ec8b5996546ee1aa4647e4fdd8b7cefa961a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11051-011-0435-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11051-011-0435-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Männle, Ferdinand</creatorcontrib><creatorcontrib>Rosquist Tofteberg, Terje</creatorcontrib><creatorcontrib>Skaugen, Morten</creatorcontrib><creatorcontrib>Bu, Huaitian</creatorcontrib><creatorcontrib>Peters, Thijs</creatorcontrib><creatorcontrib>Dietzel, Pascal D. C.</creatorcontrib><creatorcontrib>Pilz, Monika</creatorcontrib><title>Polymer nanocomposite coatings based on polyhedral oligosilsesquioxanes: route for industrial manufacturing and barrier properties</title><title>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</title><addtitle>J Nanopart Res</addtitle><description>A route to a large variety of functionalized POSS compounds by a two-step procedure has been developed. Up-scaling to high volume industrial applications is feasible. In the first step, an amino-functionalized silane such as 3-aminopropyltriethoxy silane is converted to amino-functionalized POSS (amine-POSS) by a sol–gel process. In the second step, the amine groups of amine-POSS are converted by state-of-the-art amine chemistry. A large number of reactants including carboxylic acids, esters, anhydrides, isocyanates, carbonates, epoxides, and acrylates as well as reactants suitable for nucleophilic substitution can be applied. Conversion of an amine-POSS with hexanoic acid leads to an amide-POSS. Amine chemistry can usually be performed under mild conditions, which suppresses degradation and/or cross-linking reactions of the amine-POSS during the conversion. MALDI-TOF mass spectroscopy and dynamic light scattering (particle size: 3–6 nm) have been applied to prove the conversion of an amine-POSS to an amide-POSS.
1
H-NMR and TGA-MS prove the presence of amide-POSS and its thermal stability. Gas barrier properties of nanocomposite coatings based on functionalized POSS are characterized.</description><subject>Amines</subject><subject>Barriers</subject><subject>Carbonates</subject><subject>Carboxylic acids</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Coatings</subject><subject>Conversion</subject><subject>Esters</subject><subject>Inorganic Chemistry</subject><subject>Isocyanates</subject><subject>Lasers</subject><subject>Light scattering</subject><subject>Mass spectroscopy</subject><subject>Materials Science</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photonics</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Research Paper</subject><subject>Silanes</subject><issn>1388-0764</issn><issn>1572-896X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kU1LHzEQxhdpQav9AN4CXrxsTXazefFWpC-C0B4seAvZ7KxGdpM1swt69ZN3_vx7kIKBIXP4Pc8M81TVqeBfBOf6AoXgnai5oJJtV-uD6kh0uqmNVXcfqG-NqblW8rD6hPjIuVCNbY6q1995epmhsORTDnleMsYVWMh-jekeWe8RBpYTW4h7gKH4ieUp3hM2IeDTFvOzT4CXrOSNhGMuLKZhw7VEQmefttGHdSvkxnwayLCUSPOWkhcoawQ8qT6Onsw-__uPqz_fv91e_axvfv24vvp6U4dW2rXuwshtLyX0rTXG6EHpYEMjuRosBNN31qpOKgDhvVRSgxyHwfQ6wOitEr49rs73vjT6aQNc3RwxwDTR_nlDJ2RrdSeaVhB69h_6mLeSaDsn6JmOW6mJEnsqlIxYYHRLibMvL05wt0vF7VNxlIrbpeJ2mmavwWV3EihvnN8V_QWRzpOZ</recordid><startdate>20111001</startdate><enddate>20111001</enddate><creator>Männle, Ferdinand</creator><creator>Rosquist Tofteberg, Terje</creator><creator>Skaugen, Morten</creator><creator>Bu, Huaitian</creator><creator>Peters, Thijs</creator><creator>Dietzel, Pascal D. 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C.</au><au>Pilz, Monika</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymer nanocomposite coatings based on polyhedral oligosilsesquioxanes: route for industrial manufacturing and barrier properties</atitle><jtitle>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</jtitle><stitle>J Nanopart Res</stitle><date>2011-10-01</date><risdate>2011</risdate><volume>13</volume><issue>10</issue><spage>4691</spage><epage>4701</epage><pages>4691-4701</pages><issn>1388-0764</issn><eissn>1572-896X</eissn><abstract>A route to a large variety of functionalized POSS compounds by a two-step procedure has been developed. Up-scaling to high volume industrial applications is feasible. In the first step, an amino-functionalized silane such as 3-aminopropyltriethoxy silane is converted to amino-functionalized POSS (amine-POSS) by a sol–gel process. In the second step, the amine groups of amine-POSS are converted by state-of-the-art amine chemistry. A large number of reactants including carboxylic acids, esters, anhydrides, isocyanates, carbonates, epoxides, and acrylates as well as reactants suitable for nucleophilic substitution can be applied. Conversion of an amine-POSS with hexanoic acid leads to an amide-POSS. Amine chemistry can usually be performed under mild conditions, which suppresses degradation and/or cross-linking reactions of the amine-POSS during the conversion. MALDI-TOF mass spectroscopy and dynamic light scattering (particle size: 3–6 nm) have been applied to prove the conversion of an amine-POSS to an amide-POSS.
1
H-NMR and TGA-MS prove the presence of amide-POSS and its thermal stability. Gas barrier properties of nanocomposite coatings based on functionalized POSS are characterized.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11051-011-0435-7</doi><tpages>11</tpages></addata></record> |
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| subjects | Amines Barriers Carbonates Carboxylic acids Characterization and Evaluation of Materials Chemistry and Materials Science Coatings Conversion Esters Inorganic Chemistry Isocyanates Lasers Light scattering Mass spectroscopy Materials Science Nanocomposites Nanomaterials Nanoparticles Nanostructure Nanotechnology Optical Devices Optics Photonics Physical Chemistry Polymers Research Paper Silanes |
| title | Polymer nanocomposite coatings based on polyhedral oligosilsesquioxanes: route for industrial manufacturing and barrier properties |
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