Preparation and ionic conductive properties of all-solid polymer electrolytes based on multiarm star block polymers
A series of star block polymers with a hyperbranched core and 26 arms are successfully synthesized by atom transfer radical polymerization of styrene (St), and poly(ethylene glycol) methyl ether methacrylate from a hyperbranched polystyrene (HBPS) multifunctional initiator. All‐solid polymer electro...
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| Veröffentlicht in: | Journal of applied polymer science 2013-08, Vol.129 (3), p.1131-1142 |
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| container_title | Journal of applied polymer science |
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| creator | Ren, Shitong Chang, Hefei He, Lijuan Dang, Xiaofei Fang, Yanyan Zhang, Liaoyun Li, Huayi Hu, Youliang Lin, Yuan |
| description | A series of star block polymers with a hyperbranched core and 26 arms are successfully synthesized by atom transfer radical polymerization of styrene (St), and poly(ethylene glycol) methyl ether methacrylate from a hyperbranched polystyrene (HBPS) multifunctional initiator. All‐solid polymer electrolytes composed of these multiarm star polymers and lithium salts are prepared. The influences of polyoxyethylene (PEO) side‐chain length, PEO content, lithium salt concentration and type, and the structure of polymer on ionic conductivity are systematically investigated. The resulting polymer electrolyte with the longest PEO side chains exhibits the best ionic conductive properties. The maximum conductivity is 0.8 × 10−4 S cm−1 at 25°C with EO/Li = 30. All the prepared multiarm star block polymers possess good thermal stability. The mechanical property is greatly improved owing to the existence of polystyrene blocks in the multiarm star polymer molecules, and flexible films can be obtained by solution‐casting technique. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| doi_str_mv | 10.1002/app.38798 |
| format | Article |
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All‐solid polymer electrolytes composed of these multiarm star polymers and lithium salts are prepared. The influences of polyoxyethylene (PEO) side‐chain length, PEO content, lithium salt concentration and type, and the structure of polymer on ionic conductivity are systematically investigated. The resulting polymer electrolyte with the longest PEO side chains exhibits the best ionic conductive properties. The maximum conductivity is 0.8 × 10−4 S cm−1 at 25°C with EO/Li = 30. All the prepared multiarm star block polymers possess good thermal stability. The mechanical property is greatly improved owing to the existence of polystyrene blocks in the multiarm star polymer molecules, and flexible films can be obtained by solution‐casting technique. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.38798</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Blocking ; electrochemistry ; Electrolytes ; Ethers ; Exact sciences and technology ; Lithium ; Materials science ; Organic polymers ; Physicochemistry of polymers ; Polymers ; Polymers with particular properties ; Polystyrene resins ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; properties and characterization ; Radicals ; Reproduction ; Stars ; structure-property relations</subject><ispartof>Journal of applied polymer science, 2013-08, Vol.129 (3), p.1131-1142</ispartof><rights>Copyright © 2012 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3988-39994f45beea8f5c0a6fbd8698af946f1d7bf223c3d02df6a4890a2b31aaf6053</citedby><cites>FETCH-LOGICAL-c3988-39994f45beea8f5c0a6fbd8698af946f1d7bf223c3d02df6a4890a2b31aaf6053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.38798$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.38798$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27364241$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ren, Shitong</creatorcontrib><creatorcontrib>Chang, Hefei</creatorcontrib><creatorcontrib>He, Lijuan</creatorcontrib><creatorcontrib>Dang, Xiaofei</creatorcontrib><creatorcontrib>Fang, Yanyan</creatorcontrib><creatorcontrib>Zhang, Liaoyun</creatorcontrib><creatorcontrib>Li, Huayi</creatorcontrib><creatorcontrib>Hu, Youliang</creatorcontrib><creatorcontrib>Lin, Yuan</creatorcontrib><title>Preparation and ionic conductive properties of all-solid polymer electrolytes based on multiarm star block polymers</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A series of star block polymers with a hyperbranched core and 26 arms are successfully synthesized by atom transfer radical polymerization of styrene (St), and poly(ethylene glycol) methyl ether methacrylate from a hyperbranched polystyrene (HBPS) multifunctional initiator. All‐solid polymer electrolytes composed of these multiarm star polymers and lithium salts are prepared. The influences of polyoxyethylene (PEO) side‐chain length, PEO content, lithium salt concentration and type, and the structure of polymer on ionic conductivity are systematically investigated. The resulting polymer electrolyte with the longest PEO side chains exhibits the best ionic conductive properties. The maximum conductivity is 0.8 × 10−4 S cm−1 at 25°C with EO/Li = 30. All the prepared multiarm star block polymers possess good thermal stability. 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Sci., 2013</description><subject>Applied sciences</subject><subject>Blocking</subject><subject>electrochemistry</subject><subject>Electrolytes</subject><subject>Ethers</subject><subject>Exact sciences and technology</subject><subject>Lithium</subject><subject>Materials science</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Polymers with particular properties</subject><subject>Polystyrene resins</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>properties and characterization</subject><subject>Radicals</subject><subject>Reproduction</subject><subject>Stars</subject><subject>structure-property relations</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kE1rFTEUhgex4LW68B8ERLCLaZPJxyTLUrQVqr2LFpfhTCaBtJnJmGSq99839bZdCK4OIc_75ORtmg8EHxOMuxNYlmMqeyVfNRuCVd8y0cnXzabekVYqxd80b3O-xZgQjsWmydtkF0hQfJwRzCOq0xtk4jyupvh7i5YUF5uKtxlFhyCENsfgR7TEsJtsQjZYU1I9lEoMkO2IqmpaQ_GQJpQLJDSEaO6eE_ldc-AgZPv-aR42N1-_XJ9dtJdX59_OTi9bQ5WULVVKMcf4YC1Ixw0G4YZRCiXBKSYcGfvBdR01dMTd6AQwqTB0AyUATmBOD5vPe2_9wq_V5qInn40NAWYb16wJo6qvLRBS0Y__oLdxTXPdThPKJOe0512ljvaUSTHnZJ1ekp8g7TTB-rF-XevXf-uv7KcnI2QDwSWYjc8vga6ngnXs8eWTPffbB7v7v1CfbrfP5naf8LnYPy8JSHda9HVP_fPHuebf6QWTUmpBHwAZHqSQ</recordid><startdate>20130805</startdate><enddate>20130805</enddate><creator>Ren, Shitong</creator><creator>Chang, Hefei</creator><creator>He, Lijuan</creator><creator>Dang, Xiaofei</creator><creator>Fang, Yanyan</creator><creator>Zhang, Liaoyun</creator><creator>Li, Huayi</creator><creator>Hu, Youliang</creator><creator>Lin, Yuan</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130805</creationdate><title>Preparation and ionic conductive properties of all-solid polymer electrolytes based on multiarm star block polymers</title><author>Ren, Shitong ; Chang, Hefei ; He, Lijuan ; Dang, Xiaofei ; Fang, Yanyan ; Zhang, Liaoyun ; Li, Huayi ; Hu, Youliang ; Lin, Yuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3988-39994f45beea8f5c0a6fbd8698af946f1d7bf223c3d02df6a4890a2b31aaf6053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Blocking</topic><topic>electrochemistry</topic><topic>Electrolytes</topic><topic>Ethers</topic><topic>Exact sciences and technology</topic><topic>Lithium</topic><topic>Materials science</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Polymers with particular properties</topic><topic>Polystyrene resins</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>properties and characterization</topic><topic>Radicals</topic><topic>Reproduction</topic><topic>Stars</topic><topic>structure-property relations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ren, Shitong</creatorcontrib><creatorcontrib>Chang, Hefei</creatorcontrib><creatorcontrib>He, Lijuan</creatorcontrib><creatorcontrib>Dang, Xiaofei</creatorcontrib><creatorcontrib>Fang, Yanyan</creatorcontrib><creatorcontrib>Zhang, Liaoyun</creatorcontrib><creatorcontrib>Li, Huayi</creatorcontrib><creatorcontrib>Hu, Youliang</creatorcontrib><creatorcontrib>Lin, Yuan</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ren, Shitong</au><au>Chang, Hefei</au><au>He, Lijuan</au><au>Dang, Xiaofei</au><au>Fang, Yanyan</au><au>Zhang, Liaoyun</au><au>Li, Huayi</au><au>Hu, Youliang</au><au>Lin, Yuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and ionic conductive properties of all-solid polymer electrolytes based on multiarm star block polymers</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. 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The maximum conductivity is 0.8 × 10−4 S cm−1 at 25°C with EO/Li = 30. All the prepared multiarm star block polymers possess good thermal stability. The mechanical property is greatly improved owing to the existence of polystyrene blocks in the multiarm star polymer molecules, and flexible films can be obtained by solution‐casting technique. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.38798</doi><tpages>12</tpages></addata></record> |
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| subjects | Applied sciences Blocking electrochemistry Electrolytes Ethers Exact sciences and technology Lithium Materials science Organic polymers Physicochemistry of polymers Polymers Polymers with particular properties Polystyrene resins Preparation, kinetics, thermodynamics, mechanism and catalysts properties and characterization Radicals Reproduction Stars structure-property relations |
| title | Preparation and ionic conductive properties of all-solid polymer electrolytes based on multiarm star block polymers |
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