Results of thermodynamic calculation of the composition of passive films on Ni-Cr system alloys compared to Fe-Cr alloys

The development of a thermodynamic model for the formation of passive films on Ni-Cr alloys that was previously designed for the Fe-Cr system is presented in this study. The potential for using this model to calculate the composition of passive films and the Flade potential of multicomponent systems...

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Veröffentlicht in:Protection of metals and physical chemistry of surfaces 2012-11, Vol.48 (6), p.699-709
Hauptverfasser: Safonov, I. A., Andreev, Yu. Ya, Dub, A. V.
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Andreev, Yu. Ya
Dub, A. V.
description The development of a thermodynamic model for the formation of passive films on Ni-Cr alloys that was previously designed for the Fe-Cr system is presented in this study. The potential for using this model to calculate the composition of passive films and the Flade potential of multicomponent systems is demonstrated. The similarity between the mechanism of formation of the transition layer between a passive film and an alloy upon corrosion of the alloy in aqueous solution and under high-temperature oxidation conditions is shown.
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subjects Alloys
Characterization and Evaluation of Materials
Chemistry and Materials Science
Corrosion and Coatings
Corrosion mechanisms
Corrosion prevention
Ferrous alloys
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Intermetallic compounds
Investigation Methods for Physicochemical Systems
Iron
Materials Science
Mathematical models
Metallic Materials
Nickel base alloys
Similarity
Tribology
title Results of thermodynamic calculation of the composition of passive films on Ni-Cr system alloys compared to Fe-Cr alloys
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