Novel amphiphilic homopolymers containing meta- and para-pyridine moieties with living characteristics and their self-assembly
ABSTRACT Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized using the Suzuki coupling reaction. A living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2013-08, Vol.51 (16), p.3458-3469 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
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| creator | Hur, Yoon-Hyung Kang, Nam-Goo Kang, Beom-Goo Yu, Yong-Guen Changez, Mohammed Lee, Jae-Suk |
| description | ABSTRACT
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized using the Suzuki coupling reaction. A living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions to overcome the limitations of anionic polymerization and to compare their properties with those of poly(2‐(4‐vinylphenyl)pyridine) as reported previously. Several characteristics of the resulting isomeric P3VPPy and P4VPPy were studied, such as thermal stability, solubility, and the living nature. The block copolymerization of 4VPPy with 2‐vinylpyridine and MMA was carried out without additive to estimate the nucleophilicity of P4VPPy and to confirm its living nature. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3458–3469
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized and a living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM. |
| doi_str_mv | 10.1002/pola.26743 |
| format | Article |
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Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized using the Suzuki coupling reaction. A living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions to overcome the limitations of anionic polymerization and to compare their properties with those of poly(2‐(4‐vinylphenyl)pyridine) as reported previously. Several characteristics of the resulting isomeric P3VPPy and P4VPPy were studied, such as thermal stability, solubility, and the living nature. The block copolymerization of 4VPPy with 2‐vinylpyridine and MMA was carried out without additive to estimate the nucleophilicity of P4VPPy and to confirm its living nature. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3458–3469
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized and a living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM.</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.26743</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken, NJ: Blackwell Publishing Ltd</publisher><subject>amphiphilic homopolymers ; Anionic polymerization ; Applied sciences ; block copolymers ; Exact sciences and technology ; isomeric pyridine moiety ; living polymerization ; micelles ; Monomers ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Pyridines ; Scanning electron microscopy ; Self assembly ; Solvents ; styrene derivatives ; Styrenes ; Transmission electron microscopy</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2013-08, Vol.51 (16), p.3458-3469</ispartof><rights>2013 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4023-f918400344fdddeb670386f8ee1bc7995fdcc6ef77a238a74a58742a8f606b2e3</citedby><cites>FETCH-LOGICAL-c4023-f918400344fdddeb670386f8ee1bc7995fdcc6ef77a238a74a58742a8f606b2e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.26743$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.26743$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27531128$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hur, Yoon-Hyung</creatorcontrib><creatorcontrib>Kang, Nam-Goo</creatorcontrib><creatorcontrib>Kang, Beom-Goo</creatorcontrib><creatorcontrib>Yu, Yong-Guen</creatorcontrib><creatorcontrib>Changez, Mohammed</creatorcontrib><creatorcontrib>Lee, Jae-Suk</creatorcontrib><title>Novel amphiphilic homopolymers containing meta- and para-pyridine moieties with living characteristics and their self-assembly</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><description>ABSTRACT
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized using the Suzuki coupling reaction. A living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions to overcome the limitations of anionic polymerization and to compare their properties with those of poly(2‐(4‐vinylphenyl)pyridine) as reported previously. Several characteristics of the resulting isomeric P3VPPy and P4VPPy were studied, such as thermal stability, solubility, and the living nature. The block copolymerization of 4VPPy with 2‐vinylpyridine and MMA was carried out without additive to estimate the nucleophilicity of P4VPPy and to confirm its living nature. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3458–3469
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized and a living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM.</description><subject>amphiphilic homopolymers</subject><subject>Anionic polymerization</subject><subject>Applied sciences</subject><subject>block copolymers</subject><subject>Exact sciences and technology</subject><subject>isomeric pyridine moiety</subject><subject>living polymerization</subject><subject>micelles</subject><subject>Monomers</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Pyridines</subject><subject>Scanning electron microscopy</subject><subject>Self assembly</subject><subject>Solvents</subject><subject>styrene derivatives</subject><subject>Styrenes</subject><subject>Transmission electron microscopy</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kUFrFTEUhYMo-Kxu_AUBEUSYmkwySWZZHrUKj7aCoruQl7lxUjOTMZnXOpv-9ub11S5cCIG7yHcO956D0GtKjikh9YcpBnNcC8nZE7SipG0r0lD1FK2IUrISNf_xHL3I-YqQ8teoFbo9j9cQsBmm3pcXvMV9HGLxWQZIGds4zsaPfvyJB5hNhc3Y4ckkU01L8p0fAQ_Rw-wh4xs_9zj46z1s-8LYGZLPs7f5Xjb34BPOEFxlcoZhG5aX6JkzIcOrh3mEvn08_br-VG0uzj6vTzaV5aRmlWup4oQwzl3XdbAVkjAlnAKgWyvLJa6zVoCT0tRMGclNoySvjXKCiG0N7Ai9O_hOKf7eQZ714LOFEMwIcZc15awtoTVUFPTNP-hV3KWxbKcpk4yVmGlbqPcHyqaYcwKnp-QHkxZNid5XofdV6PsqCvz2wdJka4JLZrQ-Pypq2TBKa1U4euBufIDlP4768mJz8te7OmhK0PDnUWPSLy0kk43-fn6mL9W6EZsvTHN2B02Eqgg</recordid><startdate>20130815</startdate><enddate>20130815</enddate><creator>Hur, Yoon-Hyung</creator><creator>Kang, Nam-Goo</creator><creator>Kang, Beom-Goo</creator><creator>Yu, Yong-Guen</creator><creator>Changez, Mohammed</creator><creator>Lee, Jae-Suk</creator><general>Blackwell Publishing Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130815</creationdate><title>Novel amphiphilic homopolymers containing meta- and para-pyridine moieties with living characteristics and their self-assembly</title><author>Hur, Yoon-Hyung ; Kang, Nam-Goo ; Kang, Beom-Goo ; Yu, Yong-Guen ; Changez, Mohammed ; Lee, Jae-Suk</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4023-f918400344fdddeb670386f8ee1bc7995fdcc6ef77a238a74a58742a8f606b2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>amphiphilic homopolymers</topic><topic>Anionic polymerization</topic><topic>Applied sciences</topic><topic>block copolymers</topic><topic>Exact sciences and technology</topic><topic>isomeric pyridine moiety</topic><topic>living polymerization</topic><topic>micelles</topic><topic>Monomers</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Pyridines</topic><topic>Scanning electron microscopy</topic><topic>Self assembly</topic><topic>Solvents</topic><topic>styrene derivatives</topic><topic>Styrenes</topic><topic>Transmission electron microscopy</topic><toplevel>online_resources</toplevel><creatorcontrib>Hur, Yoon-Hyung</creatorcontrib><creatorcontrib>Kang, Nam-Goo</creatorcontrib><creatorcontrib>Kang, Beom-Goo</creatorcontrib><creatorcontrib>Yu, Yong-Guen</creatorcontrib><creatorcontrib>Changez, Mohammed</creatorcontrib><creatorcontrib>Lee, Jae-Suk</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hur, Yoon-Hyung</au><au>Kang, Nam-Goo</au><au>Kang, Beom-Goo</au><au>Yu, Yong-Guen</au><au>Changez, Mohammed</au><au>Lee, Jae-Suk</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel amphiphilic homopolymers containing meta- and para-pyridine moieties with living characteristics and their self-assembly</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><date>2013-08-15</date><risdate>2013</risdate><volume>51</volume><issue>16</issue><spage>3458</spage><epage>3469</epage><pages>3458-3469</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>ABSTRACT
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized using the Suzuki coupling reaction. A living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions to overcome the limitations of anionic polymerization and to compare their properties with those of poly(2‐(4‐vinylphenyl)pyridine) as reported previously. Several characteristics of the resulting isomeric P3VPPy and P4VPPy were studied, such as thermal stability, solubility, and the living nature. The block copolymerization of 4VPPy with 2‐vinylpyridine and MMA was carried out without additive to estimate the nucleophilicity of P4VPPy and to confirm its living nature. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3458–3469
Amphiphilic monomers containing the isomeric pyridine moieties 3‐(4‐vinylphenyl)pyridine (3VPPy) and 4‐(4‐vinylphenyl)pyridine (4VPPy) were synthesized and a living anionic polymerization of 3VPPy and 4VPPy was successfully performed under various conditions. Additionally, each amphiphilic homopolymer of P3VPPy and P4VPPy containing both a hydrophilic pyridine unit and a hydrophobic styrene unit was tested for self‐assembly behavior in a mixed solvent (THF/water) and monitored with TEM and SEM.</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/pola.26743</doi><tpages>12</tpages></addata></record> |
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| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2013-08, Vol.51 (16), p.3458-3469 |
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| subjects | amphiphilic homopolymers Anionic polymerization Applied sciences block copolymers Exact sciences and technology isomeric pyridine moiety living polymerization micelles Monomers Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Pyridines Scanning electron microscopy Self assembly Solvents styrene derivatives Styrenes Transmission electron microscopy |
| title | Novel amphiphilic homopolymers containing meta- and para-pyridine moieties with living characteristics and their self-assembly |
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