Kinetic modelling and bifurcation analysis of chemomechanically miniaturized gels under mechanical load
Chemomechanically responsive gels, with great potential applications in the fields of smart structures and biomedicines, present autonomously oscillatory deformation driven by the Belousov-Zhabotinsky chemical reaction. The dynamic behavior of the responsive gels is obviously affected by the externa...
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| Veröffentlicht in: | The European physical journal. E, Soft matter and biological physics Soft matter and biological physics, 2013-09, Vol.36 (9), p.108-108, Article 108 |
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| container_issue | 9 |
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| container_title | The European physical journal. E, Soft matter and biological physics |
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| creator | Wang, Pengfei Liu, Shaobao Zhou, Jinxiong Xu, Feng Lu, Tianjian |
| description | Chemomechanically responsive gels, with great potential applications in the fields of smart structures and biomedicines, present autonomously oscillatory deformation driven by the Belousov-Zhabotinsky chemical reaction. The dynamic behavior of the responsive gels is obviously affected by the external mechanical load. This approach proposed a kinetic model with an ordinary differential equation to describe the oscillatory deformation of the gels under the mechanical load. Then the periodic solutions and phase diagrams of the oscillation are obtained using the improved Runge-Kutta and shooting methods. The results demonstrated that bifurcations are typically existent in the system and the characters of the oscillatory deformation regularly depend on the mechanical load as well as the concentration of reactants and the stoichiometric coefficient of chemical reaction. This development is supposed to promote the practical applications of the chemomechanically responsive gels.
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| doi_str_mv | 10.1140/epje/i2013-13108-x |
| format | Article |
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E</stitle><addtitle>Eur Phys J E Soft Matter</addtitle><date>2013-09</date><risdate>2013</risdate><volume>36</volume><issue>9</issue><spage>108</spage><epage>108</epage><pages>108-108</pages><artnum>108</artnum><issn>1292-8941</issn><eissn>1292-895X</eissn><abstract>Chemomechanically responsive gels, with great potential applications in the fields of smart structures and biomedicines, present autonomously oscillatory deformation driven by the Belousov-Zhabotinsky chemical reaction. The dynamic behavior of the responsive gels is obviously affected by the external mechanical load. This approach proposed a kinetic model with an ordinary differential equation to describe the oscillatory deformation of the gels under the mechanical load. Then the periodic solutions and phase diagrams of the oscillation are obtained using the improved Runge-Kutta and shooting methods. The results demonstrated that bifurcations are typically existent in the system and the characters of the oscillatory deformation regularly depend on the mechanical load as well as the concentration of reactants and the stoichiometric coefficient of chemical reaction. This development is supposed to promote the practical applications of the chemomechanically responsive gels.
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| subjects | Biological and Medical Physics Biophysics Chemistry Complex Fluids and Microfluidics Complex Systems Exact sciences and technology General and physical chemistry Nanotechnology Physics Physics and Astronomy Polymer Sciences Regular Article Soft and Granular Matter Surfaces and Interfaces Theory of reactions, general kinetics Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Thin Films |
| title | Kinetic modelling and bifurcation analysis of chemomechanically miniaturized gels under mechanical load |
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