A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs
A two-dimensional polymer (2DP) based on the dimerization of anthraceno groups arranged in a triptycene motif is reported. A photoinduced polymerization is performed in the crystalline state and gives a lamellar 2DP via a crystal-to-crystal (but not single-crystal to single-crystal) transformation....
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| Veröffentlicht in: | Journal of the American Chemical Society 2013-09, Vol.135 (38), p.14134-14141 |
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| Sprache: | eng |
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| container_end_page | 14141 |
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| container_issue | 38 |
| container_start_page | 14134 |
| container_title | Journal of the American Chemical Society |
| container_volume | 135 |
| creator | Bhola, Radha Payamyar, Payam Murray, Daniel J Kumar, Bharat Teator, Aaron J Schmidt, Martin U Hammer, Sonja M Saha, Animesh Sakamoto, Junji Schlüter, A. Dieter King, Benjamin T |
| description | A two-dimensional polymer (2DP) based on the dimerization of anthraceno groups arranged in a triptycene motif is reported. A photoinduced polymerization is performed in the crystalline state and gives a lamellar 2DP via a crystal-to-crystal (but not single-crystal to single-crystal) transformation. Solvent-induced exfoliation provides monolayer sheets of the 2DP. The 2DP is considered to be a tiling, a mathematical approach that facilitates structural elucidation. |
| doi_str_mv | 10.1021/ja404351p |
| format | Article |
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| title | A Two-Dimensional Polymer from the Anthracene Dimer and Triptycene Motifs |
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