Volatilization of hydrogen sulfide from a quiescent surface
Air-water mass transfer of hydrogen sulfide from a shallow tank with a quiescent surface under the influence of weak wind stress on the water surface was studied numerically using a two-dimensional model. The flow field in the tank was investigated using a computational code based on a finite volume...
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Veröffentlicht in: | Water science and technology 2012-01, Vol.66 (9), p.1991-1996 |
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container_end_page | 1996 |
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container_issue | 9 |
container_start_page | 1991 |
container_title | Water science and technology |
container_volume | 66 |
creator | de Cassia Feroni, Rita Santos, Jane Meri Reis, Jr, Neyval Costa |
description | Air-water mass transfer of hydrogen sulfide from a shallow tank with a quiescent surface under the influence of weak wind stress on the water surface was studied numerically using a two-dimensional model. The flow field in the tank was investigated using a computational code based on a finite volume, which is used to numerically solve momentum, mass and continuity conservation equations. The results show that water phase flow field is strongly dependent on the wind-induced surface velocity and the aspect ratio of the tank. Based on the numerical study, the liquid-side mass transfer coefficient is correlated with Reynolds number (R(e)), tank aspect ratio (AR) and Schmidt number (S(c)). Overall mass transfer coefficient (K(L)) values extend further downstream as the R(e) number increases. |
doi_str_mv | 10.2166/wst.2012.382 |
format | Article |
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The flow field in the tank was investigated using a computational code based on a finite volume, which is used to numerically solve momentum, mass and continuity conservation equations. The results show that water phase flow field is strongly dependent on the wind-induced surface velocity and the aspect ratio of the tank. Based on the numerical study, the liquid-side mass transfer coefficient is correlated with Reynolds number (R(e)), tank aspect ratio (AR) and Schmidt number (S(c)). Overall mass transfer coefficient (K(L)) values extend further downstream as the R(e) number increases.</description><identifier>ISSN: 0273-1223</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.2166/wst.2012.382</identifier><identifier>PMID: 22925874</identifier><language>eng</language><publisher>England: IWA Publishing</publisher><subject>Aerodynamics ; Aspect ratio ; Computational fluid dynamics ; Computer applications ; Conservation equations ; Continuity (mathematics) ; Fluid flow ; Hydrogen sulfide ; Hydrogen Sulfide - chemistry ; Hydrogen sulphide ; Mass ; Mass transfer ; Mathematical analysis ; Mathematical models ; Models, Theoretical ; Momentum ; Reynolds number ; Schmidt number ; Sulphides ; Surface velocity ; Two dimensional flow ; Two dimensional models ; Volatilization ; Wind ; Wind effects ; Wind stress</subject><ispartof>Water science and technology, 2012-01, Vol.66 (9), p.1991-1996</ispartof><rights>Copyright IWA Publishing Aug 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-27d2747d205e92cc87dcbaf565f58a9091d7754a9cccf9c0c061fb36cf7e4fc33</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22925874$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>de Cassia Feroni, Rita</creatorcontrib><creatorcontrib>Santos, Jane Meri</creatorcontrib><creatorcontrib>Reis, Jr, Neyval Costa</creatorcontrib><title>Volatilization of hydrogen sulfide from a quiescent surface</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>Air-water mass transfer of hydrogen sulfide from a shallow tank with a quiescent surface under the influence of weak wind stress on the water surface was studied numerically using a two-dimensional model. 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The flow field in the tank was investigated using a computational code based on a finite volume, which is used to numerically solve momentum, mass and continuity conservation equations. The results show that water phase flow field is strongly dependent on the wind-induced surface velocity and the aspect ratio of the tank. Based on the numerical study, the liquid-side mass transfer coefficient is correlated with Reynolds number (R(e)), tank aspect ratio (AR) and Schmidt number (S(c)). Overall mass transfer coefficient (K(L)) values extend further downstream as the R(e) number increases.</abstract><cop>England</cop><pub>IWA Publishing</pub><pmid>22925874</pmid><doi>10.2166/wst.2012.382</doi><tpages>6</tpages></addata></record> |
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source | MEDLINE; EZB-FREE-00999 freely available EZB journals |
subjects | Aerodynamics Aspect ratio Computational fluid dynamics Computer applications Conservation equations Continuity (mathematics) Fluid flow Hydrogen sulfide Hydrogen Sulfide - chemistry Hydrogen sulphide Mass Mass transfer Mathematical analysis Mathematical models Models, Theoretical Momentum Reynolds number Schmidt number Sulphides Surface velocity Two dimensional flow Two dimensional models Volatilization Wind Wind effects Wind stress |
title | Volatilization of hydrogen sulfide from a quiescent surface |
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