Volatilization of hydrogen sulfide from a quiescent surface

Air-water mass transfer of hydrogen sulfide from a shallow tank with a quiescent surface under the influence of weak wind stress on the water surface was studied numerically using a two-dimensional model. The flow field in the tank was investigated using a computational code based on a finite volume...

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Veröffentlicht in:Water science and technology 2012-01, Vol.66 (9), p.1991-1996
Hauptverfasser: de Cassia Feroni, Rita, Santos, Jane Meri, Reis, Jr, Neyval Costa
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container_end_page 1996
container_issue 9
container_start_page 1991
container_title Water science and technology
container_volume 66
creator de Cassia Feroni, Rita
Santos, Jane Meri
Reis, Jr, Neyval Costa
description Air-water mass transfer of hydrogen sulfide from a shallow tank with a quiescent surface under the influence of weak wind stress on the water surface was studied numerically using a two-dimensional model. The flow field in the tank was investigated using a computational code based on a finite volume, which is used to numerically solve momentum, mass and continuity conservation equations. The results show that water phase flow field is strongly dependent on the wind-induced surface velocity and the aspect ratio of the tank. Based on the numerical study, the liquid-side mass transfer coefficient is correlated with Reynolds number (R(e)), tank aspect ratio (AR) and Schmidt number (S(c)). Overall mass transfer coefficient (K(L)) values extend further downstream as the R(e) number increases.
doi_str_mv 10.2166/wst.2012.382
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identifier ISSN: 0273-1223
ispartof Water science and technology, 2012-01, Vol.66 (9), p.1991-1996
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1996-9732
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source MEDLINE; EZB-FREE-00999 freely available EZB journals
subjects Aerodynamics
Aspect ratio
Computational fluid dynamics
Computer applications
Conservation equations
Continuity (mathematics)
Fluid flow
Hydrogen sulfide
Hydrogen Sulfide - chemistry
Hydrogen sulphide
Mass
Mass transfer
Mathematical analysis
Mathematical models
Models, Theoretical
Momentum
Reynolds number
Schmidt number
Sulphides
Surface velocity
Two dimensional flow
Two dimensional models
Volatilization
Wind
Wind effects
Wind stress
title Volatilization of hydrogen sulfide from a quiescent surface
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