An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence

A reaction between a ZrIV salt and a porphyrinic tetracarboxylic acid leads to a metal–organic framework (MOF) with two types of open channels, representing a MOF featuring a (4,8)-connected sqc net. The MOF remains intact in both boiling water and aqueous solutions with pH ranging from 1 to 11, a r...

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Veröffentlicht in:	J. Am. Chem Soc 2013-09, Vol.135 (37), p.13934-13938
Hauptverfasser:	Jiang, Hai-Long, Feng, Dawei, Wang, Kecheng, Gu, Zhi-Yuan, Wei, Zhangwen, Chen, Ying-Pin, Zhou, Hong-Cai
Format:	Artikel
Sprache:	eng
Schlagworte:	membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)
Online-Zugang:	Volltext
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