An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence
A reaction between a ZrIV salt and a porphyrinic tetracarboxylic acid leads to a metal–organic framework (MOF) with two types of open channels, representing a MOF featuring a (4,8)-connected sqc net. The MOF remains intact in both boiling water and aqueous solutions with pH ranging from 1 to 11, a r...
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| Veröffentlicht in: | J. Am. Chem Soc 2013-09, Vol.135 (37), p.13934-13938 |
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| container_end_page | 13938 |
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| container_issue | 37 |
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| container_title | J. Am. Chem Soc |
| container_volume | 135 |
| creator | Jiang, Hai-Long Feng, Dawei Wang, Kecheng Gu, Zhi-Yuan Wei, Zhangwen Chen, Ying-Pin Zhou, Hong-Cai |
| description | A reaction between a ZrIV salt and a porphyrinic tetracarboxylic acid leads to a metal–organic framework (MOF) with two types of open channels, representing a MOF featuring a (4,8)-connected sqc net. The MOF remains intact in both boiling water and aqueous solutions with pH ranging from 1 to 11, a remarkably extensive pH range that a MOF can sustain. Given its exceptional stability and pH-dependent fluorescent intensity, the MOF can potentially be applied in fluorescent pH sensing. |
| doi_str_mv | 10.1021/ja406844r |
| format | Article |
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Soc</addtitle><date>2013-09-18</date><risdate>2013</risdate><volume>135</volume><issue>37</issue><spage>13934</spage><epage>13938</epage><pages>13934-13938</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>A reaction between a ZrIV salt and a porphyrinic tetracarboxylic acid leads to a metal–organic framework (MOF) with two types of open channels, representing a MOF featuring a (4,8)-connected sqc net. The MOF remains intact in both boiling water and aqueous solutions with pH ranging from 1 to 11, a remarkably extensive pH range that a MOF can sustain. Given its exceptional stability and pH-dependent fluorescent intensity, the MOF can potentially be applied in fluorescent pH sensing.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>23984878</pmid><doi>10.1021/ja406844r</doi><tpages>5</tpages></addata></record> |
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| source | ACS Publications |
| subjects | membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing) |
| title | An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence |
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