Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material

The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption...

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Veröffentlicht in:Water science and technology 2013-01, Vol.68 (1), p.227-233
Hauptverfasser: RUBIO, Fernanda, CELSO GONCALVES, Affonso, MENEGHEL, Ana Paula, TEIXEIRA TARLEY, Cesar Ricardo, SCHWANTES, Daniel, FERREIRA COELHO, Gustavo
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container_title Water science and technology
container_volume 68
creator RUBIO, Fernanda
CELSO GONCALVES, Affonso
MENEGHEL, Ana Paula
TEIXEIRA TARLEY, Cesar Ricardo
SCHWANTES, Daniel
FERREIRA COELHO, Gustavo
description The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact.
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The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact.</abstract><cop>London</cop><pub>International Water Association</pub><pmid>23823559</pmid><doi>10.2166/wst.2013.233</doi><tpages>7</tpages></addata></record>
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subjects Activated carbon
Adsorption
Analysis methods
Analytical methods
Applied sciences
Biological and physicochemical phenomena
Biomass
Byproducts
Cadmium
Cadmium - chemistry
Comparative analysis
Comparative studies
Crambe
Crambe abyssinica
Crambe Plant
Desorption
Electron microscopy
Enthalpy
Environmental impact
Exact sciences and technology
Infrared spectroscopy
Ions
Isotherms
Mathematical models
Natural water pollution
Pollution
Removal
Scanning electron microscopy
Seeds
Seeds - chemistry
Sustainable materials
Wastewater
Wastewater treatment
Water Pollutants, Chemical - chemistry
Water treatment and pollution
title Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material
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