Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material
The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption...
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description | The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact. |
doi_str_mv | 10.2166/wst.2013.233 |
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The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact.</description><identifier>ISSN: 0273-1223</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.2166/wst.2013.233</identifier><identifier>PMID: 23823559</identifier><identifier>CODEN: WSTED4</identifier><language>eng</language><publisher>London: International Water Association</publisher><subject>Activated carbon ; Adsorption ; Analysis methods ; Analytical methods ; Applied sciences ; Biological and physicochemical phenomena ; Biomass ; Byproducts ; Cadmium ; Cadmium - chemistry ; Comparative analysis ; Comparative studies ; Crambe ; Crambe abyssinica ; Crambe Plant ; Desorption ; Electron microscopy ; Enthalpy ; Environmental impact ; Exact sciences and technology ; Infrared spectroscopy ; Ions ; Isotherms ; Mathematical models ; Natural water pollution ; Pollution ; Removal ; Scanning electron microscopy ; Seeds ; Seeds - chemistry ; Sustainable materials ; Wastewater ; Wastewater treatment ; Water Pollutants, Chemical - chemistry ; Water treatment and pollution</subject><ispartof>Water science and technology, 2013-01, Vol.68 (1), p.227-233</ispartof><rights>2014 INIST-CNRS</rights><rights>Copyright IWA Publishing Jul 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c382t-44ea743b2732ff2f1b8bcb930624da2acd5c82f0fbc836bb2389ddd2367efe4f3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27591894$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23823559$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>RUBIO, Fernanda</creatorcontrib><creatorcontrib>CELSO GONCALVES, Affonso</creatorcontrib><creatorcontrib>MENEGHEL, Ana Paula</creatorcontrib><creatorcontrib>TEIXEIRA TARLEY, Cesar Ricardo</creatorcontrib><creatorcontrib>SCHWANTES, Daniel</creatorcontrib><creatorcontrib>FERREIRA COELHO, Gustavo</creatorcontrib><title>Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact.</description><subject>Activated carbon</subject><subject>Adsorption</subject><subject>Analysis methods</subject><subject>Analytical methods</subject><subject>Applied sciences</subject><subject>Biological and physicochemical phenomena</subject><subject>Biomass</subject><subject>Byproducts</subject><subject>Cadmium</subject><subject>Cadmium - chemistry</subject><subject>Comparative analysis</subject><subject>Comparative studies</subject><subject>Crambe</subject><subject>Crambe abyssinica</subject><subject>Crambe Plant</subject><subject>Desorption</subject><subject>Electron microscopy</subject><subject>Enthalpy</subject><subject>Environmental impact</subject><subject>Exact sciences and technology</subject><subject>Infrared spectroscopy</subject><subject>Ions</subject><subject>Isotherms</subject><subject>Mathematical models</subject><subject>Natural water pollution</subject><subject>Pollution</subject><subject>Removal</subject><subject>Scanning electron microscopy</subject><subject>Seeds</subject><subject>Seeds - chemistry</subject><subject>Sustainable materials</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water treatment and pollution</subject><issn>0273-1223</issn><issn>1996-9732</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>BENPR</sourceid><recordid>eNqFkc9rFTEUhYMo9rW6cy0BEVw4zyQ3k5ksy0PbQqFQdB3yU6fMTGrujOX99-bRp4KbrrLIx7nn8BHyhrOt4Ep9esBlKxiHrQB4RjZca9XoDsRzsmGig4YLASfkFPGOMdaBZC_JiYBeQNvqDQm3ccq_7Ehzot6GaVgnmkqe6INdYqErDvN36vbNfclh9QvdFTu5SK3bY_0avKWX2f_AhWKMAalF6oaMubg4L3Q6ZAx2fEVeJDtifH18z8i3L5-_7i6b65uLq935deNrn6WRMtpOgqutRUoicdc77zQwJWSwwvrQ-l4klpzvQTlXV-gQggDVxRRlgjPy4TG3tv25RlzMNKCP42jnmFc0XNb5vJWdfhoFrVumQEFF3_2H3uW1zHWI4VpCp9peHAI_PlK-ZMQSk7kvw2TL3nBmDqJMFWUOokwVVfG3x9DVTTH8hf-YqcD7I2DR2zEVO_sB_3Fdq3lfz_8GPn2bwg</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>RUBIO, Fernanda</creator><creator>CELSO GONCALVES, Affonso</creator><creator>MENEGHEL, Ana Paula</creator><creator>TEIXEIRA TARLEY, Cesar Ricardo</creator><creator>SCHWANTES, Daniel</creator><creator>FERREIRA COELHO, Gustavo</creator><general>International Water Association</general><general>IWA Publishing</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QH</scope><scope>7UA</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>H96</scope><scope>H97</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>L.G</scope><scope>L6V</scope><scope>M0S</scope><scope>M1P</scope><scope>M7S</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>7X8</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>20130101</creationdate><title>Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material</title><author>RUBIO, Fernanda ; CELSO GONCALVES, Affonso ; MENEGHEL, Ana Paula ; TEIXEIRA TARLEY, Cesar Ricardo ; SCHWANTES, Daniel ; FERREIRA COELHO, Gustavo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c382t-44ea743b2732ff2f1b8bcb930624da2acd5c82f0fbc836bb2389ddd2367efe4f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Activated carbon</topic><topic>Adsorption</topic><topic>Analysis methods</topic><topic>Analytical methods</topic><topic>Applied sciences</topic><topic>Biological and physicochemical phenomena</topic><topic>Biomass</topic><topic>Byproducts</topic><topic>Cadmium</topic><topic>Cadmium - chemistry</topic><topic>Comparative analysis</topic><topic>Comparative studies</topic><topic>Crambe</topic><topic>Crambe abyssinica</topic><topic>Crambe Plant</topic><topic>Desorption</topic><topic>Electron microscopy</topic><topic>Enthalpy</topic><topic>Environmental impact</topic><topic>Exact sciences and technology</topic><topic>Infrared spectroscopy</topic><topic>Ions</topic><topic>Isotherms</topic><topic>Mathematical models</topic><topic>Natural water pollution</topic><topic>Pollution</topic><topic>Removal</topic><topic>Scanning electron microscopy</topic><topic>Seeds</topic><topic>Seeds - chemistry</topic><topic>Sustainable materials</topic><topic>Wastewater</topic><topic>Wastewater treatment</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>RUBIO, Fernanda</creatorcontrib><creatorcontrib>CELSO GONCALVES, Affonso</creatorcontrib><creatorcontrib>MENEGHEL, Ana Paula</creatorcontrib><creatorcontrib>TEIXEIRA TARLEY, Cesar Ricardo</creatorcontrib><creatorcontrib>SCHWANTES, Daniel</creatorcontrib><creatorcontrib>FERREIRA COELHO, Gustavo</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>ProQuest Engineering Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Engineering Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>MEDLINE - Academic</collection><collection>Environment Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Water science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>RUBIO, Fernanda</au><au>CELSO GONCALVES, Affonso</au><au>MENEGHEL, Ana Paula</au><au>TEIXEIRA TARLEY, Cesar Ricardo</au><au>SCHWANTES, Daniel</au><au>FERREIRA COELHO, Gustavo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material</atitle><jtitle>Water science and technology</jtitle><addtitle>Water Sci Technol</addtitle><date>2013-01-01</date><risdate>2013</risdate><volume>68</volume><issue>1</issue><spage>227</spage><epage>233</epage><pages>227-233</pages><issn>0273-1223</issn><eissn>1996-9732</eissn><coden>WSTED4</coden><abstract>The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact.</abstract><cop>London</cop><pub>International Water Association</pub><pmid>23823559</pmid><doi>10.2166/wst.2013.233</doi><tpages>7</tpages></addata></record> |
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subjects | Activated carbon Adsorption Analysis methods Analytical methods Applied sciences Biological and physicochemical phenomena Biomass Byproducts Cadmium Cadmium - chemistry Comparative analysis Comparative studies Crambe Crambe abyssinica Crambe Plant Desorption Electron microscopy Enthalpy Environmental impact Exact sciences and technology Infrared spectroscopy Ions Isotherms Mathematical models Natural water pollution Pollution Removal Scanning electron microscopy Seeds Seeds - chemistry Sustainable materials Wastewater Wastewater treatment Water Pollutants, Chemical - chemistry Water treatment and pollution |
title | Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material |
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