Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions
The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (81), p.9296-9298 |
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| container_end_page | 9298 |
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| container_issue | 81 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 49 |
| creator | Yamanishi, Katsunori Yairi, Takeshi Suzuki, Keisuke Kondo, Mitsuru |
| description | The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described. |
| doi_str_mv | 10.1039/c3cc44558e |
| format | Article |
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| ispartof | Chemical communications (Cambridge, England), 2013-01, Vol.49 (81), p.9296-9298 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Biomimetic Materials - chemistry Biomimetic Materials - metabolism Carbon - chemistry Catalysis Coordination Complexes - chemistry Copper - chemistry Crystallography, X-Ray Hydroxylation Ligands Molecular Conformation Porphyrins - chemistry Stereoisomerism |
| title | Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions |
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