Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.

Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-10, Vol.49 (78), p.8830-8832
Hauptverfasser:	Zhang, Luo-Qiang, Yang, Shiping, Huang, Xiaolei, You, Jingsong, Song, Feijie
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Carbazoles - chemistry Catalysis Indoles - chemistry Oxidants - chemistry Oxygen - chemistry Pyrroles - chemistry Ruthenium - chemistry
Online-Zugang:	Volltext
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