Halonium Ion Mediated Synthesis of 2‑Halomethylene-3-oxoketoxime Derivatives from Isoxazoline N‑Oxides

A protocol for the N-bromosuccinimide (NBS)- and trichloroisocyanuric acid (TCCA)-mediated synthesis of novel 2-halomethylene-3-oxoketoximes via one-pot halogenation/oxidation of isoxazoline N-oxide derivatives is described here. The keto functionality of 3-ketoximes was selectively reduced by lithi...

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Veröffentlicht in:	Journal of organic chemistry 2013-09, Vol.78 (17), p.8872-8879
Hauptverfasser:	Raihan, Mustafa J, Rajawinslin, R. R, Kavala, Veerababurao, Kuo, Chun-Wei, Kuo, Ting-Shen, He, Chiu-Hui, Huang, Hsiu-Ni, Yao, Ching-Fa
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzophenones - chemical synthesis Benzophenones - chemistry Crystallography, X-Ray Halogens - chemistry Ions - chemistry Isoxazoles - chemistry Models, Molecular Molecular Structure Oxides - chemistry Oximes - chemical synthesis Oximes - chemistry
Online-Zugang:	Volltext
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