Modified infiltration of solvated ions and ionic liquid in a nanoporous carbon

Infiltration of ions in a nanoporous carbon is responsive to the external electric field. If the liquid phase is an aqueous solution of electrolyte, the effective solid-liquid interfacial tension decreases as the voltage rises, similar to the electrowetting phenomenon at a large graphite surface. If...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2013-09, Vol.112 (4), p.885-889
Hauptverfasser: Lu, Weiyi, Kim, Taewan, Zhao, Cang, Chen, Xi, Qiao, Yu
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container_title Applied physics. A, Materials science & processing
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creator Lu, Weiyi
Kim, Taewan
Zhao, Cang
Chen, Xi
Qiao, Yu
description Infiltration of ions in a nanoporous carbon is responsive to the external electric field. If the liquid phase is an aqueous solution of electrolyte, the effective solid-liquid interfacial tension decreases as the voltage rises, similar to the electrowetting phenomenon at a large graphite surface. If the liquid phase is an ionic liquid, however, the effective interfacial tension increases with the voltage. The accessible nanopore volume is not dependent on the electric field. The unique phenomena should be related to the confinement effects of the nanopore inner surfaces.
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subjects Carbon
Characterization and Evaluation of Materials
Condensed Matter Physics
Condensed matter: structure, mechanical and thermal properties
Electric potential
Exact sciences and technology
Infiltration
Ionic liquids
Machines
Manufacturing
Nanocomposites
Nanomaterials
Nanostructure
Nanotechnology
Optical and Electronic Materials
Physics
Physics and Astronomy
Processes
Solid-fluid interfaces
Surfaces and Interfaces
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin Films
Voltage
Wetting
title Modified infiltration of solvated ions and ionic liquid in a nanoporous carbon
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