Effect of Ba0.91Ca0.09Ti0.916Sn0.084O3 on the microstructure and electrical properties of Bi0.5(Na0.925Li0.075)0.5TiO3 ceramics

(1− x )[Bi 0.5 (Na 0.925 Li 0.075 ) 0.5 ]TiO 3 – x Ba 0.91 Ca 0.09 Ti 0.916 Sn 0.084 O 3 [(1− x )BNLT– x BCTS] ceramics were prepared by the conventional sintering method in order to study the effects of BCTS content on their microstructure and electrical properties. X-ray diffraction patterns indic...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2013-05, Vol.111 (2), p.471-476
Hauptverfasser: Chen, Tao, Zhang, Ting, Wang, Guangchang, Zhou, Jifang, Zhang, Jianwei, Liu, Yuhong
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creator Chen, Tao
Zhang, Ting
Wang, Guangchang
Zhou, Jifang
Zhang, Jianwei
Liu, Yuhong
description (1− x )[Bi 0.5 (Na 0.925 Li 0.075 ) 0.5 ]TiO 3 – x Ba 0.91 Ca 0.09 Ti 0.916 Sn 0.084 O 3 [(1− x )BNLT– x BCTS] ceramics were prepared by the conventional sintering method in order to study the effects of BCTS content on their microstructure and electrical properties. X-ray diffraction patterns indicate that the BCTS diffuses into the BNLT lattice to form a solid solution. Their grain size decreases with increasing BCTS content. The macro–micro domain switching model of relaxor ferroelectrics was used to explain their abnormal temperature dependence of the dielectric loss. A better dielectric, ferroelectric, and piezoelectric behavior is demonstrated in the ceramic with x =0.06. (1− x )BNLT– x BCTS ceramics with x =0.06 have an optimum electrical behavior of d 33 ∼185 pC/N, k p ∼33.1 %, ε r ∼1335, tan δ ∼0.026, P r ∼26.7 μC/cm 2 , and E c ∼16.2 kV/cm. As a result, the introduction of BCTS to BNLT is an effective way to enhance piezoelectric properties.
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X-ray diffraction patterns indicate that the BCTS diffuses into the BNLT lattice to form a solid solution. Their grain size decreases with increasing BCTS content. The macro–micro domain switching model of relaxor ferroelectrics was used to explain their abnormal temperature dependence of the dielectric loss. A better dielectric, ferroelectric, and piezoelectric behavior is demonstrated in the ceramic with x =0.06. (1− x )BNLT– x BCTS ceramics with x =0.06 have an optimum electrical behavior of d 33 ∼185 pC/N, k p ∼33.1 %, ε r ∼1335, tan δ ∼0.026, P r ∼26.7 μC/cm 2 , and E c ∼16.2 kV/cm. 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A</stitle><date>2013-05-01</date><risdate>2013</risdate><volume>111</volume><issue>2</issue><spage>471</spage><epage>476</epage><pages>471-476</pages><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>(1− x )[Bi 0.5 (Na 0.925 Li 0.075 ) 0.5 ]TiO 3 – x Ba 0.91 Ca 0.09 Ti 0.916 Sn 0.084 O 3 [(1− x )BNLT– x BCTS] ceramics were prepared by the conventional sintering method in order to study the effects of BCTS content on their microstructure and electrical properties. X-ray diffraction patterns indicate that the BCTS diffuses into the BNLT lattice to form a solid solution. Their grain size decreases with increasing BCTS content. The macro–micro domain switching model of relaxor ferroelectrics was used to explain their abnormal temperature dependence of the dielectric loss. A better dielectric, ferroelectric, and piezoelectric behavior is demonstrated in the ceramic with x =0.06. (1− x )BNLT– x BCTS ceramics with x =0.06 have an optimum electrical behavior of d 33 ∼185 pC/N, k p ∼33.1 %, ε r ∼1335, tan δ ∼0.026, P r ∼26.7 μC/cm 2 , and E c ∼16.2 kV/cm. As a result, the introduction of BCTS to BNLT is an effective way to enhance piezoelectric properties.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00339-012-7530-1</doi><tpages>6</tpages></addata></record>
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subjects Ceramics
Characterization and Evaluation of Materials
Condensed Matter Physics
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Dielectric loss
Dielectric loss and relaxation
Dielectric properties of solids and liquids
Dielectric, piezoelectric, ferroelectric and antiferroelectric materials
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Electrical properties
Exact sciences and technology
Ferroelectric materials
Machines
Manufacturing
Materials science
Microstructure
Nanotechnology
Optical and Electronic Materials
Physics
Physics and Astronomy
Piezoelectricity
Piezoelectricity and electromechanical effects
Processes
Rapid Communication
Relaxors
Surfaces and Interfaces
Thin Films
title Effect of Ba0.91Ca0.09Ti0.916Sn0.084O3 on the microstructure and electrical properties of Bi0.5(Na0.925Li0.075)0.5TiO3 ceramics
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